File name: Pandora21s1_Bremen_20200618_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T042150.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v3d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200618_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200618 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200618T084127.0Z 7474.362119 307 1 20.08 2 42.88 117.47 38.22 170.68 0.00 1 0.00 1 0 17 1.215e-02 6.086e-03 8.122e-03 3.791e-03 2.153397e-01 2.015938e-03 2.863329e-03 -6.000000e+00 7.364677e-03 233.65 -2.00 3.88 -2.00 316.34 0.00e+00 2.440972e-04 2.063260e-04 3.713492e-05 -6.000000e+00 2.906532e-04 280.35 -2.00 20.00 -2.00 316.02 0.00e+00 1.363 0.000 302.00 328.00 3 6.1154e+00 5.3157e-03 1.8673e-02 -6.0000e+00 1.8684e-02 3.9820e-02 5.8926e-03 1.2490e-02 -6.0000e+00 2.0243e-02 -7.9033e-04 3.4081e-03 6.0848e-03 -6.0000e+00 1.1843e-02 -1.1902e-03 1.5535e-03 1.6755e-03 -6.0000e+00 4.8390e-03 2.3103e-04 -5.3646e-05 1.1776e-04 2.2352e-05 -6.0000e+00 3.6588e-04 -3.7822e-03 1.5758e-04 12 1 1 12 9 1 99.27 22.48 0.22 -0.00378 -0.00419 4 3 1 5 0 3980.735 25.39 20.00 22.48 29.09 17.9 1010.64 4935 2496 -2883 -8021 1546 -1048 846 1188 1933 -1366 -1225 -1987 -1743 802 1214 112 290 -1455 -1282 1360 190 -1080 1249 -571 1258 -2135 129 -161 437 827 1396 2871 894 -1369 -929 -509 -2077 309 -164 -444 -376 -392 52 -775 -310 -1292 -785 -1177 76 740 438 1634 1030 979 1395 -108 -643 1192 -265 1314 1337 663 1147 808 -58 -220 -459 -714 571 701 112 85 658 -269 571 -419 -744 -104 -1290 -1067 -153 -1044 -1055 -1205 -839 -843 -206 420 702 -381 74 163 236 462 308 550 276 203 158 30 -597 -495 -807 -367 -831 -539 -394 159 75 304 810 359 515 71 -28 56 -536 -134 -506 -180 -582 176 10 539 233 347 944 535 707 -250 455 35 199 -62 -36 70 680 65 -42 -235 -350 -599 -591 865 471 -567 -1536 250 -171 145 224 389 -291 -260 -443 -426 214 355 35 94 -493 -446 473 67 -389 450 -218 492 -876 51 -61 155 290 508 1092 362 -566 -369 -202 -906 151 -92 -278 -251 -270 36 -549 -219 -912 -542 -795 50 488 300 1161 766 753 1091 -87 -523 954 -213 1043 1090 571 1036 755 -54 -194 -384 -589 489 649 110 87 666 -267 535 -368 -608 -82 -1052 -937 -144 -1060 -1123 -1332 -969 -1020 -258 534 890 -475 88 180 245 468 322 611 328 258 207 39 -753 -592 -941 -435 -1036 -698 -526 218 106 445 1213 542 759 100 -37 72 -684 -175 -690 -256 -847 254 14 745 312 449 1177 665 906 -336 628 49 283 -91 -54 110 1078 105 -69 -379 -553 -928 -902 SS 20200618T084720.9Z 7474.366214 310 1 49.85 2 42.10 119.11 38.08 172.92 0.00 1 0.00 1 0 17 1.037e-02 5.476e-03 5.817e-03 2.463e-03 2.118223e-01 1.304565e-03 2.796659e-03 -6.000000e+00 6.287720e-03 233.65 -2.00 3.88 -2.00 316.69 0.00e+00 3.056073e-04 1.442242e-04 4.064514e-05 -6.000000e+00 2.480988e-04 280.35 -2.00 20.00 -2.00 316.36 0.00e+00 1.346 0.000 302.00 328.00 3 6.0449e+00 3.4521e-03 1.8391e-02 -6.0000e+00 1.5952e-02 4.1117e-02 3.8303e-03 1.2259e-02 -6.0000e+00 1.7282e-02 -1.0414e-03 2.2366e-03 5.9746e-03 -6.0000e+00 1.0111e-02 -1.6469e-03 1.0349e-03 1.6506e-03 -6.0000e+00 4.1319e-03 2.5366e-04 1.4027e-04 7.7187e-05 2.1371e-05 -6.0000e+00 3.1231e-04 -4.7856e-03 1.6137e-04 10 0 0 10 0 0 99.64 22.48 0.21 -0.00479 -0.00373 13 3 1 5 0 3834.237 25.39 20.00 22.48 29.55 17.9 1012.88 -1643 -1760 -2707 -3425 -4872 2933 -2264 963 -2415 -2465 -1925 1448 554 324 1361 -764 1274 785 294 1268 2090 1840 -109 1341 -600 153 -1302 -117 -624 374 542 1036 623 -1316 -491 -1063 -393 1268 610 -1016 -350 -317 -427 -410 -1354 -271 -1113 -846 -601 740 -656 1213 988 -256 852 360 374 59 1098 614 1831 1585 1269 438 28 -194 -506 374 -29 238 78 253 224 414 218 -623 -1018 -1277 -823 -995 -982 -985 -977 -903 -612 -445 112 349 -33 642 -217 395 -63 523 14 346 832 462 373 -74 -287 -934 -496 -62 -1335 -673 -551 -92 26 412 498 407 186 75 12 23 -592 -370 -106 -248 78 -4 135 378 680 352 643 738 -36 362 -76 329 223 79 -178 -59 334 107 -12 -257 -340 -610 -238 -271 -307 -471 -556 -738 405 -351 160 -448 -470 -365 277 118 77 356 -217 367 235 91 399 660 583 -36 456 -216 56 -472 -40 -202 119 179 362 229 -493 -175 -384 -154 564 317 -600 -220 -207 -284 -274 -912 -180 -728 -537 -375 459 -427 818 698 -189 639 276 289 46 832 468 1424 1307 1111 399 25 -165 -406 293 -24 215 75 252 223 399 199 -527 -797 -963 -638 -841 -907 -979 -1022 -985 -702 -537 141 447 -42 797 -256 431 -64 517 14 380 983 587 494 -97 -362 -1120 -573 -73 -1676 -879 -746 -128 37 615 768 632 281 107 17 30 -759 -486 -147 -359 115 -6 196 531 917 457 805 917 -47 490 -107 470 324 117 -276 -95 549 180 -19 -429 -555 -974 -373 SS 20200618T085250.1Z 7474.370025 313 1 50.28 2 41.38 120.66 37.98 175.02 0.00 1 0.00 1 0 17 9.602e-03 5.638e-03 8.675e-03 3.447e-03 2.123607e-01 1.823035e-03 2.791277e-03 -6.000000e+00 5.822124e-03 233.65 -2.00 3.88 -2.00 316.90 0.00e+00 2.218684e-05 2.108441e-04 4.311753e-05 -6.000000e+00 2.297442e-04 280.35 -2.00 20.00 -2.00 316.56 0.00e+00 1.331 0.000 302.00 328.00 3 6.3787e+00 4.8342e-03 1.8299e-02 -6.0000e+00 1.4771e-02 4.7335e-02 5.3677e-03 1.2269e-02 -6.0000e+00 1.6003e-02 1.5778e-05 3.1559e-03 5.9834e-03 -6.0000e+00 9.3624e-03 -1.3457e-03 1.4750e-03 1.6577e-03 -6.0000e+00 3.8258e-03 1.8364e-04 7.5886e-05 1.0856e-04 2.1142e-05 -6.0000e+00 2.8921e-04 -4.5793e-03 1.5503e-04 10 0 0 10 0 0 99.91 22.48 0.40 -0.00458 -0.00401 19 4 1 5 0 2645.868 25.39 19.99 22.48 30.01 17.9 1014.90 947 -2227 2308 -1096 -1274 -2221 1142 -621 1268 -2517 -5076 -207 -1350 1885 955 493 -197 817 -1334 -302 1712 1047 -182 -99 876 -1783 1345 -294 298 393 1115 -48 1047 -1057 -664 -947 -661 1169 410 127 -866 26 129 -797 -18 -831 -1766 -1569 -1358 -444 828 993 584 144 1189 729 -411 -351 466 560 1407 1236 1856 559 369 -89 429 -392 -70 758 792 129 200 329 -540 -602 -1604 -534 -1388 -461 -1458 -1382 -1264 -983 -408 -86 536 471 611 263 659 -302 -316 -429 53 418 257 346 132 206 -276 -392 -292 -715 -371 -725 -763 -30 342 413 501 544 300 119 -521 42 -453 -277 -712 72 -452 429 266 404 508 -53 438 21 475 -308 158 147 -30 217 -228 202 546 -133 24 333 -467 -472 -409 142 -363 356 -162 -174 -300 160 -98 213 -450 -929 -38 -274 415 235 130 -54 229 -393 -91 510 314 -57 -32 295 -628 450 -94 90 117 344 -16 362 -373 -224 -322 -245 493 204 71 -528 16 82 -517 -12 -533 -1118 -963 -818 -266 512 647 400 103 862 541 -312 -265 345 415 1067 996 1581 499 325 -74 332 -300 -57 666 746 126 196 313 -486 -496 -1225 -387 -1048 -377 -1324 -1357 -1310 -1065 -465 -104 672 605 783 328 771 -329 -319 -421 54 454 305 441 176 272 -350 -466 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