File name: Pandora57s1_BoulderCO_20210828_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251209T011115.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210828_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210828T134433.9Z 7910.572615 228 1 49.86 2 75.83 89.41 38.59 238.95 0.00 1 0.00 1 0 17 6.355e-02 4.520e-03 1.535e-02 6.345e-04 4.949409e-01 3.287453e-04 5.541510e-03 -6.000000e+00 3.692205e-02 229.60 -2.00 3.45 -2.00 320.08 0.00e+00 1.023125e-03 9.420585e-05 2.794606e-04 -6.000000e+00 1.476364e-03 281.16 -2.00 20.00 -2.00 319.75 0.00e+00 3.997 0.001 302.00 328.00 3 7.8746e-01 9.1744e-04 4.1678e-02 -6.0000e+00 9.2810e-02 6.7995e-03 1.0975e-03 2.5405e-02 -6.0000e+00 1.0097e-01 3.5013e-03 1.0574e-03 1.3158e-02 -6.0000e+00 5.9278e-02 -9.0798e-03 5.6134e-04 4.0197e-03 -6.0000e+00 2.4550e-02 4.9221e-03 -3.9809e-04 1.9031e-05 4.5909e-05 -6.0000e+00 1.7804e-03 8.2583e-03 -6.1558e-05 11 1 0 11 8 0 22.51 20.49 0.23 0.00826 0.00527 807 159 1 5 0 61.770 26.11 20.00 20.49 27.75 20.0 822.84 -20614 -9415 -29358 -9030 -33238 -21174 -17974 -19229 -14689 -25544 -13117 -18166 -6510 -7773 -7197 -2529 -6201 -755 -3867 -1883 -3623 -2965 -1955 -4175 488 -3311 -2575 -4917 -4953 -1294 -2876 1466 -427 -1528 -3445 -2543 -2080 -1888 -456 -1545 -1229 -1526 -1098 -718 -895 -363 -843 -301 -370 3 917 412 1357 752 683 842 425 227 20 593 581 1624 2282 1725 961 365 78 -300 882 1003 566 581 281 371 4 -126 -379 -475 -88 -522 -470 -1167 -1815 -1539 -1150 -638 -161 300 467 731 878 674 600 519 506 278 782 563 169 -41 -391 -860 -552 -23 -933 -969 -872 -791 -197 160 206 179 125 28 -175 224 118 354 50 -219 -282 76 83 185 522 298 386 812 280 299 88 44 -209 -18 -145 -95 126 41 -114 76 -10 -209 -263 -217 -101 -409 -99 -428 -240 -215 -265 -219 -458 -217 -350 -135 -201 -224 -87 -246 -31 -175 -88 -177 -145 -99 -236 28 -210 -165 -310 -303 -80 -206 116 -39 -148 -328 -240 -216 -232 -61 -249 -221 -294 -220 -146 -185 -76 -178 -64 -81 1 226 112 398 239 229 292 152 81 7 205 208 626 975 814 470 173 36 -140 441 572 357 383 185 232 2 -66 -183 -227 -46 -313 -325 -915 -1427 -1276 -1017 -600 -159 303 471 709 791 564 474 411 435 271 865 705 229 -56 -499 -1006 -596 -25 -1097 -1206 -1140 -1097 -269 239 333 301 207 45 -260 315 165 517 78 -358 -465 122 129 276 742 441 549 1172 411 482 154 81 -401 -36 -288 -198 269 89 -250 162 -19 -434 -531 SS 20210828T135610.0Z 7910.580671 231 1 49.95 2 73.60 91.28 40.46 242.11 0.00 1 0.00 1 0 25 3.182e-02 4.627e-03 6.386e-03 4.470e-04 4.356223e-01 2.297949e-04 4.970443e-03 -6.000000e+00 1.848540e-02 229.60 -2.00 3.45 -2.00 319.52 0.00e+00 6.380152e-04 5.622208e-05 2.000299e-04 -6.000000e+00 7.391449e-04 281.15 -2.00 20.00 -2.00 319.21 0.00e+00 3.487 0.001 302.00 328.00 3 7.0141e-01 6.3657e-04 3.6497e-02 -6.0000e+00 4.6466e-02 6.0660e-03 7.3329e-04 2.2299e-02 -6.0000e+00 5.0551e-02 3.8561e-03 6.1730e-04 1.1269e-02 -6.0000e+00 2.9678e-02 -8.9156e-03 3.3119e-04 3.3278e-03 -6.0000e+00 1.2292e-02 8.6353e-03 -3.5669e-04 1.3411e-05 3.8297e-05 -6.0000e+00 8.9136e-04 7.8541e-03 -6.8590e-05 10 0 0 10 0 0 8.06 20.51 0.23 0.00785 0.00517 1066 211 1 5 0 46.670 26.11 20.00 20.51 28.53 20.1 827.28 -7679 -12872 -8339 -11998 -11154 -9810 -11879 -8983 -9186 -8539 -10745 -7716 -5876 -4288 -2868 -2889 -1074 -1366 -1409 -943 -1230 -240 -874 -972 -1309 -1354 -2153 -2403 -1662 -1070 151 313 633 -1155 -2800 -2237 -2489 -1018 -737 -945 -1051 -1053 -941 -985 -142 -388 -538 -845 -853 223 551 659 1013 907 779 949 777 307 390 595 1030 1637 2036 1808 560 451 -152 -219 803 741 505 -4 247 125 84 -185 -351 -395 -168 -463 -682 -1036 -1880 -1553 -1027 -732 -215 164 343 535 758 658 478 612 531 324 707 600 192 -116 -380 -920 -434 -43 -927 -898 -866 -744 -300 183 227 186 167 20 -115 151 193 296 88 -130 -282 122 -14 164 540 285 445 740 333 301 129 24 -256 273 -161 -138 36 20 -130 36 -46 -220 -283 -139 -277 -180 -257 -217 -186 -249 -208 -239 -237 -314 -238 -211 -183 -144 -166 -66 -91 -99 -70 -93 -18 -69 -83 -121 -131 -212 -227 -150 -99 15 36 81 -158 -373 -295 -363 -157 -137 -209 -259 -275 -256 -273 -39 -108 -151 -238 -244 66 175 228 377 362 326 410 344 136 170 256 456 781 1071 1038 332 255 -83 -120 469 493 339 -3 174 84 57 -113 -197 -217 -99 -314 -486 -831 -1645 -1431 -1007 -765 -235 185 386 578 760 609 416 527 493 339 834 734 253 -152 -471 -1050 -497 -49 -1074 -1101 -1115 -1012 -434 287 354 302 266 33 -174 216 275 438 140 -216 -476 201 -22 252 789 400 597 1005 492 488 209 40 -449 500 -315 -285 77 40 -263 76 -91 -423 -528 SS 20210828T140813.2Z 7910.589041 234 1 50.16 2 71.30 93.25 42.47 245.18 0.00 1 0.00 1 0 17 2.053e-02 4.931e-03 3.114e-03 3.407e-04 3.870256e-01 1.724538e-04 4.436751e-03 -6.000000e+00 1.192784e-02 229.60 -2.00 3.45 -2.00 319.01 0.00e+00 5.511695e-04 3.640253e-05 1.445760e-04 -6.000000e+00 4.769248e-04 281.15 -2.00 20.00 -2.00 318.69 0.00e+00 3.082 0.000 302.00 328.00 3 6.0820e-01 4.6979e-04 3.2246e-02 -6.0000e+00 2.9982e-02 5.8854e-03 5.3367e-04 1.9637e-02 -6.0000e+00 3.2618e-02 3.7730e-03 4.0587e-04 9.8420e-03 -6.0000e+00 1.9149e-02 -8.3089e-03 2.1755e-04 2.8721e-03 -6.0000e+00 7.9315e-03 1.3934e-02 -2.9854e-04 1.0185e-05 3.1445e-05 -6.0000e+00 5.7511e-04 7.5418e-03 -6.5046e-05 10 0 0 10 0 0 25.66 20.53 0.24 0.00754 0.00530 1420 281 1 5 0 34.970 26.11 20.00 20.53 29.59 20.2 833.53 -4684 -4198 -6214 -7520 -9759 -7507 -7280 -4087 -3329 -6765 -5793 -5785 -3030 -1715 -1421 -1548 -1781 -1046 -976 120 -298 -226 136 -633 -159 -993 -1200 -1690 -1149 167 387 1215 709 -1152 -2612 -2438 -2021 -1204 -525 -755 -1126 -929 -902 -698 -355 -411 -615 -291 -388 43 839 664 985 807 742 936 748 450 269 612 1092 1558 1928 1523 475 162 -179 -271 790 841 497 407 189 211 -42 -179 -342 -412 -87 -521 -640 -1216 -1941 -1537 -1022 -752 -250 186 280 500 723 497 470 592 519 394 670 606 198 -64 -396 -908 -539 -73 -881 -938 -808 -728 -262 161 191 195 161 36 -210 164 178 313 80 -95 -262 127 3 187 571 400 519 833 411 380 156 34 -189 180 -71 -116 52 -6 -151 -30 -67 -271 -376 -141 -141 -222 -258 -312 -230 -240 -147 -134 -299 -259 -277 -165 -110 -107 -132 -163 -101 -100 13 -32 -25 15 -77 -21 -123 -165 -223 -144 21 53 186 110 -189 -456 -422 -348 -242 -126 -215 -356 -310 -312 -245 -125 -145 -217 -102 -136 15 322 278 440 385 370 480 393 236 139 312 572 878 1192 937 299 106 -112 -168 520 575 375 321 149 159 -29 -113 -216 -252 -56 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