File name: Pandora57s1_BoulderCO_20211011_L2Fit_fout2c2d20201015p1-8.txt File generation date: 20251209T013017.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Glen McConville Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 57 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora57_OF_v2d20200724.txt Instrument calibration file used: Pandora57s1_CF_v2d20201015.txt Level 1 file used: Pandora57s1_BoulderCO_20211011_L1_smca1c2d20201015p1-8.txt Full location name: Boulder, CO Short location name: BoulderCO Country of location: USA Location latitude [deg]: 39.9900 Location longitude [deg]: -105.2600 Location altitude [m]: 1660 Local noon date: 20211011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.0615 305.2022 305.3429 305.4836 305.6243 305.7650 305.9056 306.0463 306.1869 306.3275 306.4681 306.6087 306.7493 306.8899 307.0305 307.1710 307.3116 307.4521 307.5926 307.7331 307.8736 308.0141 308.1546 308.2950 308.4355 308.5759 308.7164 308.8568 308.9972 309.1376 309.2780 309.4183 309.5587 309.6990 309.8394 309.9797 310.1200 310.2603 310.4006 310.5409 310.6811 310.8214 310.9616 311.1019 311.2421 311.3823 311.5225 311.6627 311.8029 311.9430 312.0832 312.2233 312.3635 312.5036 312.6437 312.7838 312.9239 313.0639 313.2040 313.3440 313.4841 313.6241 313.7641 313.9041 314.0441 314.1841 314.3241 314.4640 314.6040 314.7439 314.8838 315.0237 315.1636 315.3035 315.4434 315.5833 315.7231 315.8630 316.0028 316.1426 316.2824 316.4222 316.5620 316.7018 316.8415 316.9813 317.1210 317.2607 317.4004 317.5401 317.6798 317.8195 317.9592 318.0988 318.2385 318.3781 318.5177 318.6573 318.7969 318.9365 319.0761 319.2157 319.3552 319.4948 319.6343 319.7738 319.9133 320.0528 320.1923 320.3318 320.4712 320.6107 320.7501 320.8895 321.0289 321.1683 321.3077 321.4471 321.5865 321.7258 321.8652 322.0045 322.1438 322.2831 322.4224 322.5617 322.7010 322.8402 322.9795 323.1187 323.2579 323.3971 323.5363 323.6755 323.8147 323.9539 324.0930 324.2322 324.3713 324.5104 324.6495 324.7886 324.9277 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211011T134040.3Z 7954.569911 50 1 50.48 2 84.66 104.10 149.80 72.09 0.00 1 0.00 1 0 17 5.918e-01 6.732e-02 4.572e-01 2.702e-02 9.082626e-01 1.693186e-02 9.607505e-03 -6.000000e+00 3.664462e-01 225.58 -2.00 3.45 -2.00 322.27 0.00e+00 1.564214e-03 7.786748e-03 1.281228e-03 -6.000000e+00 2.302709e-02 276.16 -2.00 20.00 -2.00 321.91 0.00e+00 9.398 0.014 302.00 328.00 3 1.7624e+00 5.6935e-02 9.0989e-02 -6.0000e+00 9.3788e-01 9.7168e-01 7.6900e-02 4.6681e-02 -6.0000e+00 1.0368e+00 -1.2920e+00 7.9360e-02 2.4506e-02 -6.0000e+00 5.8212e-01 5.2733e-01 3.8166e-02 8.2904e-03 -6.0000e+00 2.4347e-01 1.6321e-05 -3.3665e-03 8.6848e-04 1.4257e-04 -6.0000e+00 1.9320e-02 1.9753e-02 -1.1217e-04 12 9 8 11 8 0 98.11 19.38 0.82 0.01975 -0.00554 22 4 1 5 0 2294.100 25.28 20.00 19.38 12.87 18.8 777.46 900000 58274 -219337 900000 -129527 900000 900000 900000 900000 900000 900000 900000 900000 900000 45920 900000 48148 900000 39157 900000 -26448 900000 900000 900000 900000 -30094 900000 -11400 900000 900000 -17255 900000 123879 900000 900000 900000 900000 96864 900000 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-9.6038e-04 1.5008e-04 1.0170e-04 -6.0000e+00 1.6642e-02 1.9072e-02 -1.3240e-04 11 8 0 10 0 0 97.60 19.39 0.32 0.01907 0.01186 94 19 1 5 0 530.260 25.28 20.00 19.39 14.55 19.0 787.99 -233798 900000 -106619 900000 -252975 900000 -285305 -157264 -166311 -215220 900000 -223125 -88250 -78919 117971 900000 -102370 -52902 -48813 -42619 -109146 -69427 69047 -75495 -21392 -4865 -21396 -18279 -56587 2071 -34938 12968 -28822 -17502 -19827 -739 -21370 -27085 -5543 -10588 -816 7502 -9557 15519 -7354 -3108 8570 -544 4751 494 2270 -1502 6873 8181 4677 5568 -3107 1762 -3336 4036 -1839 2081 6641 3356 1305 293 2005 1481 3087 4795 2866 7114 2539 2192 -349 -733 -48 -599 830 605 -471 -1239 -1427 -1701 -809 -200 -351 526 1036 143 771 -158 -148 98 -612 561 372 839 -41 241 131 -1300 -838 -1303 -799 -2003 -603 -1616 -464 11 80 -153 297 184 -344 576 -383 484 -207 -262 -322 -10 476 383 730 886 672 1168 451 405 -249 -447 161 180 80 -498 201 -93 -119 183 85 35 -601 -1166 900000 -532 900000 -1682 900000 -2964 -784 -829 -1756 900000 -2630 -440 -393 588 900000 -1206 -432 -420 -367 -1880 -818 344 -1129 -204 -42 -223 -182 -846 20 -602 170 -679 -397 -449 -14 -562 -909 -186 -451 -36 330 -529 689 -420 -176 451 -33 297 36 183 -131 614 795 505 627 -394 212 -409 453 -228 277 977 583 247 56 383 302 694 1223 822 2034 746 605 -90 -170 -11 -138 217 191 -178 -545 -694 -884 -446 -116 -214 326 636 85 425 -83 -77 54 -385 410 319 828 -44 261 133 -1203 -700 -1089 -709 -1898 -597 -1752 -552 14 111 -229 450 273 -488 782 -530 693 -315 -409 -494 -14 720 560 1021 1199 891 1630 724 685 -471 -919 349 417 198 -1303 534 -251 -318 467 202 78 -1301 SS 20211011T141139.5Z 7954.591429 58 1 50.14 2 78.98 109.33 144.39 79.06 0.00 1 0.00 1 0 17 2.011e-01 4.618e-03 1.381e-01 1.813e-03 6.071587e-01 9.540582e-04 6.651116e-03 -6.000000e+00 1.149460e-01 225.58 -2.00 3.45 -2.00 320.86 0.00e+00 1.777696e-03 3.437644e-04 5.085139e-04 -6.000000e+00 4.667867e-03 276.16 -2.00 20.00 -2.00 320.54 0.00e+00 5.053 0.002 302.00 328.00 3 1.6561e+00 2.8019e-03 5.1734e-02 -6.0000e+00 2.8624e-01 1.4818e-02 3.7161e-03 3.1326e-02 -6.0000e+00 3.1252e-01 3.9611e-03 4.2352e-03 1.7053e-02 -6.0000e+00 1.8404e-01 -1.0268e-02 2.1520e-03 5.5350e-03 -6.0000e+00 7.6716e-02 8.1138e-04 -5.9832e-04 5.3894e-05 6.9008e-05 -6.0000e+00 5.6278e-03 1.8989e-02 -1.0945e-04 11 1 0 11 8 0 98.67 19.40 0.27 0.01899 0.01449 226 45 1 5 0 221.810 25.28 19.99 19.40 17.15 18.9 802.90 84792 -92270 -23183 -63653 -76381 -11598 -99748 18004 -91873 -6863 -51304 -52915 -13003 -40813 -7344 -31442 -5820 -18225 -8233 -11885 -4863 -3305 -12791 -1971 -7654 -8555 -4273 -18017 -6724 -10074 2697 -5885 -2343 936 -10175 -1280 -4273 88 -818 -3456 -592 -2491 1717 -2215 -1519 -1569 -1679 386 -2354 717 -93 2223 1583 1035 2340 916 782 -565 639 363 257 2862 1845 2650 1385 969 243 -657 1917 917 1266 88 650 469 -909 -226 -1664 -597 -882 -167 -399 -1532 -1368 -1863 -530 -684 34 355 580 875 712 609 -214 578 360 198 1132 505 423 -119 -263 -874 -471 -168 -1181 -875 -929 -658 -169 225 235 -77 229 -132 25 179 132 380 -84 -88 -215 119 60 113 571 16 629 572 62 348 -183 84 -464 172 -262 -200 85 121 -49 78 152 -85 -239 150 -669 -90 -360 -459 -37 -847 54 -942 -33 -408 -496 -103 -548 -88 -573 -93 -364 -162 -256 -101 -68 -310 -47 -210 -251 -122 -577 -191 -324 91 -255 -113 46 -543 -63 -244 6 -66 -313 -58 -270 188 -258 -179 -189 -207 48 -317 101 -15 382 300 214 507 210 185 -135 147 83 61 731 539 856 471 323 81 -227 715 396 598 44 317 217 -389 -87 -605 -218 -361 -80 -222 -982 -954 -1386 -416 -573 29 317 515 743 564 452 -154 423 294 187 1111 568 512 -144 -298 -905 -488 -175 -1220 -952 -1067 -807 -225 332 380 -131 386 -215 38 261 193 580 -137 -149 -361 193 94 170 819 22 841 795 96 603 -347 169 -908 354 -576 -463 202 291 -118 180 329 -176 -518 SS 20211011T141816.7Z 7954.596027 61 1 50.01 2 77.79 110.49 143.21 80.38 0.00 1 0.00 1 0 25 1.275e-01 4.449e-03 4.294e-02 1.140e-03 5.586050e-01 5.865270e-04 6.153311e-03 -6.000000e+00 7.285182e-02 225.58 -2.00 3.45 -2.00 320.53 0.00e+00 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