File name: Pandora57s1_BoulderCO_20210712_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251209T005045.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210712_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210712T134934.7Z 7863.576096 102 1 50.37 2 68.19 79.15 93.59 61.72 0.00 1 0.00 1 0 25 2.970e-02 1.581e-02 3.147e-02 4.095e-03 3.395321e-01 2.105759e-03 3.953511e-03 -6.000000e+00 1.738565e-02 231.63 -2.00 3.45 -2.00 318.82 0.00e+00 9.766488e-05 4.101747e-04 1.146775e-04 -6.000000e+00 6.899753e-04 281.53 -2.00 20.00 -2.00 318.49 0.00e+00 2.669 0.000 302.00 328.00 3 5.4202e+00 5.7229e-03 2.8308e-02 -6.0000e+00 4.3916e-02 1.7384e-02 6.4652e-03 1.7512e-02 -6.0000e+00 4.7701e-02 1.9318e-02 4.6732e-03 8.7074e-03 -6.0000e+00 2.7960e-02 -1.3679e-02 2.4671e-03 2.5059e-03 -6.0000e+00 1.1533e-02 1.6541e-04 -6.5965e-04 1.2414e-04 2.9276e-05 -6.0000e+00 8.3241e-04 6.7258e-03 -7.5858e-05 12 9 8 11 8 0 59.32 20.34 0.50 0.00673 0.00177 14 3 1 5 0 3596.890 26.00 20.00 20.34 25.15 20.3 832.24 -7972 -2673 -4183 -1109 17089 -7404 9583 -6770 -7156 2479 -1577 -4973 -10795 -2413 -4670 -2729 -1410 4003 -2654 4628 -104 30 3430 3494 -1653 -409 -39 -305 -2834 2165 3802 1536 -4671 -1714 4121 -7004 -2183 -229 -1838 -2771 -788 -774 -1582 252 1863 -2305 42 -366 -99 -1046 -1099 870 921 702 -337 555 520 3 767 170 1177 1124 2097 2129 236 474 131 358 -491 672 37 945 1324 608 450 832 207 285 -663 -1139 -1178 -1204 -2318 -1470 -1732 -200 89 247 562 1094 1935 853 755 1845 763 145 50 893 -338 -711 -714 -1331 -682 -805 -633 -1203 -979 -107 -107 386 -408 -313 -229 103 1 -385 -407 -484 -526 -119 -16 65 414 147 1122 315 886 817 305 9 -363 -566 -699 10129 -637 -676 -642 -496 -812 -323 -403 -519 -701 -326 -115 -189 -46 535 -289 339 -318 -378 126 -85 -292 -769 -185 -426 -273 -149 422 -315 532 -13 4 422 459 -243 -62 -6 -44 -396 289 541 246 -874 -323 696 -1308 -426 -51 -504 -901 -277 -287 -612 97 707 -914 16 -139 -37 -406 -455 382 431 350 -176 296 283 2 408 90 637 655 1324 1444 165 310 81 217 -321 490 30 791 1104 491 337 560 128 168 -416 -812 -952 -1081 -2266 -1393 -1759 -214 100 286 652 1218 1980 872 715 1683 745 147 56 1121 -458 -958 -907 -1566 -746 -898 -760 -1538 -1308 -150 -157 608 -688 -541 -384 162 1 -529 -555 -686 -795 -191 -26 105 645 220 1584 428 1142 1056 424 13 -583 -947 -1200 16210 -1204 -1257 -1226 -967 -1600 -616 -792 -982 -1291 SS 20210712T135558.8Z 7863.580542 105 1 50.65 2 66.99 80.09 92.55 62.74 0.00 1 0.00 1 0 17 2.157e-02 7.559e-03 2.006e-02 3.114e-03 3.278595e-01 1.597656e-03 3.789629e-03 -6.000000e+00 1.262602e-02 231.63 -2.00 3.45 -2.00 318.60 0.00e+00 3.429850e-04 2.928738e-04 1.069072e-04 -6.000000e+00 5.010680e-04 281.53 -2.00 20.00 -2.00 318.27 0.00e+00 2.538 0.000 302.00 328.00 3 5.1736e+00 4.3198e-03 2.7044e-02 -6.0000e+00 3.1893e-02 2.7400e-02 4.8574e-03 1.6817e-02 -6.0000e+00 3.4641e-02 8.6586e-03 3.4052e-03 8.3333e-03 -6.0000e+00 2.0305e-02 -9.9403e-03 1.7927e-03 2.3846e-03 -6.0000e+00 8.3759e-03 2.3849e-04 -3.0899e-04 9.3958e-05 2.7038e-05 -6.0000e+00 6.0447e-04 6.9170e-03 -5.3595e-05 11 8 0 10 0 0 96.70 20.35 0.50 0.00692 0.00460 18 4 1 5 0 2813.220 26.00 20.01 20.35 25.85 20.3 835.62 -4299 -6361 1606 2477 -15177 -2678 -10245 -672 -2415 -1023 -4996 -611 -372 5867 4121 -333 -3274 -1330 1403 744 225 175 1009 238 2985 -2201 -556 297 -746 -846 2269 445 2889 -1976 -1376 -1772 -548 -2030 -1761 -2061 -1524 -146 -1451 -684 -259 -801 -531 -587 -897 -951 611 526 -450 1279 760 1071 1301 -2 -838 1380 2191 1193 2496 2429 168 337 -1401 -696 471 603 498 493 602 -31 266 -189 155 -553 -440 10 -907 -556 -1896 -1548 -1400 -807 -221 371 121 956 1033 1060 -124 696 192 -137 731 796 146 -453 -648 -900 -372 27 -942 -986 -509 -678 -179 28 -166 -18 508 -145 -30 -296 79 240 -216 -49 -291 329 102 488 1012 403 326 528 714 -302 -325 -303 -305 3055 -234 21 -104 24 -483 -107 -496 -281 -562 -203 -339 81 117 -776 -118 -519 -35 -142 -63 -322 -40 -28 477 395 -37 -400 -168 181 100 31 24 143 36 468 -378 -94 47 -113 -140 361 79 549 -408 -268 -342 -115 -504 -524 -721 -584 -58 -604 -286 -108 -336 -220 -239 -364 -393 265 246 -226 670 416 599 740 -1 -476 761 1236 731 1649 1722 122 230 -913 -444 316 457 415 429 523 -26 207 -133 99 -340 -285 7 -752 -510 -1758 -1504 -1452 -891 -255 440 145 1090 1090 1026 -120 654 192 -141 838 1015 199 -616 -833 -1067 -411 30 -1152 -1278 -688 -964 -268 44 -263 -30 796 -230 -44 -408 108 340 -327 -78 -479 531 161 735 1438 550 425 687 993 -457 -523 -505 -520 5240 -411 39 -197 46 -945 -203 -909 -494 -965 SS 20210712T141248.4Z 7863.592227 110 1 49.86 2 63.80 82.57 89.78 65.39 0.00 1 0.00 1 0 17 1.429e-02 7.474e-03 8.706e-03 1.942e-03 2.947865e-01 9.936847e-04 3.466011e-03 -6.000000e+00 8.368586e-03 231.63 -2.00 3.45 -2.00 318.04 0.00e+00 -1.697714e-04 1.565477e-04 7.853583e-05 -6.000000e+00 3.320958e-04 281.53 -2.00 20.00 -2.00 317.71 0.00e+00 2.252 0.000 302.00 328.00 3 4.6674e+00 2.6603e-03 2.4168e-02 -6.0000e+00 2.1139e-02 3.1849e-02 2.9751e-03 1.5181e-02 -6.0000e+00 2.2960e-02 9.7105e-03 1.9303e-03 7.4843e-03 -6.0000e+00 1.3458e-02 -1.2550e-02 9.8994e-04 2.1138e-03 -6.0000e+00 5.5519e-03 5.2411e-04 -1.7865e-04 5.8236e-05 2.4746e-05 -6.0000e+00 4.0061e-04 6.5465e-03 -4.7194e-05 11 8 0 10 0 0 72.93 20.38 0.41 0.00655 0.00520 35 7 1 5 0 1424.280 26.00 20.00 20.38 27.41 20.4 845.04 649 -7604 -3653 -704 -5523 -2582 -4191 703 1983 -947 -71 -520 2371 -2843 1513 -1006 2143 513 -2664 1599 -617 657 31 528 2078 93 1082 -1385 -65 1513 727 1973 239 -463 -3715 -1115 -2140 -657 197 -232 -998 -561 -785 -768 -342 -488 -643 -720 -577 -154 536 101 1136 83 940 1046 598 662 267 908 1055 1584 1643 1714 565 160 274 -279 1135 662 815 -5866 164 747 -212 77 107 -245 -143 -363 -417 -1097 -1673 -1442 -539 -456 31 410 752 616 477 856 467 712 760 391 720 718 12 148 -365 -929 -526 252 -996 -870 -1002 -752 -298 -5 347 74 402 -79 -105 73 15 157 -79 -173 -267 -26 44 -159 846 401 427 638 452 421 53 -61 -396 1540 50 -207 -16 -261 -150 6 -171 -365 -431 42 -588 -278 -54 -398 -176 -310 56 173 -90 -7 -51 256 -373 218 -149 357 82 -462 276 -111 116 6 103 420 20 230 -312 -13 309 159 465 62 -125 -979 -282 -599 -192 69 -95 -452 -265 -383 -379 -168 -239 -310 -341 -269 -72 265 54 636 50 577 657 384 423 168 564 674 1080 1218 1354 451 120 192 -192 818 540 728 -5371 154 671 -179 58 73 -161 -98 -281 -363 -1064 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