File name: Pandora57s1_BoulderCO_20210908_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251209T011116.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20210908_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20210908 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210908T133948.8Z 7921.569315 66 1 50.81 2 78.61 92.42 97.40 82.54 0.00 1 0.00 1 0 25 3.395e-01 8.152e-03 2.456e-01 5.899e-03 5.630701e-01 3.139379e-03 6.150988e-03 -6.000000e+00 1.965141e-01 228.76 -2.00 3.45 -2.00 320.85 0.00e+00 2.480839e-03 1.096613e-03 4.320176e-04 -6.000000e+00 7.959901e-03 280.20 -2.00 20.00 -2.00 320.52 0.00e+00 4.898 0.002 302.00 328.00 3 3.7475e+00 9.1393e-03 4.9675e-02 -6.0000e+00 4.9298e-01 1.9492e-02 1.1787e-02 2.9217e-02 -6.0000e+00 5.3680e-01 -2.7835e-02 1.2985e-02 1.5740e-02 -6.0000e+00 3.1555e-01 2.6750e-03 6.6586e-03 5.0694e-03 -6.0000e+00 1.3166e-01 1.1805e-04 -7.9429e-04 1.8019e-04 5.8024e-05 -6.0000e+00 9.5107e-03 1.1466e-02 -8.3506e-05 11 8 0 10 0 0 88.84 20.12 0.45 0.01147 0.00550 35 7 1 5 0 1451.400 25.79 20.00 20.12 21.06 19.3 785.14 -100551 900000 -96302 61652 -131508 -62615 -86038 235905 109337 -84301 81887 -63151 24725 -17660 -60202 52890 -14097 20077 -53100 2755 -17909 -42420 31921 -38707 15613 -32497 -5395 -4009 -14950 9206 -22281 6988 -5524 -329 -1134 -9085 7022 -2936 -5207 -1530 6941 -1982 135 11466 -3497 -2284 -5287 751 7010 -233 4791 -4993 7893 4098 1632 1671 -1425 3274 2500 3898 -2753 1302 3076 855 4856 -1585 899 1744 -309 3938 -283 709 210 -152 482 -477 11 -402 2364 -2228 -850 -1984 -398 -891 -955 -225 -1183 360 123 79 615 -915 -26 48 611 -213 1012 1537 -256 573 -317 -263 -1401 -810 19 -997 -19 -1720 217 -290 -92 31 -335 16 -526 855 656 115 23 -322 -31 -57 321 -7 1043 421 658 1644 -353 570 194 -419 -561 697 -139 -139 68 -293 -389 109 142 484 -664 -934 900000 -1065 355 -1862 -443 -838 1357 629 -1119 471 -878 178 -245 -1465 532 -311 346 -1903 65 -491 -1502 612 -1507 412 -1352 -189 -135 -552 287 -1111 305 -288 -19 -63 -549 401 -203 -449 -152 709 -238 17 1299 -467 -308 -749 103 934 -35 765 -976 1481 865 373 397 -359 785 591 900 -705 351 919 290 1644 -555 301 592 -117 1638 -135 351 103 -71 207 -186 4 -146 921 -1063 -464 -1241 -268 -639 -732 -183 -1022 315 108 67 483 -679 -18 34 475 -191 1028 1764 -300 716 -377 -284 -1412 -816 20 -1144 -23 -2234 278 -412 -142 51 -544 25 -773 1182 909 167 35 -522 -50 -90 486 -11 1557 608 917 2331 -564 933 347 -800 -1121 1449 -310 -329 165 -722 -962 260 321 1032 -1387 SS 20210908T134624.7Z 7921.573897 69 1 50.52 2 77.35 93.49 96.21 83.60 0.00 1 0.00 1 0 17 1.721e-01 5.971e-03 1.968e-01 4.136e-03 5.171862e-01 2.169916e-03 5.714413e-03 -6.000000e+00 9.965960e-02 228.76 -2.00 3.45 -2.00 320.54 0.00e+00 1.404119e-03 7.075500e-04 3.496012e-04 -6.000000e+00 3.997899e-03 280.20 -2.00 20.00 -2.00 320.21 0.00e+00 4.445 0.001 302.00 328.00 3 3.6632e+00 6.2325e-03 4.5228e-02 -6.0000e+00 2.5001e-01 -1.2376e-02 7.7613e-03 2.6678e-02 -6.0000e+00 2.7221e-01 2.2679e-02 8.1744e-03 1.4145e-02 -6.0000e+00 1.5991e-01 -2.1434e-02 4.2609e-03 4.4710e-03 -6.0000e+00 6.6312e-02 1.9389e-04 -3.8501e-04 1.2614e-04 5.0895e-05 -6.0000e+00 4.8215e-03 1.0870e-02 -7.7745e-05 10 0 0 10 0 0 84.75 20.13 0.36 0.01087 0.00798 45 9 1 5 0 1122.360 25.79 20.00 20.13 21.63 19.3 788.01 38102 -89135 47938 -86194 3489 -41763 -23205 50075 -50256 -33069 -63231 62770 17491 -7055 42688 -24038 24363 -7151 -3499 -1711 -17785 -4666 5340 5737 -15429 9412 -9006 -8071 8651 -778 -806 -3114 10272 3450 -4082 -5808 -9924 -823 -6290 5 -4257 -752 807 -2389 4783 274 -946 22 -723 -785 -1692 3580 2922 3946 -330 1479 454 -156 492 -157 1328 547 1539 1879 -676 682 -413 500 1202 795 753 342 263 -339 815 -1508 -1058 -927 -719 -817 -1200 -1912 -1231 -877 -367 -422 473 390 945 81 1396 445 140 818 626 440 805 867 -177 60 219 -1170 -188 -458 -1058 -1229 -1212 -604 -635 331 36 65 25 -115 211 -44 -33 279 214 196 151 161 -70 69 261 40 587 673 930 247 672 -139 -183 -1242 -84 87 148 182 -78 -21 106 -126 -219 154 -1209 193 -1169 20 -371 -187 222 -689 -414 -1122 354 190 -122 551 -708 491 -216 -110 -56 -639 -164 179 208 -679 376 -440 -378 335 -35 -42 -192 630 218 -268 -390 -771 -69 -685 1 -606 -111 122 -384 724 44 -156 4 -125 -144 -343 761 680 982 -90 414 132 -46 140 -45 385 175 545 731 -278 267 -159 194 506 384 400 191 146 -180 394 -672 -435 -379 -321 -424 -721 -1307 -909 -684 -305 -374 438 373 897 74 1183 354 106 618 518 415 864 1051 -214 72 270 -1330 -196 -484 -1209 -1489 -1545 -815 -847 479 57 107 41 -180 307 -61 -47 404 329 316 245 254 -107 101 367 59 830 975 1356 400 1176 -259 -355 -2560 -181 198 346 434 -187 -49 234 -265 -448 SS 20210908T135206.4Z 7921.577852 72 1 50.01 2 76.26 94.42 95.18 84.51 0.00 1 0.00 1 0 25 6.979e-02 4.685e-03 6.610e-02 2.534e-03 4.848367e-01 1.321341e-03 5.417640e-03 -6.000000e+00 4.040598e-02 228.76 -2.00 3.45 -2.00 320.31 0.00e+00 1.117042e-03 4.003459e-04 2.887678e-04 -6.000000e+00 1.620916e-03 280.20 -2.00 20.00 -2.00 319.97 0.00e+00 4.116 0.001 302.00 328.00 3 3.1810e+00 3.7489e-03 4.2027e-02 -6.0000e+00 1.0136e-01 -9.6638e-03 4.5150e-03 2.4848e-02 -6.0000e+00 1.1036e-01 3.4937e-03 4.4304e-03 1.2970e-02 -6.0000e+00 6.4835e-02 -9.5865e-03 2.3414e-03 4.0254e-03 -6.0000e+00 2.6885e-02 4.2316e-04 -4.8142e-04 7.7772e-05 4.5967e-05 -6.0000e+00 1.9548e-03 1.0942e-02 -7.7807e-05 11 1 0 11 8 0 -8.30 20.13 0.39 0.01094 0.00732 83 16 1 5 0 602.430 25.79 20.00 20.13 22.06 19.4 791.11 -29263 -20467 -32834 -14425 -15464 -27614 -21216 -20105 20177 -9543 -10559 -19649 -15661 -14903 -4910 5610 -14742 2546 -4894 -4855 98 -6656 8165 -4676 -216 -5383 132 -4925 -6177 15 150 -3086 -981 -5447 -661 -6741 572 -4438 -646 -3022 -1480 -2517 -2173 121 403 84 -329 -2671 1417 773 1712 607 2053 1057 638 864 -559 603 1415 400 972 684 2084 2172 1992 -200 1018 -129 108 1609 217 734 344 659 -381 -695 222 -295 612 -986 -540 -1370 -2075 -1559 -815 -402 -169 395 399 375 922 968 680 723 306 534 323 626 31 -10 -433 -985 -399 -315 -816 -897 -803 -693 -341 469 48 195 226 120 -176 208 33 51 13 -149 53 15 -121 83 413 236 366 1036 66 279 141 5 -3 -26 31 -107 107 -32 -141 -27 -20 -101 -271 -318 -233 -446 -157 -157 -314 -246 -263 199 -137 -159 -359 -333 -387 -140 166 -590 93 -207 -216 4 -313 347 -245 -12 -322 8 -286 -353 1 10 -234 -82 -502 -56 -606 53 -512 -87 -497 -243 -446 -401 22 75 16 -63 -530 304 159 381 150 543 304 194 272 -183 195 444 126 315 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