File name: Pandora21s1_Bremen_20200320_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T024846.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v2d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200320_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200320T081827.3Z 7384.346149 517 1 50.58 2 66.44 125.31 73.52 172.53 0.00 1 0.00 1 0 25 2.095e-02 4.721e-03 1.551e-02 1.720e-03 3.784240e-01 8.848196e-04 4.958831e-03 -6.000000e+00 1.232260e-02 225.50 -2.00 3.88 -2.00 319.04 0.00e+00 3.825493e-04 1.899977e-04 1.651602e-04 -6.000000e+00 5.014495e-04 269.01 -2.00 20.00 -2.00 318.73 0.00e+00 2.484 0.000 302.00 328.00 3 3.9396e+00 2.3937e-03 3.2706e-02 -6.0000e+00 3.0660e-02 2.9339e-02 2.7241e-03 2.1347e-02 -6.0000e+00 3.3425e-02 6.5835e-04 2.0708e-03 1.0854e-02 -6.0000e+00 1.9681e-02 -5.8439e-03 1.1086e-03 3.2203e-03 -6.0000e+00 8.1725e-03 5.4006e-04 -9.4130e-05 5.4168e-05 3.9914e-05 -6.0000e+00 6.2982e-04 -2.9089e-04 1.3829e-04 10 0 0 10 0 0 99.98 22.48 0.20 -0.00029 -0.00100 78 15 1 5 0 640.181 25.39 19.99 22.48 14.34 25.10 15.4 1005.83 -5402 -4011 -8342 1886 -5669 4589 -7539 10478 -4847 6613 -4500 1389 2011 -2825 1663 -3662 -49 -3952 2535 -4106 -241 -1935 1384 -676 -2639 1202 -3222 822 -2419 2026 -935 2053 -1144 -3729 -807 -836 1082 -670 98 -1043 -205 -1801 -899 -669 -1166 -187 -922 -41 -1074 849 1052 918 958 529 1087 536 652 -145 499 711 1341 1724 857 777 231 635 -517 1710 705 500 8 58 -80 -128 116 -86 146 247 592 -402 -271 -1097 -1037 -1254 -1030 -916 -538 -230 -106 4 219 886 1061 1087 959 633 841 68 -242 -362 -266 -482 99 -221 -726 -550 -730 -259 12 143 -74 39 35 162 265 339 259 88 -25 -674 -360 -75 -32 157 134 415 942 757 370 291 230 267 -64 313 -275 -144 254 -170 -157 -202 -202 -184 -69 -181 -144 -315 60 -183 134 -271 355 -210 268 -212 68 113 -190 124 -319 -4 -392 247 -444 -25 -211 152 -81 -343 155 -429 101 -297 245 -128 303 -189 -642 -131 -138 194 -145 25 -312 -67 -603 -307 -231 -406 -67 -332 -14 -389 312 414 376 420 246 524 267 330 -73 247 351 683 946 518 500 150 391 -308 1001 451 359 6 45 -62 -99 83 -55 87 144 367 -285 -217 -945 -960 -1232 -1076 -982 -604 -265 -121 5 232 858 961 978 923 680 976 88 -321 -478 -342 -571 114 -252 -886 -709 -990 -356 17 224 -120 65 56 256 389 472 371 127 -39 -1087 -588 -120 -49 234 191 584 1269 1031 542 445 376 453 -108 553 -516 -276 497 -341 -314 -397 -380 -343 -125 SS 20200320T082412.8Z 7384.350148 521 1 49.65 2 65.74 126.68 73.41 173.91 0.00 1 0.00 1 0 25 2.001e-02 4.796e-03 6.952e-03 9.134e-04 3.663563e-01 4.692173e-04 4.817076e-03 -6.000000e+00 1.176661e-02 225.50 -2.00 3.88 -2.00 318.78 0.00e+00 1.268920e-04 9.410492e-05 1.465689e-04 -6.000000e+00 4.788547e-04 269.01 -2.00 20.00 -2.00 318.48 0.00e+00 2.417 0.000 302.00 328.00 3 2.9709e+00 1.2602e-03 3.1737e-02 -6.0000e+00 2.9277e-02 1.6849e-02 1.4284e-03 2.0625e-02 -6.0000e+00 3.1918e-02 1.5466e-03 1.0436e-03 1.0452e-02 -6.0000e+00 1.8793e-02 -5.5297e-03 5.5640e-04 3.0880e-03 -6.0000e+00 7.8036e-03 1.5549e-03 -2.4802e-04 2.8732e-05 3.8119e-05 -6.0000e+00 6.0144e-04 -3.2668e-04 1.2366e-04 12 1 1 12 1 1 99.93 22.48 0.15 -0.00033 -0.00219 179 36 1 5 0 271.786 25.39 20.00 22.48 14.55 26.80 15.7 1008.63 -8840 -5975 -6555 -8905 -7962 -6588 -4140 -5992 -1877 -6499 -1832 -3907 -669 -1406 -1363 -630 -1932 -994 -1012 444 -2840 584 -380 598 -112 -305 -2090 -2430 588 236 1272 362 592 -2239 -2298 -1210 -607 -45 -271 -340 -948 -773 -1116 -508 -509 -504 -414 -575 266 609 1196 1018 1310 547 882 702 672 435 534 1136 1320 1804 1364 675 32 275 64 766 1140 332 8 -441 -317 -498 -236 -301 1 428 357 143 -755 -981 -1402 -1077 -1078 -724 -414 -179 -118 46 430 179 837 892 908 613 734 127 -283 -344 -471 -241 206 22 -864 -674 -540 -309 38 -16 -12 -45 137 121 369 513 436 195 -212 -517 -492 -45 -297 211 337 582 1026 863 425 301 116 77 148 212 -126 -273 157 -130 -397 3 -202 -184 -147 -352 -250 -278 -363 -300 -245 -164 -273 -90 -343 -95 -227 -44 -109 -121 -62 -205 -111 -118 53 -356 72 -49 82 -16 -46 -317 -353 80 33 193 61 109 -429 -427 -226 -125 -11 -79 -114 -326 -280 -418 -191 -192 -190 -155 -214 106 233 488 449 617 274 458 376 365 236 284 601 724 1063 881 466 23 182 40 482 773 254 7 -359 -256 -386 -180 -207 0 264 235 107 -602 -869 -1341 -1087 -1160 -779 -468 -206 -135 51 469 181 783 827 898 676 851 164 -389 -469 -605 -285 244 25 -1056 -872 -733 -441 55 -25 -20 -75 223 186 527 733 619 288 -315 -811 -786 -71 -453 308 497 816 1378 1171 619 448 184 128 251 376 -225 -512 303 -256 -784 6 -374 -327 -255 SS 20200320T113503.5Z 7384.482680 651 1 51.03 2 52.96 180.93 80.72 218.20 0.00 1 0.00 1 0 25 1.912e-02 6.731e-03 1.707e-02 4.495e-03 2.656895e-01 2.301103e-03 3.561988e-03 -6.000000e+00 1.124428e-02 225.51 -2.00 3.88 -2.00 317.82 0.00e+00 -5.233025e-04 3.473359e-04 7.279681e-05 -6.000000e+00 4.574630e-04 269.03 -2.00 20.00 -2.00 317.49 0.00e+00 1.656 0.000 302.00 328.00 3 6.3185e+00 6.0761e-03 2.2327e-02 -6.0000e+00 2.7978e-02 4.1709e-02 6.8233e-03 1.4943e-02 -6.0000e+00 3.0500e-02 7.0764e-03 4.3044e-03 7.5115e-03 -6.0000e+00 1.7958e-02 -5.1625e-03 2.1707e-03 2.1833e-03 -6.0000e+00 7.4581e-03 1.3073e-04 8.3256e-05 1.4197e-04 2.7672e-05 -6.0000e+00 5.7458e-04 -9.3374e-04 1.5596e-04 11 8 0 10 0 0 99.85 22.48 0.18 -0.00093 -0.00031 17 3 1 5 0 2952.599 25.39 20.00 22.48 16.67 28.80 16.1 1019.13 -7128 2951 -12599 -7263 546 -3121 -646 555 1414 -5443 -422 1244 2726 -2765 462 1526 -1488 -2241 -1386 4917 1135 2104 1412 4319 -1352 -390 349 -233 909 803 -1159 4085 1230 -2575 81 -2444 783 -274 1943 -1417 -1413 -1406 -109 -1005 -1490 79 -2739 -952 -676 1028 631 -323 1078 565 701 8 1787 141 144 701 1443 2335 991 1202 117 934 -115 -8 728 1132 739 141 270 -439 -240 -1154 -41 -119 -69 -808 -1361 -925 -1859 -291 -323 -367 -544 622 81 -9 76 -439 283 122 231 -700 1377 71 -237 584 -622 -223 -557 -597 -1955 -951 -450 508 315 612 377 336 266 -63 15 -319 -223 -995 280 -405 292 -61 105 412 1004 321 667 499 -181 612 906 -65 32 -124 -42 -106 467 -453 223 134 -609 -338 -491 -670 267 -1316 -671 43 -256 -56 53 146 -621 -46 143 344 -418 76 267 -281 -443 -282 968 235 434 303 955 -333 -97 85 -54 199 175 -273 988 324 -708 21 -653 223 -92 755 -647 -697 -724 -57 -531 -789 41 -1433 -479 -336 512 331 -182 633 348 445 5 1163 93 93 453 956 1638 754 953 93 692 -81 -5 538 921 648 129 246 -388 -198 -876 -28 -79 -48 -628 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