File name: Pandora57s1_BoulderCO_20201222_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251208T234451.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20201222_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20201222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201222T153754.9Z 7661.651330 234 1 51.74 2 78.96 133.83 132.71 43.94 0.00 1 0.00 1 0 17 2.775e-01 2.568e-02 2.386e-01 8.643e-03 5.835262e-01 4.524170e-03 6.489942e-03 -6.000000e+00 1.577025e-01 222.47 -2.00 3.45 -2.00 320.66 0.00e+00 -3.135490e-03 1.518320e-03 4.355534e-04 -6.000000e+00 6.765390e-03 267.54 -2.00 20.00 -2.00 320.34 0.00e+00 5.046 0.002 302.00 328.00 3 4.3333e+00 1.3019e-02 5.0283e-02 -6.0000e+00 3.9049e-01 1.6719e-01 1.6409e-02 2.9430e-02 -6.0000e+00 4.2683e-01 -5.4016e-02 1.7361e-02 1.6022e-02 -6.0000e+00 2.5123e-01 -5.3480e-03 9.0472e-03 5.2425e-03 -6.0000e+00 1.0602e-01 5.5866e-05 -5.5738e-05 2.5805e-04 6.4319e-05 -6.0000e+00 7.8399e-03 -7.8146e-03 5.1269e-05 12 9 8 11 8 0 -33.15 20.23 0.16 -0.00781 -0.00823 13 3 1 5 0 3931.080 25.90 19.99 20.23 20.16 18.4 907.39 -160299 -79485 -45999 -117815 900000 -71352 -79580 86423 -85640 900000 -72847 10420 -67117 -26947 -3533 -48920 -15617 -18574 36243 -47316 -3021 5050 -8404 12807 -18996 44045 -44303 -21865 -37483 -32716 4488 -19831 -17050 -13461 8752 5514 -5250 2253 -2801 4345 -797 5179 4109 3945 12978 -817 19295 352 11144 7200 -4948 6105 14176 10077 5706 9588 6039 6706 13058 9200 12628 1329 7831 2241 1691 5799 -1012 6385 2482 1155 3773 -34258 7423 2461 3710 -499 232 276 -3091 2359 -2834 1719 139 -394 -330 876 2353 706 2870 1281 2156 98 -1098 -165 176 205 459 1501 992 -71 -241 -2147 -789 202 -1231 -1611 -1479 -414 -1264 927 952 14 501 -410 907 -223 260 2 790 -188 -576 -267 -35 1051 339 79 787 -995 -140 -294 754 -570 -654 659 -809 255 33 498 462 -280 679 -865 -275 -3429 -876 -388 -1985 900000 -694 -928 728 -1443 900000 -1275 88 -1479 -489 -62 -1585 -405 -542 658 -2085 -88 137 -278 382 -862 1142 -2843 -1077 -2065 -1781 192 -1260 -1205 -986 499 322 -374 177 -285 498 -109 722 605 591 1775 -129 2514 56 1654 1176 -1004 1235 2894 2332 1472 2492 1683 1860 3301 2355 3176 404 2497 841 622 2150 -391 2338 1025 512 1807 -25216 3587 1188 1748 -220 93 110 -1379 1157 -1580 1042 94 -285 -254 709 1969 617 2456 1075 1670 72 -776 -116 135 179 457 1680 1214 -88 -283 -2340 -774 194 -1281 -1783 -1718 -506 -1686 1336 1507 24 845 -672 1381 -325 374 2 1236 -310 -957 -429 -54 1551 481 108 1027 -1344 -206 -485 1344 -1097 -1315 1375 -1826 601 75 1141 1061 -672 1525 -1867 -568 SS 20201222T154021.0Z 7661.653020 236 1 49.92 2 78.62 134.28 132.39 44.60 0.00 1 0.00 1 0 17 2.364e-01 1.067e-02 2.711e-01 8.127e-03 5.597898e-01 4.232502e-03 6.231662e-03 -6.000000e+00 1.350698e-01 222.47 -2.00 3.45 -2.00 320.62 0.00e+00 7.350689e-04 1.438535e-03 4.264237e-04 -6.000000e+00 5.727611e-03 267.54 -2.00 20.00 -2.00 320.32 0.00e+00 4.909 0.002 302.00 328.00 3 4.4016e+00 1.2143e-02 4.8726e-02 -6.0000e+00 3.3360e-01 8.3039e-02 1.5658e-02 2.8391e-02 -6.0000e+00 3.6495e-01 8.3466e-03 1.7280e-02 1.5467e-02 -6.0000e+00 2.1438e-01 -2.0446e-02 8.9552e-03 5.0433e-03 -6.0000e+00 9.1028e-02 6.0633e-05 -3.7319e-04 2.4201e-04 6.0040e-05 -6.0000e+00 6.7079e-03 -5.9704e-03 3.1056e-05 12 8 8 10 0 0 77.25 20.23 0.52 -0.00597 -0.00877 13 3 1 5 0 3839.040 25.90 20.01 20.23 20.27 18.4 908.56 900000 -92665 -26245 23067 900000 900000 -144927 36096 -1524 -108528 13323 -67466 10989 -45666 79304 27277 -15617 -29491 -12834 27820 -6188 42240 -306 -7634 84329 -1874 -4408 -7245 -1441 5466 25227 15730 -2203 22973 -34378 1514 32431 21882 9049 -11774 17014 -3556 7393 -3671 -125 4138 -7373 4314 -4161 255 480 4242 10931 4809 10585 2194 1987 119 -2167 1347 -8690 2734 -3981 -1051 -696 -1165 3605 -2308 1479 -3077 -352 -658 1347 1814 212 1077 -3851 1367 -1698 -1741 476 -3071 1438 -992 -238 431 1172 1416 -166 739 1368 -29 -958 -1521 207 -1384 2137 1320 1004 -471 -707 -1339 -938 982 -1417 -1033 -250 -1635 531 -262 1327 -48 910 -486 62 206 -1449 514 -546 -345 -400 681 567 -703 1839 -720 1090 -108 -137 857 -699 812 -238 170 -453 -64 37 -157 439 -87 68 107 -589 900000 -1016 -208 183 900000 900000 -2826 286 -12 -2116 106 -1113 102 -935 628 396 -392 -934 -373 569 -184 781 -9 -267 1280 -72 -177 -292 -53 198 866 696 -134 1168 -2786 92 1584 1401 744 -1435 1763 -488 955 -544 -18 582 -1182 628 -682 42 87 825 2171 1102 2432 571 534 33 -593 350 -2558 780 -1363 -390 -270 -442 1270 -876 585 -1453 -179 -353 706 902 99 446 -1544 514 -715 -853 265 -2011 988 -740 -188 360 1023 1270 -152 647 1109 -22 -699 -1121 163 -1263 2155 1525 1267 -606 -861 -1495 -953 970 -1530 -1177 -297 -2098 720 -393 2000 -77 1454 -757 97 305 -2165 780 -886 -585 -682 1117 899 -1089 2650 -1022 1463 -150 -208 1433 -1293 1462 -452 338 -963 -142 85 -366 1025 -197 147 218 -1162 SS 20201222T154244.7Z 7661.654684 238 1 51.41 2 78.30 134.73 132.07 45.25 0.00 1 0.00 1 0 25 2.875e-01 9.006e-03 2.514e-01 7.748e-03 5.506093e-01 4.032559e-03 6.187015e-03 -6.000000e+00 1.630575e-01 222.47 -2.00 3.45 -2.00 320.52 0.00e+00 2.535155e-03 1.316774e-03 3.832335e-04 -6.000000e+00 6.737335e-03 267.54 -2.00 20.00 -2.00 320.20 0.00e+00 4.782 0.002 302.00 328.00 3 4.4061e+00 1.1561e-02 4.7585e-02 -6.0000e+00 4.0333e-01 1.1958e-01 1.4368e-02 2.7726e-02 -6.0000e+00 4.4070e-01 -4.6464e-02 1.5021e-02 1.4964e-02 -6.0000e+00 2.6029e-01 9.5160e-03 7.8763e-03 4.8566e-03 -6.0000e+00 1.1041e-01 6.6367e-05 -4.4167e-04 2.3326e-04 5.9487e-05 -6.0000e+00 8.0352e-03 -5.7058e-03 5.7470e-05 11 9 0 11 8 0 51.03 20.24 0.08 -0.00571 -0.00902 14 3 1 5 0 3671.060 25.90 20.00 20.24 20.34 18.5 909.12 -57510 900000 173253 -85430 -38752 -110640 -34713 -531 -80237 28124 -67664 -539 193481 655 7795 -30038 -12586 -36211 -42324 1541 -1189 -11103 -16588 10398 -6195 608 -21292 -69 9537 -27919 -2677 5114 3510 836 2127 -1118 -5612 6431 -4898 -14346 4505 -2302 -1860 4957 213 -2218 2061 -1787 1651 2214 6783 -142 1635 3535 5333 -2504 3879 1580 6889 -375 2885 -32 -1356 -1467 2160 1355 -1940 1508 1626 1851 721 1224 48 276 62 411 -3084 -527 -1668 898 1723 674 -1806 -1322 -1435 -969 1172 -602 -11 -219 1997 -298 -124 -559 -1269 338 -656 2196 1000 -297 -227 -780 -1626 -2158 -990 -2106 -217 -1180 462 237 566 611 659 -45 -479 194 -774 151 -664 162 489 506 811 78 1475 216 -191 105 966 -417 34 591 -569 364 6 -373 -458 234 -17 -82 286 -187 -344 -535 900000 1309 -1291 -338 -1929 -328 -4 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