File name: Pandora57s1_BoulderCO_20210112_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251208T235312.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210112_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210112T155015.2Z 7682.659898 77 1 52.33 2 77.06 133.18 76.87 140.75 0.00 1 0.00 1 0 17 2.913e-01 1.334e-02 2.381e-01 7.120e-03 6.180788e-01 3.766510e-03 6.883886e-03 -6.000000e+00 1.666872e-01 223.06 -2.00 3.45 -2.00 320.64 0.00e+00 3.840555e-03 1.267249e-03 4.655371e-04 -6.000000e+00 7.224973e-03 266.31 -2.00 20.00 -2.00 320.33 0.00e+00 4.355 0.001 302.00 328.00 3 4.5907e+00 1.0774e-02 4.7112e-02 -6.0000e+00 4.1283e-01 1.7762e-01 1.3720e-02 3.1247e-02 -6.0000e+00 4.5130e-01 -1.0654e-01 1.4932e-02 1.7021e-02 -6.0000e+00 2.6547e-01 3.8096e-02 7.7839e-03 5.5395e-03 -6.0000e+00 1.1268e-01 6.8212e-05 -6.0343e-04 2.0811e-04 6.8063e-05 -6.0000e+00 8.3268e-03 -3.1377e-03 -1.2435e-05 12 9 8 11 8 0 -4.36 20.21 0.36 -0.00314 -0.00767 13 3 1 5 0 3976.820 25.79 20.00 20.21 10.60 17.3 860.64 -145345 900000 -115247 900000 -56629 -59232 900000 -42012 20213 -95865 -36528 900000 -83886 56092 -73864 44739 -32645 81714 -16741 12949 38762 -39122 69055 -39784 4418 -13941 -7755 124067 -59265 14593 -11442 27454 -2504 -3247 11146 -35092 9569 -5530 1026 12838 7192 -4953 -7426 1713 -5446 7522 2691 -517 4904 -1602 7133 6151 4297 859 -2980 2496 641 4350 -1401 3517 6654 -22 1896 -301 1165 -3211 847 1485 -1629 2713 -1233 21007 2210 217 -2470 -183 -3869 -3438 1564 1524 1779 107 -2663 -2172 -2408 243 -982 595 -867 -321 1804 -821 -1039 -1922 -140 -634 -1006 1776 139 1386 -515 -1153 -2156 -385 -377 -1700 -1372 -1340 -227 652 351 257 611 -1 -908 74 -274 116 -139 -25 298 846 638 1114 1170 765 -163 574 308 263 227 -161 -380 -323 -99 -82 544 -42 -283 -122 130 135 -808 -2483 900000 -1845 900000 -453 -474 900000 -336 140 -1586 -351 900000 -1836 422 -2366 525 -941 898 -491 297 703 -1545 1038 -1762 134 -536 -286 1291 -3511 444 -531 1026 -146 -205 589 -2903 552 -434 91 1213 810 -677 -1094 237 -820 1016 389 -79 743 -275 1237 1198 931 209 -795 653 175 1138 -377 884 1666 -6 613 -112 448 -1265 314 558 -685 1245 -650 9273 1167 111 -1181 -77 -1555 -1373 653 746 1012 71 -1977 -1577 -1863 194 -834 511 -756 -268 1481 -643 -777 -1466 -116 -558 -1025 2006 174 1722 -614 -1254 -2148 -371 -387 -1868 -1577 -1643 -298 940 560 435 1032 -2 -1414 109 -399 175 -220 -42 491 1337 972 1624 1627 1027 -212 758 452 432 408 -310 -765 -683 -221 -180 1219 -96 -648 -268 287 281 -1630 SS 20210112T160015.8Z 7682.666850 80 1 51.62 2 75.68 135.11 75.73 142.67 0.00 1 0.00 1 0 17 2.083e-01 1.781e-02 2.079e-01 5.888e-03 5.624002e-01 3.077027e-03 6.292851e-03 -6.000000e+00 1.201368e-01 223.06 -2.00 3.45 -2.00 320.43 0.00e+00 -8.890079e-04 1.001517e-03 3.834123e-04 -6.000000e+00 4.881100e-03 266.31 -2.00 20.00 -2.00 320.12 0.00e+00 3.962 0.001 302.00 328.00 3 4.6622e+00 8.7790e-03 4.2759e-02 -6.0000e+00 2.9807e-01 5.1432e-02 1.1060e-02 2.8249e-02 -6.0000e+00 3.2616e-01 3.4524e-02 1.1861e-02 1.5334e-02 -6.0000e+00 1.9056e-01 -2.8750e-02 6.2019e-03 4.9763e-03 -6.0000e+00 8.0131e-02 9.6594e-05 -4.5280e-04 1.7464e-04 5.8744e-05 -6.0000e+00 6.0214e-03 -4.4684e-03 4.5590e-05 12 9 8 11 8 0 -12.05 20.21 0.53 -0.00447 -0.00787 16 3 1 5 0 3225.400 25.79 20.00 20.21 12.31 17.4 873.10 900000 28189 -89610 -80096 -102383 -66026 900000 900000 41622 120972 -45398 -1128 -21975 -3268 -12881 -28238 42753 -7401 -12468 -6839 4410 5681 -32071 -27346 16615 -19060 -18362 -15908 5993 31230 -3096 6865 -4830 26953 -3577 -17715 9702 -2252 2199 987 -3588 -3332 5594 3390 1769 -2915 1491 -4790 -3067 456 2292 1541 2289 2127 1062 -231 143 639 987 -137 -2583 1686 780 2734 1065 61 -177 -1143 -307 -1552 1459 1596 2355 1897 1009 -1527 250 -1251 -201 -3154 -1322 -2323 -2519 -868 -1352 -966 365 2061 579 2272 1773 2453 1070 -678 1072 -1609 295 686 309 50 -505 -977 -1663 -958 -938 -703 124 151 844 -53 379 15 502 -23 -1075 -152 -1015 -264 -1211 -260 29 308 550 352 1075 -255 111 209 -904 -645 -638 -664 -1147 9810 -1016 -427 -258 -518 -332 -499 165 -421 -383 900000 162 -1108 -884 -1311 -583 900000 900000 239 694 -608 -11 -315 -48 -239 -723 654 -190 -363 -199 119 153 -1331 -1195 513 -900 -884 -723 229 971 -144 336 -305 1333 -234 -1322 604 -187 215 118 -509 -508 818 518 276 -484 240 -835 -543 82 446 336 542 547 294 -68 43 192 288 -40 -781 529 277 1059 440 25 -70 -464 -134 -781 790 906 1322 1018 502 -700 104 -519 -90 -1678 -801 -1614 -1923 -690 -1151 -874 342 1954 557 2076 1516 1933 810 -524 885 -1550 319 778 383 62 -597 -1135 -1777 -1006 -1051 -832 153 197 1099 -77 598 25 832 -37 -1634 -217 -1443 -385 -1883 -419 46 481 827 510 1588 -367 152 291 -1297 -1027 -1106 -1223 -2213 17791 -2184 -961 -595 -1218 -781 -1136 354 -857 -750 SS 20210112T161058.1Z 7682.674283 83 1 50.15 2 74.26 137.23 74.55 144.77 0.00 1 0.00 1 0 17 1.135e-01 7.904e-03 1.595e-01 4.667e-03 5.304216e-01 2.374118e-03 5.961501e-03 -6.000000e+00 6.448571e-02 223.06 -2.00 3.45 -2.00 320.15 0.00e+00 -4.190383e-04 7.065068e-04 3.176669e-04 -6.000000e+00 2.638319e-03 266.31 -2.00 20.00 -2.00 319.85 0.00e+00 3.625 0.001 302.00 328.00 3 4.6803e+00 6.6441e-03 3.9555e-02 -6.0000e+00 1.5971e-01 7.2773e-02 8.0685e-03 2.6340e-02 -6.0000e+00 1.7447e-01 -2.8035e-03 8.0632e-03 1.4007e-02 -6.0000e+00 1.0293e-01 -1.2321e-02 4.2978e-03 4.4383e-03 -6.0000e+00 4.3291e-02 1.2761e-04 -3.8973e-04 1.3667e-04 5.0500e-05 -6.0000e+00 3.1735e-03 -2.9323e-03 -2.6669e-05 11 9 0 11 8 0 -24.04 20.22 0.39 -0.00293 -0.00586 18 4 1 5 0 2785.460 25.79 20.00 20.22 14.45 17.5 887.15 -26075 1527 -45995 -33944 -38839 -17829 60039 -33193 31278 -19127 -26635 45749 -11062 -13610 -141 4219 -23119 -6910 -10224 -9562 -15004 -16558 -13942 8895 1241 -20394 -8478 6129 -4800 7186 -5127 1509 1611 -6146 1417 -5374 -3295 -8542 -3819 6219 3150 537 -1687 2549 -2602 4722 -1639 1555 1244 -737 3226 -1093 3906 -1541 236 2192 800 2101 2680 1006 93 -181 1411 2252 2037 1212 323 -270 -66 1033 399 -4511 -539 487 46 832 390 -3163 -60 -444 341 -1523 -2193 -635 -1476 454 -29 131 229 2063 445 285 1246 -307 466 -71 348 1547 280 804 -518 -1117 -691 -418 -1331 -1232 -1071 -749 42 1071 235 294 -114 -39 -119 -529 -253 -553 241 -1 150 115 389 422 634 100 505 -79 128 -420 -37 -288 -646 2044 -197 -407 71 236 -216 246 -319 -12 -469 -237 12 -628 -399 -442 -162 273 -441 249 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