File name: Pandora21s1_Bremen_20200401_L2Fit_fwvt1c2d20191026p1-8.txt File generation date: 20240830T030909.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v3d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200401_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200401 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1712 1862 Nominal wavelengths inside fitting window [nm]: 492.0410 492.1614 492.2819 492.4023 492.5227 492.6430 492.7634 492.8838 493.0041 493.1244 493.2447 493.3650 493.4852 493.6055 493.7257 493.8459 493.9661 494.0863 494.2065 494.3266 494.4467 494.5669 494.6870 494.8070 494.9271 495.0472 495.1672 495.2872 495.4072 495.5272 495.6472 495.7671 495.8871 496.0070 496.1269 496.2468 496.3667 496.4865 496.6063 496.7262 496.8460 496.9658 497.0855 497.2053 497.3250 497.4448 497.5645 497.6842 497.8039 497.9235 498.0432 498.1628 498.2824 498.4020 498.5216 498.6412 498.7607 498.8802 498.9997 499.1192 499.2387 499.3582 499.4777 499.5971 499.7165 499.8359 499.9553 500.0747 500.1940 500.3134 500.4327 500.5520 500.6713 500.7906 500.9098 501.0291 501.1483 501.2675 501.3867 501.5059 501.6250 501.7442 501.8633 501.9824 502.1015 502.2206 502.3396 502.4587 502.5777 502.6967 502.8157 502.9347 503.0537 503.1726 503.2916 503.4105 503.5294 503.6483 503.7672 503.8860 504.0048 504.1237 504.2425 504.3613 504.4800 504.5988 504.7175 504.8363 504.9550 505.0737 505.1923 505.3110 505.4296 505.5483 505.6669 505.7855 505.9041 506.0226 506.1412 506.2597 506.3782 506.4967 506.6152 506.7337 506.8521 506.9706 507.0890 507.2074 507.3258 507.4441 507.5625 507.6808 507.7991 507.9175 508.0357 508.1540 508.2723 508.3905 508.5087 508.6269 508.7451 508.8633 508.9815 509.0996 509.2177 509.3359 509.4540 509.5720 509.6901 509.8081 509.9262 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200401T065726.7Z 7396.289892 398 1 7.31 2 72.99 105.25 101.80 20.48 0.00 1 0.00 1 0 15 2.939e-03 2.921e-03 6.970e-04 6.963e-04 1.438157e+03 3.681786e+01 1.117316e+02 -6.000000e+00 1.491754e+02 270.53 -2.00 20.00 -2.00 505.27 0.00e+00 6.882635e-04 1.825337e-05 3.785186e-05 -6.000000e+00 7.862656e-05 270.53 -2.00 20.00 -2.00 500.52 0.00e+00 3.206508e-01 1.343421e-02 1.278120e-02 -6.000000e+00 5.742790e-02 226.51 -2.00 3.88 -2.00 502.10 0.00e+00 3.367 0.001 489.00 513.00 1 5.2817e+00 1.0230e-03 4.9834e-03 -6.0000e+00 4.3731e-03 -6.3230e-03 2.6877e-04 3.9000e-04 -6.0000e+00 1.1543e-03 5.9803e-03 2.5291e-03 5.9778e-05 2.0853e-05 -6.0000e+00 2.5748e-04 -3.3299e-03 5.3383e-06 12 1 1 12 1 1 43.36 22.45 1.33 -0.00333 0.01421 15 22 1 4 0 445.577 25.39 20.00 22.45 9.63 15.5 1024.98 -604 -516 -281 25 343 481 537 394 478 264 236 -29 -247 -276 -315 -232 -138 152 153 401 232 249 279 239 285 418 325 203 101 -211 -472 -395 -320 -93 173 176 203 -135 -207 -363 -272 -121 15 18 178 227 293 154 51 -100 -439 -505 -689 -616 -465 -54 51 160 227 184 172 210 334 142 335 167 274 -125 -101 -255 -411 -503 -443 -124 -88 96 -43 -271 -335 -266 -389 -403 -338 -218 23 -156 -73 25 -144 -100 -3 -31 72 287 281 279 87 -158 -236 -359 -646 -604 -329 -310 -48 8 -41 -314 -333 -307 -97 -27 136 220 367 468 556 541 494 316 222 70 118 102 282 192 320 265 255 279 156 257 16 -63 -141 -218 -37 -83 58 208 225 218 304 110 169 83 -117 -347 -358 -436 -469 -583 -494 -278 25 344 493 548 407 493 270 242 -29 -247 -278 -315 -233 -138 155 157 416 242 259 290 250 300 431 341 212 103 -211 -464 -389 -320 -95 178 183 209 -138 -213 -370 -277 -123 15 19 184 236 303 158 53 -101 -439 -491 -674 -603 -456 -54 52 162 229 185 173 212 340 144 339 167 275 -124 -99 -252 -402 -493 -428 -121 -87 96 -42 -266 -325 -256 -376 -394 -332 -212 23 -155 -73 25 -144 -99 -3 -31 73 288 286 279 86 -156 -227 -344 -613 -576 -314 -302 -49 8 -40 -312 -326 -300 -96 -26 136 223 374 469 561 549 500 322 223 69 118 102 278 190 316 261 251 274 154 256 16 -60 -134 -208 -37 -81 57 205 224 218 305 111 172 84 -118 -342 -349 -427 -452 SQ 20200401T071844.8Z 7396.304685 408 1 49.61 2 69.93 109.83 100.60 25.10 0.00 1 0.00 1 0 22 2.949e-03 2.928e-03 1.009e-03 1.008e-03 1.247487e+03 5.288479e+01 1.012996e+02 -6.000000e+00 1.496622e+02 270.53 -2.00 20.00 -2.00 505.26 0.00e+00 6.148406e-04 2.639869e-05 3.297227e-05 -6.000000e+00 7.888439e-05 270.53 -2.00 20.00 -2.00 500.50 0.00e+00 2.576839e-01 1.945805e-02 1.025419e-02 -6.000000e+00 5.760152e-02 226.51 -2.00 3.88 -2.00 502.08 0.00e+00 2.884 0.000 489.00 513.00 1 6.0530e+00 1.4817e-03 4.2604e-03 -6.0000e+00 4.3866e-03 -3.4782e-03 3.8969e-04 3.2760e-04 -6.0000e+00 1.1574e-03 2.9790e-03 1.7955e-03 8.6364e-05 1.8608e-05 -6.0000e+00 2.5831e-04 -1.9416e-03 2.0527e-05 12 1 1 12 1 1 -15.07 22.45 1.43 -0.00194 0.01051 8 12 1 4 0 810.295 25.39 19.99 22.45 9.58 15.4 1023.40 -741 -590 -247 137 185 368 574 477 330 431 -22 -86 -124 -210 -296 -236 -39 187 100 233 308 19 196 199 428 356 428 93 120 -85 -546 -321 -247 -80 192 409 -60 36 -218 -341 -62 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99 276 287 106 227 280 255 185 -323 -309 -63 -10 -8 49 293 193 186 116 274 161 42 42 -368 -453 -434 -403 SQ 20200401T072321.2Z 7396.307884 411 1 50.32 2 69.28 110.84 100.32 26.09 0.00 1 0.00 1 0 15 2.347e-03 2.325e-03 5.641e-04 5.630e-04 1.218623e+03 2.977055e+01 9.850004e+01 -6.000000e+00 1.191446e+02 270.53 -2.00 20.00 -2.00 505.26 0.00e+00 5.632867e-04 1.473832e-05 3.031793e-05 -6.000000e+00 6.279882e-05 270.53 -2.00 20.00 -2.00 500.43 0.00e+00 2.953373e-01 1.091724e-02 9.863547e-03 -6.000000e+00 4.587713e-02 226.51 -2.00 3.88 -2.00 502.03 0.00e+00 2.799 0.000 489.00 513.00 1 6.6576e+00 8.3112e-04 4.1256e-03 -6.0000e+00 3.4934e-03 3.0401e-04 2.1871e-04 3.1809e-04 -6.0000e+00 9.2237e-04 1.6437e-03 2.9411e-03 4.8312e-05 1.7721e-05 -6.0000e+00 2.0566e-04 -1.6086e-05 -3.6506e-05 10 0 0 10 0 0 99.52 22.45 1.40 -0.00002 0.02038 53 10 1 4 0 949.305 25.39 20.00 22.45 9.51 15.5 1023.85 -481 -317 -227 41 181 268 457 393 283 237 0 -64 -161 -138 -200 -128 -21 103 178 300 184 274 213 187 185 329 293 75 19 -92 -394 -124 -235 -94 26 172 28 -110 -33 -185 -125 -104 -195 105 160 69 120 65 -29 -194 -324 -470 -612 -489 -217 -232 27 133 111 207 220 180 237 202 195 191 182 -19 -170 -167 -307 -282 -297 -160 48 33 -152 -84 -257 -305 -277 -280 -264 -246 -157 -35 -110 68 -66 -110 -67 137 63 114 360 158 187 -41 -315 -315 -522 -450 -339 -307 -47 -120 33 -166 -289 -303 -139 -212 78 320 349 289 354 411 366 307 196 138 129 96 217 279 254 179 184 211 183 187 -9 -195 -166 -33 -107 95 70 107 318 214 131 142 54 132 12 -267 -336 -458 -428 -461 -306 -224 41 186 278 479 415 299 248 0 -65 -163 -139 -200 -129 -22 106 186 316 194 288 224 197 196 348 309 79 20 -92 -392 -123 -236 -96 27 182 29 -115 -34 -190 -128 -107 -202 110 167 72 126 67 -30 -197 -322 -458 -590 -471 -212 -233 28 137 114 211 224 184 243 208 199 194 181 -19 -167 -163 -296 -272 -288 -157 48 33 -149 -81 -245 -291 -264 -269 -255 -238 -153 -34 -109 66 -65 -109 -66 136 63 115 363 158 185 -40 -302 -297 -488 -422 -322 -299 -47 -121 32 -164 -281 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