File name: Pandora21s1_Bremen_20200626_L2Fit_fout2c14d20191026p1-8.txt File generation date: 20250507T104253.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v14d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200626_L1_smca1c14d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1120 305.2523 305.3926 305.5329 305.6731 305.8134 305.9537 306.0939 306.2341 306.3744 306.5146 306.6548 306.7950 306.9352 307.0753 307.2155 307.3557 307.4958 307.6359 307.7761 307.9162 308.0563 308.1964 308.3364 308.4765 308.6166 308.7566 308.8966 309.0367 309.1767 309.3167 309.4567 309.5967 309.7366 309.8766 310.0166 310.1565 310.2964 310.4363 310.5763 310.7162 310.8560 310.9959 311.1358 311.2756 311.4155 311.5553 311.6952 311.8350 311.9748 312.1146 312.2543 312.3941 312.5339 312.6736 312.8134 312.9531 313.0928 313.2325 313.3722 313.5119 313.6516 313.7913 313.9309 314.0706 314.2102 314.3498 314.4894 314.6290 314.7686 314.9082 315.0478 315.1873 315.3269 315.4664 315.6059 315.7455 315.8850 316.0245 316.1639 316.3034 316.4429 316.5823 316.7218 316.8612 317.0006 317.1400 317.2794 317.4188 317.5582 317.6976 317.8369 317.9763 318.1156 318.2549 318.3942 318.5335 318.6728 318.8121 318.9514 319.0906 319.2299 319.3691 319.5083 319.6475 319.7867 319.9259 320.0651 320.2043 320.3435 320.4826 320.6217 320.7609 320.9000 321.0391 321.1782 321.3173 321.4563 321.5954 321.7345 321.8735 322.0125 322.1515 322.2906 322.4296 322.5685 322.7075 322.8465 322.9854 323.1244 323.2633 323.4022 323.5411 323.6800 323.8189 323.9578 324.0967 324.2355 324.3744 324.5132 324.6520 324.7908 324.9296 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200626T065541.5Z 7482.288675 214 1 51.09 2 58.45 92.49 103.98 45.95 0.00 1 0.00 1 0 17 7.916e-03 4.315e-03 1.434e-03 3.456e-04 2.761390e-01 1.823977e-04 3.647584e-03 -6.000000e+00 4.798758e-03 233.78 -2.00 3.88 -2.00 317.98 0.00e+00 3.824108e-04 2.780154e-05 7.812390e-05 -6.000000e+00 1.894694e-04 281.07 -2.00 20.00 -2.00 317.64 0.00e+00 1.904 0.000 302.00 328.00 3 1.8160e+00 4.9075e-04 2.5144e-02 -6.0000e+00 1.2178e-02 -1.4217e-02 5.4623e-04 1.6160e-02 -6.0000e+00 1.3195e-02 4.7174e-03 3.4511e-04 7.9058e-03 -6.0000e+00 7.7194e-03 -4.7749e-03 1.7302e-04 2.2039e-03 -6.0000e+00 3.1509e-03 9.2891e-03 -4.6823e-04 1.0992e-05 2.7578e-05 -6.0000e+00 2.3850e-04 1.8953e-03 0.0000e+00 10 0 0 10 0 0 96.22 22.66 0.19 0.00190 -0.00162 1864 366 1 5 0 26.614 25.58 20.00 22.66 30.80 18.2 1030.29 -584 -1246 -3451 -3749 -2405 -1387 746 1026 -21 -1083 -618 -116 326 430 -61 -236 -407 117 45 98 -196 330 642 64 17 -680 -1191 -1058 -20 400 930 1066 -317 -1652 -1554 -949 -381 304 1 -724 -907 -842 -1049 -865 -743 -879 -811 -870 -222 504 756 1000 1236 920 859 952 649 317 582 1032 1298 1620 1419 631 108 -10 -62 524 824 494 87 -93 -195 -363 -290 -281 -302 -84 -67 -382 -589 -1097 -1202 -921 -767 -532 -145 -81 -31 -65 63 -187 213 423 456 501 768 288 -228 -312 -395 -408 83 -146 -747 -517 -477 -264 205 200 226 237 231 223 276 370 224 110 -155 -457 -424 -61 -125 273 383 426 851 680 383 272 72 -24 0 35 -282 -184 125 -45 -178 26 -174 -151 -222 -47 -107 -301 -305 -178 -101 57 88 -2 -107 -61 -12 39 59 -9 -40 -72 21 9 19 -39 66 133 14 4 -162 -280 -236 -4 84 208 258 -83 -440 -399 -244 -108 100 0 -306 -418 -406 -520 -432 -371 -437 -397 -418 -105 241 380 537 702 550 530 601 417 203 368 650 846 1130 1072 504 86 -8 -43 362 610 408 74 -82 -171 -308 -244 -213 -210 -56 -47 -301 -520 -1004 -1179 -952 -846 -625 -179 -97 -37 -79 71 -195 205 396 449 542 921 359 -301 -410 -490 -499 97 -175 -958 -662 -640 -371 301 313 350 373 373 339 386 489 294 150 -226 -708 -675 -97 -192 402 537 568 1150 920 516 392 110 -39 0 59 -473 -324 227 -84 -334 48 -309 -259 -372 SS 20200626T070139.8Z 7482.292821 218 1 51.52 2 57.55 93.71 103.37 47.24 0.00 1 0.00 1 0 17 9.334e-03 4.907e-03 5.291e-04 1.509e-04 2.679813e-01 7.969357e-05 3.537537e-03 -6.000000e+00 5.659454e-03 233.78 -2.00 3.88 -2.00 317.54 0.00e+00 2.820438e-04 1.089683e-05 6.795136e-05 -6.000000e+00 2.233994e-04 281.07 -2.00 20.00 -2.00 317.19 0.00e+00 1.857 0.000 302.00 328.00 3 5.1664e-01 2.1323e-04 2.4436e-02 -6.0000e+00 1.4362e-02 -1.4130e-02 2.3692e-04 1.5624e-02 -6.0000e+00 1.5561e-02 2.9479e-03 1.4535e-04 7.6321e-03 -6.0000e+00 9.1034e-03 -2.9788e-03 7.1257e-05 2.1191e-03 -6.0000e+00 3.7167e-03 3.6139e-02 -3.4292e-04 4.7635e-06 2.6774e-05 -6.0000e+00 2.8121e-04 3.2407e-04 0.0000e+00 10 0 0 10 0 0 -1.70 22.66 0.27 0.00032 -0.00225 3760 738 1 5 0 13.037 25.58 20.00 22.66 31.50 18.2 1033.09 -2001 -2648 -4403 -4383 -3612 -1615 -690 213 -742 -1632 -1097 -238 261 312 186 -799 -111 -150 154 57 60 676 542 497 -17 -331 -1311 -722 124 954 1438 1620 386 -1245 -914 -569 60 515 275 -597 -652 -847 -968 -740 -741 -765 -899 -844 -300 538 748 987 989 763 676 708 591 358 690 981 1298 1460 1233 425 -77 -12 -60 719 858 488 -58 -191 -331 -457 -286 -154 58 328 320 -178 -538 -1166 -1284 -1054 -915 -732 -378 -239 -158 -5 232 283 693 914 738 635 715 141 -310 -408 -391 -369 217 -114 -749 -566 -570 -387 2 -22 -58 -56 2 66 307 512 445 307 -23 -416 -387 -80 -131 265 454 573 1070 902 514 404 164 118 148 228 -199 -184 69 -151 -342 -130 -245 -274 -241 -194 -276 -464 -430 -324 -141 -64 22 -84 -193 -130 -30 37 50 34 -158 -23 -32 34 13 14 157 130 126 -5 -91 -358 -186 30 230 367 447 115 -378 -266 -167 19 194 114 -284 -337 -460 -539 -415 -416 -427 -493 -453 -159 287 420 590 627 508 464 498 422 255 483 687 939 1051 960 350 -63 -9 -46 547 648 412 -54 -184 -318 -423 -246 -119 44 240 245 -143 -483 -1158 -1274 -1103 -1021 -872 -472 -288 -190 -7 267 297 718 921 782 691 862 176 -410 -536 -485 -452 253 -136 -967 -725 -767 -543 2 -32 -90 -87 3 100 429 673 579 416 -33 -641 -577 -118 -200 389 634 761 1441 1216 687 578 248 184 222 356 -328 -320 116 -261 -597 -223 -430 -465 -400 SS 20200626T070657.7Z 7482.296501 221 1 51.45 2 56.76 94.81 102.82 48.39 0.00 1 0.00 1 0 17 9.227e-03 4.911e-03 4.941e-04 1.456e-04 2.622786e-01 7.693625e-05 3.461040e-03 -6.000000e+00 5.594573e-03 233.78 -2.00 3.88 -2.00 317.50 0.00e+00 2.751515e-04 1.042455e-05 6.572762e-05 -6.000000e+00 2.208381e-04 281.07 -2.00 20.00 -2.00 317.16 0.00e+00 1.818 0.000 302.00 328.00 3 5.1055e-01 2.0572e-04 2.3915e-02 -6.0000e+00 1.4198e-02 -1.4946e-02 2.2845e-04 1.5284e-02 -6.0000e+00 1.5383e-02 3.5494e-03 1.3962e-04 7.4604e-03 -6.0000e+00 8.9990e-03 -3.0558e-03 6.8321e-05 2.0712e-03 -6.0000e+00 3.6741e-03 3.8125e-02 -3.4095e-04 4.5959e-06 2.5548e-05 -6.0000e+00 2.7798e-04 3.1813e-04 0.0000e+00 10 0 0 10 0 0 1.39 22.66 0.27 0.00032 -0.00224 3864 758 1 5 0 12.680 25.58 20.00 22.66 32.08 18.2 1036.44 -1663 -2793 -4074 -4659 -3480 -1767 -446 317 -706 -1610 -1185 42 253 353 85 -486 -324 37 196 25 -26 525 724 453 200 -431 -1119 -835 199 884 1350 1645 305 -1155 -1068 -396 -87 593 226 -500 -690 -856 -907 -802 -647 -843 -841 -854 -296 496 703 950 999 779 656 743 486 371 629 972 1276 1453 1241 400 -65 -46 3 649 897 461 -37 -187 -331 -432 -262 -132 18 330 328 -151 -549 -1154 -1298 -1092 -906 -743 -363 -269 -125 -6 246 251 718 909 744 649 695 177 -316 -376 -402 -353 240 -118 -719 -595 -562 -407 8 -54 -36 -63 -13 63 278 540 394 306 -47 -421 -378 -67 -100 284 463 561 1089 885 541 400 155 149 163 243 -193 -189 43 -126 -344 -106 -293 -276 -257 -167 -302 -444 -474 -323 -174 -43 34 -83 -196 -145 5 36 58 16 -98 -68 8 44 6 -6 125 177 117 54 -121 -310 -218 49 216 349 458 92 -353 -314 -117 -28 224 102 -239 -359 -467 -507 -452 -364 -472 -463 -459 -156 264 394 567 631 517 449 521 345 263 439 678 920 1122 961 328 -53 -35 2 490 723 386 -34 -178 -315 -396 -223 -109 13 239 249 -128 -487 -1130 -1361 -1127 -996 -872 -448 -342 -158 -7 278 279 732 902 776 694 823 231 -411 -484 -521 -425 275 -140 -912 -800 -743 -562 12 -83 -55 -97 -19 93 380 739 535 405 -66 -635 -586 -104 -150 408 632 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