File name: Pandora57s1_BoulderCO_20210717_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251209T005328.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210717_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210717 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210717T130530.8Z 7868.545496 79 1 50.05 2 76.95 73.27 147.58 1.07 0.00 1 0.00 1 0 25 1.249e-01 4.418e-03 3.562e-02 1.046e-03 5.382939e-01 5.519808e-04 5.912624e-03 -6.000000e+00 7.323968e-02 231.57 -2.00 3.45 -2.00 320.52 0.00e+00 8.877365e-04 1.778763e-04 3.716839e-04 -6.000000e+00 2.903229e-03 281.88 -2.00 20.00 -2.00 320.21 0.00e+00 4.318 0.001 302.00 328.00 3 1.3537e+00 1.5978e-03 4.5484e-02 -6.0000e+00 1.8498e-01 -1.9624e-02 1.9857e-03 2.8095e-02 -6.0000e+00 2.0083e-01 7.5416e-03 2.0788e-03 1.4722e-02 -6.0000e+00 1.1772e-01 -9.9233e-03 1.0796e-03 4.5823e-03 -6.0000e+00 4.8644e-02 2.0792e-03 -3.2720e-04 3.1475e-05 5.2933e-05 -6.0000e+00 3.4991e-03 -2.0015e-03 1.6707e-05 10 0 0 10 0 0 5.29 21.48 0.26 -0.00200 -0.00446 432 85 1 5 0 115.820 26.83 20.00 21.48 25.97 20.1 832.28 -55784 -39318 -30788 -37841 -40453 -62968 -40179 -40780 -30580 -28423 -34702 -12841 -27110 -13219 -16215 -17159 -167 -11207 258 -8893 -5398 -6913 -5771 -5320 -7785 -1228 -8122 -5218 -6327 -5445 -3256 -897 2612 -4630 -3531 -6024 -2107 -2390 -2000 -190 -1894 -1215 -2246 -856 611 -193 1564 -479 44 51 940 1124 809 1371 727 865 752 383 453 479 1582 1174 2636 1850 752 390 130 340 482 1250 407 624 419 128 379 -612 -744 -814 -473 -292 -733 -600 -2075 -1387 -1204 -650 -172 391 682 729 929 979 427 658 231 445 380 752 210 -108 -167 -834 -548 -157 -705 -1078 -980 -693 -459 289 163 198 93 71 -100 -5 275 260 -88 -164 -323 117 70 150 411 286 172 586 330 295 289 -28 -282 -12 -95 -33 46 63 -105 111 -23 -219 -220 -461 -321 -248 -320 -326 -629 -348 -407 -315 -313 -428 -141 -420 -222 -346 -436 -4 -329 7 -293 -178 -234 -203 -203 -331 -52 -377 -228 -272 -244 -164 -51 165 -337 -247 -430 -159 -215 -219 -22 -256 -175 -344 -133 94 -31 247 -79 7 9 182 241 190 346 196 243 218 112 129 135 455 369 914 717 307 155 50 133 205 603 220 354 238 70 190 -279 -313 -338 -213 -152 -444 -412 -1583 -1115 -1034 -544 -151 353 616 637 824 806 335 515 197 396 387 865 263 -137 -200 -918 -553 -157 -764 -1244 -1188 -891 -634 436 269 316 149 118 -156 -8 403 397 -144 -281 -515 197 114 235 611 410 238 818 507 502 494 -50 -536 -23 -202 -75 107 149 -249 254 -51 -455 -441 SS 20210717T131217.0Z 7868.550197 82 1 49.96 2 75.71 74.27 147.56 4.05 0.00 1 0.00 1 0 25 7.431e-02 4.498e-03 2.040e-02 7.889e-04 4.970272e-01 4.109355e-04 5.506557e-03 -6.000000e+00 4.356704e-02 231.57 -2.00 3.45 -2.00 320.18 0.00e+00 1.090816e-03 1.204698e-04 2.944744e-04 -6.000000e+00 1.726937e-03 281.88 -2.00 20.00 -2.00 319.85 0.00e+00 3.966 0.001 302.00 328.00 3 1.2014e+00 1.1610e-03 4.1769e-02 -6.0000e+00 1.1004e-01 -1.7786e-02 1.3953e-03 2.5719e-02 -6.0000e+00 1.1946e-01 9.8414e-03 1.3632e-03 1.3318e-02 -6.0000e+00 7.0029e-02 -1.0805e-02 7.2033e-04 4.0731e-03 -6.0000e+00 2.8937e-02 3.3381e-03 -3.2601e-04 2.3711e-05 4.5535e-05 -6.0000e+00 2.0814e-03 -1.9926e-03 2.3993e-05 11 1 0 11 8 0 13.32 21.48 0.24 -0.00199 -0.00444 572 113 1 5 0 87.310 26.83 19.99 21.48 26.08 20.1 832.92 -23744 -28153 -8022 -35907 -20152 -26095 -32146 -25090 -23449 -12002 -23703 -9636 -16751 -3618 -6397 -7660 -1617 -8501 -1073 -4994 -2913 -3154 -2197 -3439 -3171 -1568 -4991 -3766 -3693 -3059 -967 -1073 340 -2983 -2328 -3100 -4484 -1008 -1232 -555 -1593 -1366 -1073 -1160 32 -792 -134 -797 -474 364 386 1069 390 1139 707 804 497 20 416 214 1272 1289 2076 1994 929 960 -236 146 726 1122 750 439 523 246 217 -193 -350 -696 -313 -329 -686 -1004 -1745 -1613 -1153 -853 -121 255 501 689 868 707 351 603 381 450 614 664 223 -75 -179 -914 -534 -89 -750 -936 -944 -741 -462 205 198 227 107 104 -94 -7 170 258 12 -53 -398 52 24 223 454 314 354 745 461 250 161 -68 -286 129 -88 -25 -82 56 -97 49 26 -176 -277 -228 -327 -81 -470 -208 -281 -398 -330 -345 -171 -396 -153 -345 -81 -179 -253 -56 -343 -43 -221 -131 -143 -103 -178 -176 -91 -305 -220 -209 -179 -63 -80 28 -275 -207 -275 -444 -114 -154 -82 -269 -247 -203 -225 6 -157 -27 -162 -98 78 90 274 110 343 226 266 170 7 140 71 432 475 846 897 438 437 -105 65 347 610 453 280 333 150 122 -99 -165 -323 -156 -189 -456 -757 -1447 -1297 -987 -779 -116 251 494 657 770 582 298 508 318 424 659 807 295 -100 -226 -1059 -569 -95 -861 -1142 -1210 -1007 -672 299 313 377 177 163 -139 -11 256 402 19 -86 -653 83 38 331 697 463 500 1063 719 399 278 -124 -544 256 -187 -51 -175 122 -213 104 56 -367 -558 SS 20210717T132354.7Z 7868.558272 85 1 50.03 2 73.56 75.99 147.36 9.15 0.00 1 0.00 1 0 25 3.555e-02 4.626e-03 8.530e-03 5.377e-04 4.392497e-01 2.806535e-04 5.009688e-03 -6.000000e+00 2.084215e-02 231.57 -2.00 3.45 -2.00 319.64 0.00e+00 5.834945e-04 7.006547e-05 2.095362e-04 -6.000000e+00 8.261466e-04 281.88 -2.00 20.00 -2.00 319.33 0.00e+00 3.477 0.001 302.00 328.00 3 1.0181e+00 7.8143e-04 3.6812e-02 -6.0000e+00 5.2642e-02 -1.6889e-02 9.0211e-04 2.2768e-02 -6.0000e+00 5.7151e-02 1.1240e-02 7.7424e-04 1.1544e-02 -6.0000e+00 3.3501e-02 -1.1056e-02 4.1413e-04 3.4311e-03 -6.0000e+00 1.3843e-02 6.3287e-03 -2.2915e-04 1.6162e-05 3.9362e-05 -6.0000e+00 9.9569e-04 -2.0734e-03 2.3452e-05 10 0 0 10 0 0 14.56 21.48 0.23 -0.00207 -0.00380 840 166 1 5 0 59.330 26.83 20.01 21.48 26.72 20.2 837.45 -8034 -6704 -13482 -9103 -17826 -10256 -15214 -7472 -10685 -12342 -5651 -11301 -6067 -6555 -1462 -1100 -3129 -2077 -1353 -307 -1841 -947 -910 -2532 -1122 -2686 -1779 -2791 -1859 -1238 -1372 941 -140 -724 -2969 -2107 -2574 -2012 -711 -1373 -933 -1201 -628 -747 -409 -235 -980 -341 -791 -95 539 472 1018 786 925 954 867 147 259 567 716 1619 1935 1866 916 483 168 -353 972 940 531 -122 231 350 -127 77 -361 -430 -199 -670 -606 -1057 -1741 -1570 -996 -752 -243 332 345 645 812 716 401 533 542 272 582 589 202 -74 -348 -896 -666 -3 -854 -920 -899 -787 -315 161 257 254 187 61 -226 139 142 265 48 -39 -341 82 42 113 551 364 404 739 395 346 171 96 -225 175 -137 -60 -20 22 -72 -12 -46 -229 -335 -128 -120 -273 -170 -334 -174 -293 -151 -253 -320 -142 -324 -195 -256 -65 -56 -178 -126 -87 -21 -129 -66 -66 -202 -95 -243 -162 -246 -156 -106 -131 99 -17 -92 -372 -259 -348 -289 -123 -283 -214 -295 -160 -195 -107 -62 -261 -91 -214 -27 161 154 358 297 368 392 366 63 108 234 303 734 968 1022 521 264 88 -186 541 595 373 -83 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