File name: Pandora57s1_BoulderCO_20210123_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251208T235402.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210123_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210123T154308.9Z 7693.654964 165 1 49.71 2 76.80 129.76 120.25 12.38 0.00 1 0.00 1 0 17 2.618e-01 9.642e-03 2.261e-01 6.845e-03 5.935704e-01 3.585004e-03 6.590772e-03 -6.000000e+00 1.497636e-01 223.42 -2.00 3.45 -2.00 320.60 0.00e+00 1.739971e-03 1.194129e-03 4.354273e-04 -6.000000e+00 6.401260e-03 266.06 -2.00 20.00 -2.00 320.30 0.00e+00 4.276 0.001 302.00 328.00 3 4.6268e+00 1.0217e-02 4.5761e-02 -6.0000e+00 3.7238e-01 1.2397e-01 1.3043e-02 2.9979e-02 -6.0000e+00 4.0718e-01 -4.9921e-02 1.4179e-02 1.6283e-02 -6.0000e+00 2.3876e-01 1.1647e-02 7.3979e-03 5.2674e-03 -6.0000e+00 1.0022e-01 7.3928e-05 -6.2847e-04 2.0128e-04 6.2936e-05 -6.0000e+00 7.5290e-03 1.3028e-03 -7.6078e-05 12 9 8 11 8 0 8.74 19.78 0.41 0.00130 -0.00342 13 3 1 5 0 3823.030 25.47 20.02 19.78 8.94 17.2 839.84 -89476 64426 53171 900000 152359 -36061 -108339 900000 -96088 900000 -104037 -107771 6677 -11960 -24807 -7506 29001 -9952 -14910 -8012 13491 34809 18769 21194 -17399 -16601 -9889 3105 -8628 -26419 37024 -10876 -4666 10507 -4462 -1935 12467 6855 -11899 11727 -2622 -1042 -783 -6915 -1369 766 1103 5591 -789 1100 -2405 7386 -6205 2835 -1272 -561 461 -1636 2110 -2922 1856 4225 3482 5568 -281 2274 -1344 -1912 960 1698 2506 1414 671 1348 1333 1258 -1183 907 1056 -983 -2396 -1502 -462 -2979 608 -1779 -61 1768 952 1172 595 553 59 123 -366 -676 135 559 713 -292 -534 -877 -2173 -175 -1291 -1192 -1080 -17 -135 -14 482 -282 699 -460 -151 1198 -643 140 -557 396 -373 -38 123 473 1548 188 614 -643 1041 56 -37 678 -1492 1547 -490 -31 306 299 -123 -250 226 -579 -567 -918 430 355 900000 1016 -241 -1612 900000 -1627 900000 -2189 -2655 65 -178 -522 -158 476 -266 -451 -238 332 697 462 555 -723 -724 -411 110 -337 -1315 1140 -636 -295 609 -291 -122 749 514 -1313 1222 -355 -149 -117 -1048 -214 119 174 864 -135 196 -489 1512 -1475 668 -330 -150 125 -453 547 -783 487 1182 1105 1929 -108 831 -498 -728 387 774 1251 745 353 667 603 511 -456 368 436 -484 -1390 -981 -326 -2286 480 -1528 -54 1578 856 1012 481 415 42 89 -293 -622 142 663 915 -379 -653 -975 -2234 -175 -1393 -1358 -1291 -21 -185 -22 741 -460 1130 -723 -238 1771 -962 215 -911 670 -634 -62 194 716 2207 261 817 -886 1560 95 -69 1230 -2888 3053 -1049 -70 701 694 -286 -563 476 -1162 -1096 SS 20210123T155318.7Z 7693.662022 168 1 51.36 2 75.32 131.70 119.78 14.98 0.00 1 0.00 1 0 25 1.980e-01 8.376e-03 1.996e-01 5.717e-03 5.525506e-01 2.977167e-03 6.202994e-03 -6.000000e+00 1.131701e-01 223.42 -2.00 3.45 -2.00 320.33 0.00e+00 1.206352e-03 9.337646e-04 3.618355e-04 -6.000000e+00 4.660833e-03 266.06 -2.00 20.00 -2.00 320.02 0.00e+00 3.871 0.001 302.00 328.00 3 4.6766e+00 8.4456e-03 4.1919e-02 -6.0000e+00 2.8029e-01 9.9198e-02 1.0412e-02 2.7714e-02 -6.0000e+00 3.0629e-01 -1.9439e-02 1.0702e-02 1.4867e-02 -6.0000e+00 1.8017e-01 -5.3739e-03 5.6358e-03 4.7668e-03 -6.0000e+00 7.5501e-02 1.0166e-04 -3.2971e-04 1.7088e-04 5.6723e-05 -6.0000e+00 5.5396e-03 1.3630e-03 -2.9240e-05 11 9 0 11 8 0 23.08 19.77 0.26 0.00136 -0.00111 16 3 1 5 0 3209.150 25.47 19.99 19.77 9.46 17.4 843.53 -52596 7272 -65641 26305 -126467 900000 -76136 9248 -14508 -87807 7786 -43110 95211 -27077 6185 4391 -16136 -123 -33794 -13112 7980 -441 10613 -10387 -10273 -12542 788 -15809 -1440 11216 -4444 23292 -6147 9238 -2148 711 307 -10461 1744 -1756 2402 -674 -1698 -224 -1801 1681 221 5284 -3737 134 4901 -934 7685 272 2790 1430 1105 109 -295 2983 817 3761 1406 998 -662 971 -1130 -2009 1916 1468 -971 1532 508 893 -1120 431 -104 -732 -1384 -2418 1314 -1418 -2048 -1473 -1597 598 -1462 179 957 2265 801 -207 -624 -1522 -317 1255 1001 365 349 443 -1388 -524 -446 115 -438 -1352 -635 -1152 -45 -35 594 -147 725 920 -445 -135 -533 -128 126 -142 169 411 382 -641 881 -19 -49 851 359 315 -525 192 -589 1498 -470 -538 116 -7 -67 104 -285 67 -153 -496 47 -873 147 -2766 900000 -1077 69 -155 -1958 76 -721 531 -592 129 102 -512 -4 -1507 -500 253 -15 346 -454 -485 -640 36 -820 -63 457 -244 1129 -456 626 -158 50 24 -1072 193 -240 354 -110 -293 -39 -321 293 40 918 -732 27 1019 -228 1872 77 815 439 349 35 -92 883 254 1235 530 419 -294 411 -475 -865 860 754 -564 906 301 500 -587 200 -45 -313 -650 -1335 808 -1015 -1608 -1216 -1406 548 -1435 178 942 2117 706 -171 -490 -1214 -272 1208 1104 426 441 558 -1675 -570 -478 122 -500 -1527 -748 -1449 -60 -51 951 -248 1211 1468 -675 -194 -761 -188 197 -231 274 647 580 -947 1221 -25 -68 1195 517 503 -919 354 -1138 2973 -1012 -1219 267 -16 -158 234 -611 136 -300 SS 20210123T160416.7Z 7693.669638 171 1 49.43 2 73.78 133.86 119.19 17.75 0.00 1 0.00 1 0 17 1.364e-01 1.483e-02 1.042e-01 4.511e-03 5.083880e-01 2.299527e-03 5.722140e-03 -6.000000e+00 7.751949e-02 223.42 -2.00 3.45 -2.00 320.07 0.00e+00 2.061804e-03 6.578055e-04 2.774781e-04 -6.000000e+00 3.169064e-03 266.06 -2.00 20.00 -2.00 319.76 0.00e+00 3.524 0.001 302.00 328.00 3 4.7241e+00 6.3589e-03 3.8165e-02 -6.0000e+00 1.9213e-01 8.1924e-02 7.6080e-03 2.5126e-02 -6.0000e+00 2.0987e-01 -4.0352e-02 7.2501e-03 1.3290e-02 -6.0000e+00 1.2378e-01 1.0352e-02 3.8916e-03 4.1915e-03 -6.0000e+00 5.1995e-02 1.3556e-04 -4.2702e-04 1.3302e-04 4.6548e-05 -6.0000e+00 3.8135e-03 8.1341e-05 -5.8990e-05 12 9 8 11 8 0 11.31 19.75 0.21 0.00008 -0.00313 18 4 1 5 0 2745.620 25.47 19.99 19.75 10.50 17.4 850.26 -63425 -64400 -39595 -11584 -83839 49501 -34086 -22248 4652 -16895 2609 -24084 -17474 -16228 -14230 -7493 -1979 173 -20122 -8793 -3002 3702 -1240 3962 919 -16719 -15830 -5800 -11688 4551 -4400 3632 -1779 2465 494 -4088 5613 1027 1440 -470 -2727 1560 -3344 -1325 331 -893 1258 445 3223 -1423 1473 1878 1542 835 1423 -110 -939 209 -815 -566 2322 -305 2819 308 -503 -256 -535 -1066 -671 -205 -399 33249 909 -129 -476 -15 -1503 -1485 -226 -1949 -134 -1451 -3109 -1595 -2483 -136 124 314 1241 548 -60 -286 -231 -909 -611 -480 -88 810 423 65 -168 -1070 -659 -864 -729 -819 -776 -625 103 173 51 312 132 -363 -298 -180 -275 388 -160 -162 134 645 537 902 596 70 530 618 260 511 158 -209 -485 1574 -256 -217 29 97 -243 -231 -185 -145 -582 -1163 -1369 -697 -149 -2028 308 -525 -343 61 -297 39 -521 -429 -488 -511 -294 -81 8 -1151 -471 -155 179 -65 214 55 -1244 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