File name: Pandora57s1_BoulderCO_20210108_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251208T235317.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210108_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210108T155248.8Z 7678.661676 230 1 51.64 2 76.98 134.35 57.20 197.09 0.00 1 0.00 1 0 25 1.398e-01 2.246e-02 1.706e-01 6.475e-03 4.881965e-01 3.370670e-03 5.525100e-03 -6.000000e+00 8.011977e-02 222.94 -2.00 3.45 -2.00 320.14 0.00e+00 -4.570251e-04 1.006508e-03 2.896758e-04 -6.000000e+00 3.606066e-03 266.55 -2.00 20.00 -2.00 319.83 0.00e+00 4.330 0.001 302.00 328.00 3 4.6904e+00 9.4351e-03 4.2681e-02 -6.0000e+00 1.9870e-01 4.9924e-02 1.1438e-02 2.4426e-02 -6.0000e+00 2.1738e-01 4.1831e-02 1.1418e-02 1.3006e-02 -6.0000e+00 1.2743e-01 -2.9237e-02 6.0716e-03 4.1499e-03 -6.0000e+00 5.4120e-02 7.8483e-05 -3.6225e-04 1.9691e-04 4.7579e-05 -6.0000e+00 4.0067e-03 -1.0709e-03 8.0974e-05 12 9 8 11 8 0 -0.84 19.99 0.46 -0.00107 -0.00379 13 3 1 5 0 3971.190 25.68 20.01 19.99 10.89 17.4 857.03 -7495 900000 -59307 900000 59858 900000 -56678 -51967 900000 45946 900000 -3371 65630 -25809 -20244 -12506 -25878 21736 17465 3223 236 -6770 9722 -18119 15412 -23661 15176 14602 689 19192 -5385 2506 -9269 -1158 -17328 -672 9787 -10543 12515 -4573 -510 1182 1214 -3368 -3948 -1139 -1971 695 -3271 -6693 4536 -3065 4437 -1092 1100 3714 -2315 506 1031 6097 4062 4628 1206 1720 2797 -112 963 -4076 788 -247 -930 2199 -1172 3233 277 1090 224 402 -616 -2511 347 -1953 -2393 -2113 -2029 606 -46 1194 348 559 3024 471 826 -282 1230 -873 498 697 -853 929 -58 -280 -1176 -625 -1407 -1036 -165 -745 421 520 968 318 -508 -510 -517 -350 -1260 -169 -134 -1062 -269 -31 782 422 1010 968 375 635 -1200 -696 -1048 -988 -1018 13658 -883 -1175 -961 -284 -645 -202 -676 238 -388 -58 900000 -950 900000 378 900000 -853 -857 900000 386 900000 -53 621 -689 -619 -413 -1080 663 597 124 10 -299 382 -1029 681 -1642 729 737 38 918 -342 169 -796 -98 -1665 -54 779 -1212 1397 -726 -88 214 230 -682 -809 -229 -403 140 -698 -1546 1019 -820 1195 -335 350 1195 -814 173 343 1899 1325 1624 487 762 1272 -50 414 -1855 368 -132 -556 1338 -737 1857 151 532 101 177 -295 -1408 218 -1417 -1902 -1772 -1814 563 -45 1197 353 546 2683 397 653 -224 1037 -849 543 856 -1068 1143 -74 -323 -1262 -666 -1620 -1260 -209 -1006 558 754 1517 525 -839 -803 -761 -485 -1746 -240 -202 -1696 -431 -48 1171 611 1492 1371 512 874 -1833 -1083 -1770 -1760 -1882 22801 -1811 -2550 -2138 -639 -1464 -442 -1414 470 -745 SS 20210108T160256.0Z 7678.668703 233 1 49.91 2 75.62 136.31 57.83 199.81 0.00 1 0.00 1 0 25 1.541e-01 2.557e-02 1.304e-01 5.598e-03 4.488851e-01 2.854455e-03 5.168302e-03 -6.000000e+00 8.750712e-02 222.94 -2.00 3.45 -2.00 319.88 0.00e+00 -4.980159e-04 7.792147e-04 2.370358e-04 -6.000000e+00 3.581663e-03 266.55 -2.00 20.00 -2.00 319.57 0.00e+00 3.945 0.001 302.00 328.00 3 4.7481e+00 7.9240e-03 3.9053e-02 -6.0000e+00 2.1667e-01 3.2685e-02 9.3601e-03 2.2473e-02 -6.0000e+00 2.3671e-01 2.4145e-02 8.6011e-03 1.1747e-02 -6.0000e+00 1.3966e-01 -1.6711e-02 4.6124e-03 3.6617e-03 -6.0000e+00 5.8755e-02 1.0651e-04 -5.1194e-04 1.6961e-04 4.4596e-05 -6.0000e+00 4.3080e-03 -2.5272e-03 -6.8873e-06 12 9 8 11 8 0 30.87 20.01 0.39 -0.00253 -0.00637 15 3 1 5 0 3326.520 25.68 20.00 20.01 11.45 17.4 860.66 -63957 126431 -26713 11534 -24206 -40817 -981 -59941 8271 -40175 3274 -9005 3972 -28179 -17347 -14212 -2461 -13925 18872 5970 15536 -4867 6061 14399 4403 -11345 441 6987 -2531 337 -17961 10209 -4369 -3320 1415 -14188 3544 383 3309 -510 -2268 1753 2211 3362 -501 -343 -1396 -3898 704 -1859 1740 225 550 -1186 -2308 2783 1021 -1307 24 983 2208 -1100 1820 -501 2592 1402 586 -2417 -586 449 386 4316 753 1896 2314 355 1661 -2990 22 -1753 -1148 -787 -3105 -1166 -1239 -162 -305 221 1413 999 1592 827 391 216 259 -710 -322 793 420 -304 -691 -679 -529 -1269 -582 -714 233 -709 -217 382 324 486 -159 143 -775 -1182 -997 -1239 -359 -1047 -61 637 233 793 1160 590 433 691 -107 -720 -644 -1088 -1581 16721 -1403 -1288 -371 -825 -1044 -161 -291 -217 -645 -1423 690 -494 140 -386 -754 -13 -1661 132 -1130 62 -208 95 -1124 -743 -680 -115 -784 816 308 750 -290 339 804 294 -939 33 469 -179 24 -1682 819 -455 -363 142 -1644 377 49 504 -96 -490 388 508 778 -121 -83 -344 -987 173 -486 474 68 180 -425 -880 1045 401 -526 9 372 847 -471 839 -259 1340 703 283 -1206 -308 265 252 2845 514 1225 1378 194 820 -1504 12 -1065 -795 -611 -2685 -970 -1101 -152 -303 225 1425 978 1553 750 334 182 235 -678 -347 950 545 -397 -856 -770 -554 -1339 -655 -854 289 -941 -306 582 535 835 -272 232 -1181 -1705 -1419 -1833 -558 -1730 -101 1027 366 1193 1655 811 570 915 -155 -1149 -1106 -1975 -2982 27424 -2928 -2834 -831 -1765 -2253 -359 -618 -439 -1268 SS 20210108T161421.8Z 7678.676642 236 1 51.67 2 74.13 138.58 58.64 202.83 0.00 1 0.00 1 0 17 6.311e-02 9.691e-03 6.194e-02 4.319e-03 4.388162e-01 2.173613e-03 5.005234e-03 -6.000000e+00 3.582665e-02 222.94 -2.00 3.45 -2.00 319.64 0.00e+00 5.462002e-04 5.532430e-04 2.064690e-04 -6.000000e+00 1.466674e-03 266.55 -2.00 20.00 -2.00 319.33 0.00e+00 3.598 0.001 302.00 328.00 3 4.7157e+00 5.9461e-03 3.6351e-02 -6.0000e+00 8.8706e-02 8.8490e-02 6.9277e-03 2.1635e-02 -6.0000e+00 9.6916e-02 -1.8196e-02 5.9730e-03 1.1271e-02 -6.0000e+00 5.7181e-02 -5.9028e-03 3.2332e-03 3.4939e-03 -6.0000e+00 2.4052e-02 1.4267e-04 -2.8383e-04 1.2951e-04 3.8209e-05 -6.0000e+00 1.7643e-03 -1.2912e-03 -8.2077e-06 12 8 8 10 0 0 -5.75 20.03 0.32 -0.00129 -0.00342 18 4 1 5 0 2834.720 25.68 20.01 20.03 11.82 17.4 862.91 16019 3445 -29624 -23051 -23501 -27611 5217 -5163 3653 -31668 -17262 789 5658 -20699 8074 -6478 4513 3390 -5498 3321 -1571 -5078 870 -10548 -587 4364 -3491 -1920 -4601 -672 1153 2211 3202 4120 -1460 -4798 -4324 -4417 -1725 1501 2290 617 -289 717 -51 -1824 945 833 -869 4236 1171 785 1261 657 784 -409 -1063 95 1151 1038 -74 1726 1647 1681 1329 343 -547 -1112 1270 1526 1965 -2397 488 695 -346 -1408 -921 -1548 -608 -1160 -1025 -1236 -1934 -1971 -798 -177 225 84 273 361 232 -307 94 353 435 714 1131 1790 738 218 -535 -933 -1007 228 -459 -942 -998 -1099 101 -104 562 235 340 -21 -284 181 163 276 382 20 50 -1 -128 -1 1165 -49 401 618 -101 254 501 785 -63 -4142 106 281 676 410 422 227 164 -225 -502 236 65 -821 -574 -536 -640 93 -116 85 -1123 -545 22 181 -1039 363 -387 263 214 -403 233 -119 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