File name: Pandora57s1_BoulderCO_20210818_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251209T010135.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210818_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210818T132113.8Z 7900.556410 88 1 50.17 2 78.65 82.59 149.75 287.80 0.00 1 0.00 1 0 25 2.324e-01 6.347e-03 1.928e-01 3.171e-03 5.912314e-01 1.681338e-03 6.379214e-03 -6.000000e+00 1.354357e-01 230.36 -2.00 3.45 -2.00 320.92 0.00e+00 8.444287e-04 5.965883e-04 4.698623e-04 -6.000000e+00 5.400034e-03 282.03 -2.00 20.00 -2.00 320.59 0.00e+00 4.914 0.002 302.00 328.00 3 2.7077e+00 4.9292e-03 5.0852e-02 -6.0000e+00 3.4106e-01 3.7703e-03 6.4863e-03 3.0880e-02 -6.0000e+00 3.7082e-01 -1.4116e-02 7.3006e-03 1.6713e-02 -6.0000e+00 2.1757e-01 2.3173e-03 3.7262e-03 5.3896e-03 -6.0000e+00 8.9977e-02 3.1770e-04 -5.4064e-04 9.5609e-05 6.0239e-05 -6.0000e+00 6.5129e-03 7.3685e-03 -6.3641e-05 10 0 0 10 0 0 57.41 20.54 0.36 0.00737 0.00331 87 17 1 5 0 576.460 26.11 19.99 20.54 25.43 19.9 811.38 -331 -48630 -22026 44784 -100917 -7181 -152924 -73235 -13659 -102022 -41136 -89748 -36336 -52499 -4667 -28039 -14522 6217 -22889 1495 -23614 4693 -18584 -22025 11564 -23221 -5232 -12087 -13845 -7739 -20312 12549 -5446 7573 -10701 2466 -4578 -6533 7321 -2142 5396 -6570 2520 1333 1468 3560 -3048 2210 -1549 -220 1690 -157 5290 421 1956 -1452 1548 -315 895 2080 1229 2401 2373 2650 1147 137 2108 -790 2567 270 654 728 206 1420 -698 465 -1859 -882 -200 -338 306 -1215 -1311 -1771 -1178 -694 -482 463 -172 1372 742 1434 595 472 906 -385 931 237 164 110 -345 -952 -466 398 -1174 -1064 -800 -1051 -101 -416 356 -114 322 124 -224 491 -42 616 -316 -190 -452 32 32 -129 790 169 558 1373 241 619 89 24 -411 -379 95 -157 291 -183 219 5 -168 -131 -300 -1 -256 -95 138 -874 -24 -2459 -611 -72 -1420 -331 -1332 -393 -844 -58 -520 -265 102 -545 30 -621 94 -500 -674 275 -833 -160 -385 -441 -249 -867 454 -271 354 -582 118 -262 -454 546 -211 556 -821 302 166 185 449 -418 296 -224 -33 280 -27 940 85 416 -334 356 -74 202 460 283 599 668 829 381 45 663 -263 906 112 298 348 98 636 -293 174 -661 -311 -77 -153 160 -736 -870 -1254 -888 -556 -405 397 -148 1126 572 1022 409 330 695 -343 940 274 206 138 -410 -1036 -464 394 -1265 -1213 -958 -1348 -140 -583 544 -184 517 193 -328 743 -64 971 -487 -306 -731 49 48 -205 1188 246 781 1960 384 1008 159 46 -821 -797 212 -371 702 -451 538 13 -379 -279 -620 SS 20210818T132732.1Z 7900.560788 91 1 50.01 2 77.45 83.57 150.83 289.40 0.00 1 0.00 1 0 25 1.342e-01 5.904e-03 1.015e-01 2.245e-03 5.427406e-01 1.190145e-03 6.033174e-03 -6.000000e+00 7.821265e-02 230.36 -2.00 3.45 -2.00 320.57 0.00e+00 1.508394e-03 3.878812e-04 3.761442e-04 -6.000000e+00 3.118414e-03 282.03 -2.00 20.00 -2.00 320.23 0.00e+00 4.478 0.001 302.00 328.00 3 2.5713e+00 3.4355e-03 4.6588e-02 -6.0000e+00 1.9696e-01 1.3917e-03 4.2785e-03 2.8376e-02 -6.0000e+00 2.1414e-01 -5.6575e-03 4.4848e-03 1.4923e-02 -6.0000e+00 1.2565e-01 -1.7823e-03 2.3291e-03 4.6473e-03 -6.0000e+00 5.1961e-02 5.3784e-04 -4.9491e-04 6.7770e-05 5.5121e-05 -6.0000e+00 3.7609e-03 7.4742e-03 -5.1140e-05 10 0 0 10 0 0 92.20 20.54 0.33 0.00747 0.00376 120 24 1 5 0 416.620 26.11 20.00 20.54 26.07 19.8 814.07 -26020 -73294 51216 -40837 -58204 17889 -40194 2752 -57407 -22689 -40860 -8332 -21561 -4981 4885 -25986 14573 -8857 -11399 -39 -16445 -8395 -17274 6566 -7159 7458 -3321 -14841 5759 -12300 12003 -1606 -4152 -1321 -9041 -4845 -6544 2963 -3602 -2139 -1312 -2968 -330 -2604 -109 882 -399 -587 -1418 1909 376 1488 1681 2733 1170 -784 539 -1160 -330 -600 643 1660 1715 2245 -215 1028 -54 214 696 448 1260 6480 1161 -213 -568 -366 -1003 713 -824 215 -465 -1549 -1858 -2311 -1080 -1153 59 314 657 678 477 1237 133 881 169 206 531 529 246 -210 -192 -788 -392 15 -1073 -763 -1054 -632 -386 275 89 8 304 -156 -3 114 251 170 -57 -254 -465 262 190 292 620 266 290 860 321 194 157 3 -321 452 -241 -73 -44 83 -90 -46 132 -420 -107 -160 -834 179 -349 -548 78 -343 17 -754 -229 -519 -86 -312 -76 83 -711 297 -250 -357 -1 -591 -281 -666 217 -293 279 -141 -686 212 -576 510 -91 -275 -91 -647 -333 -507 248 -394 -275 -171 -421 -48 -397 -16 134 -62 -94 -236 325 71 310 381 664 305 -217 151 -331 -91 -165 181 505 585 844 -86 393 -20 82 289 213 657 3359 631 -112 -275 -159 -407 283 -364 109 -276 -1051 -1379 -1828 -903 -1031 55 300 627 624 409 979 101 670 142 196 578 599 302 -258 -223 -914 -418 15 -1242 -933 -1247 -793 -521 406 144 14 510 -251 -5 164 359 253 -90 -423 -781 424 298 441 891 369 388 1169 482 324 284 6 -646 947 -501 -160 -98 189 -207 -102 300 -913 -225 SS 20210818T133259.3Z 7900.564575 94 1 30.00 2 76.41 84.43 151.76 290.86 0.00 1 0.00 1 0 25 9.237e-02 5.420e-03 5.961e-02 2.217e-03 5.072034e-01 1.156069e-03 5.692394e-03 -6.000000e+00 5.381869e-02 230.36 -2.00 3.45 -2.00 320.11 0.00e+00 1.247115e-03 3.360523e-04 2.949587e-04 -6.000000e+00 2.145864e-03 282.03 -2.00 20.00 -2.00 319.79 0.00e+00 4.158 0.001 302.00 328.00 3 2.7070e+00 3.2718e-03 4.3271e-02 -6.0000e+00 1.3553e-01 6.2312e-03 3.9146e-03 2.6252e-02 -6.0000e+00 1.4736e-01 6.9593e-03 3.7877e-03 1.3508e-02 -6.0000e+00 8.6459e-02 -1.1123e-02 2.0011e-03 4.0906e-03 -6.0000e+00 3.5754e-02 6.2516e-04 -4.6202e-04 6.5784e-05 4.7125e-05 -6.0000e+00 2.5881e-03 7.3841e-03 -6.9155e-05 12 1 1 12 1 1 95.19 20.55 0.32 0.00738 0.00391 60 20 1 5 0 488.500 26.11 20.00 20.55 26.44 19.8 816.53 -40395 2318 -50055 -17751 -14867 -26278 -17709 -42959 9982 -34518 1596 -36511 -3567 -15322 -15649 -7616 -11866 -2052 -4937 -2074 -1603 -12543 -3199 -10042 3002 -6406 651 -7578 -10684 6241 -7202 3847 -3462 -2352 -1950 -4545 152 -1355 1428 -907 -1982 -1115 -1699 -268 -1536 1185 -352 -660 125 -1005 1653 348 1917 952 1790 360 221 1676 -215 1032 1029 1775 2312 1141 1683 824 1060 -479 1089 1580 275 -1687 420 782 -488 569 -599 -797 276 -984 -820 -1210 -1913 -1767 -1162 -520 -599 725 313 881 1150 773 946 409 491 346 826 665 65 -124 -372 -799 -640 -266 -825 -1350 -977 -749 -259 176 249 417 5 271 -409 165 117 207 104 -158 -211 -8 42 230 493 605 279 553 108 438 134 -26 -231 300 15 -105 228 -195 -160 -117 -16 -160 -202 -454 20 -757 -188 -141 -278 -188 -669 104 -604 20 -758 -65 -388 -484 -254 -457 -78 -208 -90 -71 -626 -153 -558 158 -391 38 -459 -649 337 -509 281 -308 -219 -175 -418 15 -158 180 -139 -344 -205 -330 -52 -308 235 -72 -137 26 -226 395 93 548 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