File name: Pandora21s1_Bremen_20191227_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240829T094227.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v2d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20191227_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20191227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20191227T093242.5Z 7300.397714 652 1 51.00 2 80.25 153.85 85.95 140.36 0.00 1 0.00 1 0 25 5.510e-01 2.957e-02 3.759e-01 1.975e-02 8.551911e-01 1.172737e-02 1.066452e-02 -6.000000e+00 3.254860e-01 220.50 -2.00 3.88 -2.00 321.86 0.00e+00 1.569492e-02 5.028160e-03 1.093665e-03 -6.000000e+00 1.767027e-02 266.84 -2.00 20.00 -2.00 321.50 0.00e+00 5.646 0.004 302.00 328.00 3 3.3529e+00 3.6727e-02 7.4272e-02 -6.0000e+00 8.0648e-01 5.8790e-01 5.0753e-02 4.9736e-02 -6.0000e+00 8.8968e-01 -8.1224e-01 5.5940e-02 2.7661e-02 -6.0000e+00 5.2294e-01 3.7139e-01 2.7657e-02 9.2586e-03 -6.0000e+00 2.1996e-01 2.5833e-05 -7.1205e-03 6.0896e-04 1.5151e-04 -6.0000e+00 1.7889e-02 1.4019e-02 -8.9144e-04 12 8 8 10 0 0 99.99 22.32 0.30 0.01402 -0.03949 77 15 1 5 0 653.320 25.28 20.00 22.32 11.56 23.60 13.3 992.79 -168166 900000 900000 -43265 70548 900000 -298216 900000 -128205 900000 900000 900000 900000 900000 900000 900000 170240 900000 900000 22284 900000 228203 15903 211741 42440 900000 -58415 900000 1026 95882 900000 5999 35099 -12744 84070 47082 900000 -12168 74073 11234 11509 62470 18507 18406 97180 81893 14533 81508 48645 28900 28635 10687 115953 23079 37801 56838 33754 9267 12484 194 67647 20248 8304 26094 7521 18009 -447 11204 -5119 20201 4700 4817 2748 -3779 25036 -4885 19813 1576 15237 2812 366 -2328 -6368 -2099 -1463 104 -4163 1466 -6520 -1362 -2928 -3702 1637 346 -3019 -2917 -245 -2215 -1212 1003 134 127 -5356 1531 236 -3644 -4806 1476 -2672 -341 -2105 -1491 -37 -40 -417 -1271 1857 -15 433 742 1644 775 1513 2716 -528 2988 3388 2426 1730 -440 290 2382 -540 -507 -174 -82 585 -357 -188 -137 89 -1038 -1685 -4299 900000 900000 -830 1354 900000 -19380 900000 -2460 900000 900000 900000 900000 900000 900000 900000 3267 900000 900000 428 900000 4379 305 4063 814 900000 -1987 900000 23 1840 900000 214 1097 -602 1731 1315 900000 -657 2246 629 691 2613 1149 1176 3362 3320 1059 3641 3017 2264 2457 1159 5744 2564 3831 4994 3568 1172 1496 26 5363 2611 1337 4020 1436 3180 -94 2237 -1293 4541 1292 1352 762 -1036 4878 -1130 3593 353 3469 844 131 -962 -2974 -999 -729 54 -2322 792 -3764 -723 -1492 -1810 756 172 -1760 -1992 -191 -2016 -1190 976 124 106 -4298 1128 184 -3102 -4377 1368 -2866 -405 -2856 -2166 -54 -59 -586 -1754 2501 -21 641 1120 2416 1096 2031 3491 -678 3603 4015 3052 2478 -736 537 4677 -1160 -1157 -419 -205 1492 -924 -481 -335 202 -2222 -3465 SS 20191227T094231.4Z 7300.404531 658 1 50.88 2 79.63 156.05 85.06 142.35 0.00 1 0.00 1 0 25 6.607e-01 1.036e-02 2.580e-01 3.985e-03 8.306742e-01 2.222476e-03 1.002039e-02 -6.000000e+00 3.806800e-01 220.50 -2.00 3.88 -2.00 321.80 0.00e+00 5.635011e-03 9.763921e-04 1.175315e-03 -6.000000e+00 1.609196e-02 266.84 -2.00 20.00 -2.00 321.46 0.00e+00 5.336 0.003 302.00 328.00 3 1.5339e+00 7.0141e-03 7.1041e-02 -6.0000e+00 9.3672e-01 1.2435e-01 1.1184e-02 4.9231e-02 -6.0000e+00 1.0255e+00 -1.6722e-01 1.3938e-02 2.9091e-02 -6.0000e+00 6.0663e-01 7.1799e-02 6.6517e-03 1.0206e-02 -6.0000e+00 2.5574e-01 2.4893e-04 -2.4925e-03 1.1837e-04 1.4527e-04 -6.0000e+00 1.9908e-02 7.9848e-03 -1.2131e-04 12 8 8 10 0 0 99.98 22.32 0.23 0.00798 -0.01074 282 55 1 5 0 177.864 25.28 20.00 22.32 11.85 24.10 13.4 993.86 -308581 900000 -247830 -67873 -254255 -269708 -9101 -284233 -170966 -225597 -15053 -221705 900000 -135081 -6180 -90607 54030 -30616 -87939 6157 -116343 2242 -91469 68381 -36190 -12241 16469 -26275 -2577 -41288 11643 -23393 36235 -20789 26132 20123 13615 7998 6960 17827 4234 29322 -781 21276 -1155 -354 6602 2973 18587 5374 19478 5654 17160 4883 10336 7119 4187 -1014 5301 6327 873 5867 1087 8841 2738 4575 4579 2854 3795 2036 3699 -2388 4126 200 2553 1025 2424 -1042 1114 674 -731 -617 -2830 -1118 -1664 191 -1538 -297 41 726 1136 823 1668 -573 257 -581 76 -286 -309 -400 -94 0 -355 -356 -2562 -1079 -1457 -441 -340 18 -172 -405 447 -355 472 192 899 201 -395 -844 -84 370 -328 629 47 1036 1202 1342 174 281 305 279 561 -53 -318 -359 218 -334 -76 173 -107 -104 -424 -3939 900000 -2296 -264 -2356 -2769 -35 -4181 -971 -2427 -58 -3076 900000 -1574 -28 -1083 210 -265 -1367 42 -2411 17 -1726 332 -498 -139 143 -353 -29 -756 170 -558 553 -555 464 391 317 222 238 646 186 1162 -42 940 -66 -21 383 181 1119 387 1384 494 1489 524 1120 833 515 -130 621 729 112 803 171 1463 516 861 883 599 887 551 1074 -723 1203 56 639 236 531 -251 304 222 -275 -267 -1380 -573 -912 109 -929 -181 25 416 611 422 842 -316 161 -432 66 -285 -319 -418 -96 0 -298 -295 -2275 -999 -1437 -466 -400 23 -246 -625 699 -550 697 276 1286 300 -621 -1363 -131 553 -472 907 66 1391 1585 1865 265 490 594 590 1259 -128 -820 -926 572 -889 -199 454 -264 -238 -937 SS 20191227T094708.7Z 7300.407739 661 1 27.38 2 79.35 157.09 84.65 143.30 0.00 1 0.00 1 0 25 5.660e-01 9.195e-03 2.966e-01 5.097e-03 8.169574e-01 2.828719e-03 9.888183e-03 -6.000000e+00 3.299565e-01 220.50 -2.00 3.88 -2.00 321.65 0.00e+00 4.683215e-03 1.204485e-03 1.101453e-03 -6.000000e+00 1.386686e-02 266.84 -2.00 20.00 -2.00 321.31 0.00e+00 5.210 0.003 302.00 328.00 3 1.9561e+00 8.7686e-03 6.9463e-02 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