File name: Pandora21s1_Bremen_20200402_L2Fit_fout2c14d20191026p1-8.txt File generation date: 20250507T094651.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora21_OF_v3d20190904.txt Instrument calibration file used: Pandora21s1_CF_v14d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200402_L1_smca1c14d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1120 305.2523 305.3926 305.5329 305.6731 305.8134 305.9537 306.0939 306.2341 306.3744 306.5146 306.6548 306.7950 306.9352 307.0753 307.2155 307.3557 307.4958 307.6359 307.7761 307.9162 308.0563 308.1964 308.3364 308.4765 308.6166 308.7566 308.8966 309.0367 309.1767 309.3167 309.4567 309.5967 309.7366 309.8766 310.0166 310.1565 310.2964 310.4363 310.5763 310.7162 310.8560 310.9959 311.1358 311.2756 311.4155 311.5553 311.6952 311.8350 311.9748 312.1146 312.2543 312.3941 312.5339 312.6736 312.8134 312.9531 313.0928 313.2325 313.3722 313.5119 313.6516 313.7913 313.9309 314.0706 314.2102 314.3498 314.4894 314.6290 314.7686 314.9082 315.0478 315.1873 315.3269 315.4664 315.6059 315.7455 315.8850 316.0245 316.1639 316.3034 316.4429 316.5823 316.7218 316.8612 317.0006 317.1400 317.2794 317.4188 317.5582 317.6976 317.8369 317.9763 318.1156 318.2549 318.3942 318.5335 318.6728 318.8121 318.9514 319.0906 319.2299 319.3691 319.5083 319.6475 319.7867 319.9259 320.0651 320.2043 320.3435 320.4826 320.6217 320.7609 320.9000 321.0391 321.1782 321.3173 321.4563 321.5954 321.7345 321.8735 322.0125 322.1515 322.2906 322.4296 322.5685 322.7075 322.8465 322.9854 323.1244 323.2633 323.4022 323.5411 323.6800 323.8189 323.9578 324.0967 324.2355 324.3744 324.5132 324.6520 324.7908 324.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200402T072527.8Z 7397.309350 387 1 49.64 2 68.63 111.14 103.56 14.40 0.00 1 0.00 1 0 17 3.581e-02 5.711e-03 3.851e-02 4.001e-03 3.909051e-01 2.071432e-03 5.073212e-03 -6.000000e+00 2.114446e-02 226.60 -2.00 3.88 -2.00 319.20 0.00e+00 9.613657e-04 4.632852e-04 1.788619e-04 -6.000000e+00 8.569818e-04 270.66 -2.00 20.00 -2.00 318.89 0.00e+00 2.719 0.000 302.00 328.00 3 5.3699e+00 5.6418e-03 3.5007e-02 -6.0000e+00 5.2741e-02 8.8127e-02 6.4342e-03 2.2119e-02 -6.0000e+00 5.7454e-02 -1.6730e-02 4.9943e-03 1.1230e-02 -6.0000e+00 3.3801e-02 -2.6806e-03 2.6716e-03 3.3379e-03 -6.0000e+00 1.4004e-02 9.8650e-05 -4.9129e-04 1.2743e-04 4.1085e-05 -6.0000e+00 1.0767e-03 1.0478e-03 0.0000e+00 10 0 0 10 0 0 88.95 22.47 0.53 0.00105 -0.00264 15 3 1 5 0 3308.832 25.39 20.00 22.47 12.87 15.6 1015.91 3228 -4459 -10811 -18158 -7602 -17231 -8304 -13544 -6414 -4792 -11197 9522 -4720 5044 2074 -5463 -3247 -4392 1119 -8507 -1141 -982 -1110 1606 -6376 4739 1135 232 -1290 -785 -2148 2641 -210 -499 564 3092 1964 -877 1137 -850 2173 -1470 -1553 -689 -1581 -287 -2044 1388 -3087 717 983 4030 130 3039 282 145 590 -683 718 -56 2309 1222 361 -361 -403 2212 403 687 -648 380 198 -84 -106 814 -632 -293 -251 87 1484 -992 37 -1558 -893 -1576 -1243 -141 -131 587 -90 314 -7 1191 -493 803 435 889 881 343 -94 -291 -396 -288 -8 -112 -524 -942 -976 54 -181 230 -124 -263 -409 463 -148 190 136 239 203 -644 -73 196 294 -74 741 400 565 966 319 -187 -142 491 70 265 -371 -253 98 348 74 -242 -191 -491 -122 88 -141 -369 -628 -224 -555 -267 -512 -248 -191 -492 377 -249 287 140 -441 -276 -401 102 -881 -112 -97 -115 172 -783 540 133 26 -145 -91 -277 362 -32 -78 85 460 326 -176 266 -233 633 -467 -510 -228 -530 -96 -690 452 -1062 247 361 1549 55 1330 132 69 286 -334 342 -27 1121 646 209 -224 -252 1290 230 392 -404 260 146 -64 -81 591 -433 -183 -145 50 888 -682 28 -1325 -807 -1509 -1256 -149 -145 661 -101 342 -8 1127 -448 717 414 927 1017 435 -126 -389 -503 -340 -9 -128 -633 -1202 -1300 74 -265 356 -203 -440 -674 725 -219 269 192 347 309 -1031 -118 313 457 -111 1068 557 761 1307 460 -290 -233 828 122 476 -700 -498 197 708 152 -487 -373 -926 -224 SS 20200402T073147.6Z 7397.313746 390 1 51.27 2 67.74 112.55 103.33 15.81 0.00 1 0.00 1 0 17 3.686e-02 5.506e-03 3.157e-02 3.593e-03 3.734072e-01 1.857677e-03 4.867713e-03 -6.000000e+00 2.176797e-02 226.60 -2.00 3.88 -2.00 319.05 0.00e+00 8.370176e-04 3.965520e-04 1.603608e-04 -6.000000e+00 8.822883e-04 270.66 -2.00 20.00 -2.00 318.73 0.00e+00 2.618 0.000 302.00 328.00 3 5.3915e+00 5.0350e-03 3.3597e-02 -6.0000e+00 5.4296e-02 6.9266e-02 5.7245e-03 2.1130e-02 -6.0000e+00 5.9149e-02 -8.2527e-03 4.3280e-03 1.0702e-02 -6.0000e+00 3.4799e-02 -4.6430e-03 2.3106e-03 3.1666e-03 -6.0000e+00 1.4416e-02 1.0984e-04 -5.0095e-04 1.1449e-04 3.8913e-05 -6.0000e+00 1.1085e-03 1.3268e-03 0.0000e+00 10 0 0 10 0 0 97.39 22.46 0.22 0.00133 -0.00244 18 4 1 5 0 2847.838 25.39 19.99 22.46 12.83 15.7 1016.29 6636 -10914 -11242 1032 -5391 901 -25357 17121 -1649 -12656 -5459 4340 -1949 5821 1448 6105 -2349 9471 -2514 -4698 -429 -5011 -694 -3379 -1047 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-872 -1292 -788 -264 -63 -164 121 -388 233 45 478 294 113 220 42 -889 -271 73 -33 459 513 663 1318 1001 446 116 343 271 200 385 -295 124 311 -87 -315 25 -563 -525 -742 SS 20200402T074125.7Z 7397.320437 393 1 49.49 2 66.42 114.72 102.93 17.96 0.00 1 0.00 1 0 17 2.875e-02 5.081e-03 1.789e-02 2.380e-03 3.563483e-01 1.228200e-03 4.667137e-03 -6.000000e+00 1.697677e-02 226.60 -2.00 3.88 -2.00 318.87 0.00e+00 4.389662e-04 2.486316e-04 1.436868e-04 -6.000000e+00 6.880691e-04 270.66 -2.00 20.00 -2.00 318.55 0.00e+00 2.481 0.000 302.00 328.00 3 4.8353e+00 3.3159e-03 3.1936e-02 -6.0000e+00 4.2346e-02 4.5179e-02 3.7543e-03 2.0165e-02 -6.0000e+00 4.6129e-02 -1.1304e-02 2.7395e-03 1.0189e-02 -6.0000e+00 2.7139e-02 -2.1019e-03 1.4552e-03 3.0010e-03 -6.0000e+00 1.1244e-02 2.2734e-04 -5.0603e-04 7.5858e-05 3.6905e-05 -6.0000e+00 8.6445e-04 1.1014e-03 0.0000e+00 10 0 0 10 0 0 72.29 22.47 0.19 0.00110 -0.00270 33 6 1 5 0 1499.459 25.39 20.00 22.47 13.28 15.7 1018.67 -3145 3249 -5520 -3963 -3897 -20900 11043 -12155 -510 -9771 2435 -6197 -1389 -1082 -685 -1040 -4976 5944 -1826 461 -4344 3531 1273 -537 1045 -2484 -616 -2382 1004 119 2645 2201 -1011 -2367 -923 1030 -2147 1050 -621 1368 -1655 -863 -1074 -944 281 -969 -525 -1589 433 -1309 1567 1430 321 659 1106 1819 376 601 424 636 877 2231 1151 709 186 108 428 -79 1517 59 379 -655 327 -595 -599 -454 -462 493 28 68 -1450 -924 -1683 -600 -638 -1212 14 -447 684 -292 507 338 682 766 773 947 430 558 -345 -410 -263 118 184 243 -804 -536 -514 -262 213 -131 -39 -143 -128 -128 227 541 131 340 -99 -289 -631 105 -164 227 128 722 1036 590 140 50 151 -81 279 -54 3 10 50 44 -248 -53 -209 -123 -208 -124 130 -243 -162 -149 -937 398 -609 -25 -547 125 -375 -92 -84 -61 -102 -539 613 -212 54 -546 416 159 -73 148 -374 -90 -340 134 17 388 358 -183 -441 -165 183 -433 241 -172 425 -576 -314 -402 -358 106 -369 -198 -601 162 -513 635 623 150 324 561 942 200 318 222 332 473 1276 718 469 124 69 261 -49 982 43 295 -533 262 -464 -437 -303 -286 296 18 48 -1167 -810 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