File name: Pandora21s1_Bremen_20200402_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T030556.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v3d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200402_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200402T072527.8Z 7397.309350 387 1 49.64 2 68.63 111.14 103.56 14.40 0.00 1 0.00 1 0 17 3.588e-02 5.710e-03 3.851e-02 4.001e-03 3.909763e-01 2.071511e-03 5.080029e-03 -6.000000e+00 2.118564e-02 226.60 -2.00 3.88 -2.00 319.20 0.00e+00 9.602349e-04 4.632923e-04 1.784252e-04 -6.000000e+00 8.588398e-04 270.66 -2.00 20.00 -2.00 318.89 0.00e+00 2.719 0.000 302.00 328.00 3 5.0764e+00 5.6417e-03 3.5016e-02 -6.0000e+00 5.2843e-02 8.8101e-02 6.4342e-03 2.2136e-02 -6.0000e+00 5.7567e-02 -1.6745e-02 4.9950e-03 1.1238e-02 -6.0000e+00 3.3868e-02 -2.6304e-03 2.6722e-03 3.3386e-03 -6.0000e+00 1.4031e-02 1.3229e-04 -6.6635e-04 1.2741e-04 4.1176e-05 -6.0000e+00 1.0790e-03 -1.9781e-03 2.7866e-05 10 0 0 10 0 0 88.95 22.47 0.53 -0.00198 -0.00699 15 3 1 5 0 3308.832 25.39 20.00 22.47 12.87 15.6 1015.91 3301 -4461 -10888 -18285 -7689 -17234 -8244 -13486 -6397 -4807 -11185 9603 -4606 5148 2147 -5429 -3233 -4379 1120 -8520 -1171 -999 -1102 1623 -6373 4715 1081 167 -1324 -766 -2102 2679 -197 -537 523 3104 2028 -791 1211 -805 2190 -1469 -1563 -708 -1601 -309 -2068 1368 -3096 725 1004 4047 143 3045 282 140 577 -703 698 -64 2318 1240 378 -359 -424 2182 385 691 -623 403 207 -87 -122 788 -664 -325 -273 86 1502 -970 55 -1545 -885 -1569 -1235 -135 -129 584 -97 303 -21 1178 -500 805 442 898 889 349 -91 -291 -397 -289 -9 -112 -524 -943 -978 52 -183 228 -125 -261 -404 470 -139 196 138 237 199 -646 -71 200 300 -67 748 408 569 959 305 -200 -151 487 65 256 -381 -260 94 346 77 -233 -180 -482 -123 90 -141 -372 -632 -226 -555 -265 -510 -247 -192 -491 381 -243 292 145 -439 -275 -400 102 -882 -115 -99 -114 174 -782 537 126 19 -149 -89 -271 367 -30 -84 79 462 337 -159 284 -221 638 -467 -513 -234 -537 -103 -698 446 -1065 249 368 1556 61 1333 131 67 280 -344 332 -31 1125 655 219 -223 -265 1273 219 395 -388 276 153 -67 -93 573 -456 -203 -158 49 899 -666 42 -1314 -800 -1503 -1248 -143 -142 658 -109 330 -22 1115 -454 718 420 937 1026 443 -122 -389 -505 -341 -10 -128 -634 -1203 -1302 72 -268 353 -205 -437 -666 737 -206 278 195 344 304 -1034 -115 319 465 -101 1079 568 766 1298 440 -310 -247 820 113 460 -720 -512 189 704 158 -469 -350 -908 -226 SS 20200402T073147.6Z 7397.313746 390 1 51.27 2 67.74 112.55 103.33 15.81 0.00 1 0.00 1 0 17 3.691e-02 5.509e-03 3.157e-02 3.593e-03 3.734428e-01 1.857409e-03 4.867346e-03 -6.000000e+00 2.179378e-02 226.60 -2.00 3.88 -2.00 319.05 0.00e+00 8.363571e-04 3.965606e-04 1.604643e-04 -6.000000e+00 8.833298e-04 270.66 -2.00 20.00 -2.00 318.73 0.00e+00 2.618 0.000 302.00 328.00 3 5.0980e+00 5.0337e-03 3.3597e-02 -6.0000e+00 5.4361e-02 6.9246e-02 5.7231e-03 2.1130e-02 -6.0000e+00 5.9218e-02 -8.2415e-03 4.3282e-03 1.0703e-02 -6.0000e+00 3.4839e-02 -4.6279e-03 2.3111e-03 3.1673e-03 -6.0000e+00 1.4435e-02 1.4729e-04 -4.8026e-04 1.1453e-04 3.8905e-05 -6.0000e+00 1.1098e-03 -1.9855e-03 6.7436e-05 10 0 0 10 0 0 97.39 22.46 0.22 -0.00199 -0.00559 18 4 1 5 0 2847.838 25.39 19.99 22.46 12.83 15.7 1016.29 6675 -10918 -11289 956 -5443 898 -25324 17154 -1641 -12666 -5455 4383 -1888 5878 1487 6121 -2343 9477 -2515 -4706 -447 -5021 -690 -3371 -1046 -2277 -4676 -5022 -1614 1831 1412 1011 556 -1775 -1759 673 344 -1131 620 -301 -589 -974 -1351 -1810 -1890 1032 -564 218 -2140 164 898 2290 547 1414 1881 90 1949 -747 539 1469 1390 2347 2326 638 -619 -458 303 -124 532 -269 -219 669 291 -907 923 -323 -230 934 1319 -397 -559 -2440 -963 -999 -871 73 -35 -160 410 556 -44 -384 509 980 289 189 574 208 345 -946 -154 -511 392 -165 -715 -1006 -591 -191 -45 -107 74 -231 145 34 330 213 81 151 25 -560 -167 48 -18 309 359 481 986 737 303 68 208 160 114 213 -164 60 155 -44 -155 18 -287 -277 -407 204 -425 -445 32 -181 28 -1096 559 -69 -622 -259 207 -110 372 113 493 -219 839 -262 -519 -48 -571 -78 -418 -134 -305 -635 -658 -199 225 191 152 91 -302 -291 110 62 -245 156 -88 -188 -329 -471 -643 -676 360 -199 76 -771 60 347 939 243 657 902 45 975 -381 268 725 711 1281 1377 406 -401 -283 178 -74 338 -190 -167 524 227 -688 643 -208 -138 542 811 -278 -438 -2129 -885 -967 -890 78 -39 -184 468 613 -46 -374 466 886 279 200 668 265 461 -1272 -196 -608 442 -189 -873 -1293 -789 -266 -65 -167 120 -386 238 53 486 300 114 218 38 -891 -270 76 -28 464 519 669 1321 996 435 105 336 267 195 377 -305 117 307 -89 -312 35 -552 -515 -742 SS 20200402T074125.7Z 7397.320437 393 1 49.49 2 66.42 114.72 102.93 17.96 0.00 1 0.00 1 0 17 2.879e-02 5.087e-03 1.789e-02 2.380e-03 3.564196e-01 1.228260e-03 4.674442e-03 -6.000000e+00 1.699627e-02 226.60 -2.00 3.88 -2.00 318.87 0.00e+00 4.387699e-04 2.486439e-04 1.432843e-04 -6.000000e+00 6.890352e-04 270.66 -2.00 20.00 -2.00 318.55 0.00e+00 2.481 0.000 302.00 328.00 3 4.5418e+00 3.3158e-03 3.1947e-02 -6.0000e+00 4.2394e-02 4.5155e-02 3.7542e-03 2.0183e-02 -6.0000e+00 4.6184e-02 -1.1306e-02 2.7399e-03 1.0198e-02 -6.0000e+00 2.7171e-02 -2.0605e-03 1.4556e-03 3.0020e-03 -6.0000e+00 1.1256e-02 3.0486e-04 -7.1857e-04 7.5852e-05 3.7005e-05 -6.0000e+00 8.6566e-04 -1.9087e-03 1.9756e-05 10 0 0 10 0 0 72.29 22.47 0.19 -0.00191 -0.00731 33 6 1 5 0 1499.459 25.39 20.00 22.47 13.28 15.7 1018.67 -3077 3240 -5607 -4103 -3993 -20903 11106 -12094 -495 -9794 2436 -6125 -1280 -981 -615 -1010 -4966 5954 -1827 447 -4376 3513 1281 -520 1048 -2511 -677 -2455 961 132 2688 2237 -999 -2409 -966 1043 -2079 1142 -542 1415 -1637 -864 -1085 -964 259 -993 -551 -1613 421 -1302 1588 1448 334 665 1106 1815 362 581 404 628 887 2250 1168 710 164 75 408 -75 1543 84 390 -657 312 -620 -632 -487 -485 491 45 91 -1431 -910 -1674 -592 -630 -1206 17 -449 678 -303 494 326 675 767 779 956 438 564 -342 -409 -263 118 185 243 -805 -537 -516 -265 210 -133 -40 -141 -122 -118 237 548 133 338 -104 -292 -629 109 -158 235 136 731 1041 583 124 35 142 -86 274 -64 -9 2 45 41 -244 -42 -196 -112 -208 -122 130 -247 -168 -153 -937 401 -606 -24 -548 125 -371 -85 -76 -54 -99 -538 614 -212 53 -550 414 160 -70 148 -378 -99 -350 129 18 395 364 -181 -449 -172 185 -419 262 -150 440 -570 -314 -406 -365 98 -379 -208 -610 157 -510 644 631 157 327 561 939 193 308 211 328 478 1287 729 470 109 48 248 -46 999 61 303 -535 250 -483 -461 -325 -301 295 29 65 -1152 -798 -1573 -579 -651 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