File name: Pandora21s1_Bremen_20200701_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T042943.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200701_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200701T083515.5Z 7487.357819 307 1 13.08 2 44.36 115.36 141.43 13.77 0.00 1 0.00 1 0 17 8.146e-03 5.566e-03 2.715e-03 1.513e-03 1.991125e-01 8.102084e-04 2.644783e-03 -6.000000e+00 4.945218e-03 233.86 -2.00 3.88 -2.00 315.78 0.00e+00 7.374788e-05 7.308358e-05 2.861883e-05 -6.000000e+00 1.949068e-04 281.53 -2.00 20.00 -2.00 315.47 0.00e+00 1.397 0.000 302.00 328.00 3 4.2647e+00 2.1260e-03 1.8240e-02 -6.0000e+00 1.2553e-02 2.2940e-02 2.3523e-03 1.1534e-02 -6.0000e+00 1.3596e-02 3.0878e-03 1.3449e-03 5.6045e-03 -6.0000e+00 7.9530e-03 -2.8911e-03 5.9441e-04 1.5394e-03 -6.0000e+00 3.2497e-03 1.4826e-03 2.6106e-04 4.6849e-05 2.1325e-05 -6.0000e+00 2.4537e-04 -5.8615e-03 2.0442e-04 12 1 1 12 1 1 99.97 22.51 0.15 -0.00586 -0.00390 23 18 1 5 0 537.906 25.39 19.99 22.51 26.21 17.9 994.19 -2027 -939 -3962 -2444 -1139 916 1138 2073 563 -1086 14 948 1568 248 1009 -509 -325 319 266 425 -358 895 453 1066 369 -71 -1133 -735 -103 728 1824 1245 340 -1229 124 -128 61 664 205 -648 -705 -989 -1286 -866 -844 -644 -1199 -900 -328 546 762 643 820 1017 766 525 595 418 596 946 1457 1402 930 166 -505 202 -131 813 658 516 -145 -377 -301 -504 -323 -251 178 352 520 -292 -650 -1048 -1221 -999 -919 -699 -351 -224 -248 -185 353 358 777 930 813 628 690 -87 -400 -347 -310 -196 325 159 -872 -580 -596 -307 -32 201 -312 -99 -43 132 442 516 445 234 -21 -414 -484 -140 -19 320 464 726 1009 814 630 352 258 236 269 189 -248 -195 47 -257 -405 -251 -169 -341 -258 -485 -233 -1000 -568 -243 188 248 493 145 -291 4 257 460 81 357 -192 -126 126 108 176 -151 374 194 470 170 -33 -526 -325 -43 299 769 554 159 -580 56 -58 30 363 127 -444 -512 -740 -979 -660 -642 -486 -894 -654 -234 389 558 491 648 825 634 441 504 354 499 792 1246 1252 872 160 -486 184 -114 691 583 490 -145 -391 -311 -511 -313 -228 151 288 435 -263 -629 -1078 -1309 -1107 -1060 -840 -435 -283 -313 -229 416 398 815 952 854 697 814 -109 -517 -446 -385 -232 375 187 -1076 -742 -784 -413 -44 287 -457 -145 -61 182 576 649 555 299 -28 -574 -685 -197 -26 434 611 925 1245 1001 796 463 348 324 373 268 -362 -293 72 -400 -635 -390 -258 -511 -381 SS 20200701T084939.8Z 7487.367822 316 1 11.56 2 42.44 119.29 140.90 18.99 0.00 1 0.00 1 0 17 8.774e-03 5.893e-03 7.134e-03 3.799e-03 2.040967e-01 2.031286e-03 2.696191e-03 -6.000000e+00 5.325383e-03 233.86 -2.00 3.88 -2.00 315.94 0.00e+00 2.096258e-04 1.898017e-04 3.159960e-05 -6.000000e+00 2.099217e-04 281.53 -2.00 20.00 -2.00 315.62 0.00e+00 1.353 0.000 302.00 328.00 3 5.7070e+00 5.3362e-03 1.8115e-02 -6.0000e+00 1.3518e-02 4.9311e-02 5.9083e-03 1.1792e-02 -6.0000e+00 1.4642e-02 -4.4964e-03 3.3859e-03 5.7310e-03 -6.0000e+00 8.5647e-03 -2.3149e-04 1.5083e-03 1.5745e-03 -6.0000e+00 3.4993e-03 3.5813e-04 -9.2953e-05 1.1750e-04 2.1367e-05 -6.0000e+00 2.6427e-04 -5.9552e-03 1.6772e-04 12 1 1 12 9 1 99.95 22.51 0.13 -0.00596 -0.00665 4 4 1 5 0 2277.338 25.39 19.99 22.51 26.58 17.9 995.51 -645 -1733 -1961 -3532 480 -2313 -1111 -150 -408 -3005 1578 1231 1259 879 76 -84 -1174 101 362 1754 -326 1096 -192 71 1485 129 -843 -890 1764 977 1268 1691 -235 -1395 -802 -316 -332 377 -1100 -661 -867 -796 -122 -451 44 -528 -753 -1376 -622 937 1016 1309 1426 758 29 570 641 790 811 760 980 1131 1180 401 -118 109 302 -785 861 44 406 -97 22 -1009 -168 -249 -625 -731 -721 -714 -728 -1373 -1764 -604 -1031 -603 4 223 276 -254 218 -4 -258 225 90 990 834 240 769 -230 -230 83 -72 546 -1011 -571 -801 141 -133 127 380 169 53 -88 -72 -245 4 341 -98 -698 12 445 505 271 354 513 649 1024 210 125 107 136 -225 -263 -158 -469 542 185 -178 200 124 -686 -753 -143 -407 -457 -778 94 -457 -230 -34 -99 -766 386 312 348 270 26 -30 -438 38 140 688 -132 437 -79 30 648 58 -375 -377 695 382 512 718 -106 -634 -350 -138 -156 199 -670 -444 -619 -585 -91 -338 33 -392 -550 -986 -436 651 728 978 1105 609 24 473 536 659 671 629 830 1003 1097 386 -112 99 259 -666 754 41 406 -100 23 -1024 -161 -224 -525 -593 -599 -637 -700 -1411 -1898 -668 -1194 -728 5 283 350 -316 258 -5 -271 230 94 1094 985 302 995 -298 -288 99 -83 640 -1253 -734 -1061 191 -186 182 560 251 77 -123 -95 -311 5 437 -131 -976 18 631 705 370 466 654 802 1255 266 165 145 187 -314 -375 -233 -714 837 291 -282 313 190 -1038 -1125 SS 20200701T115348.3Z 7487.495698 427 1 0.55 2 30.41 191.44 122.63 71.81 0.00 1 0.00 1 0 25 9.588e-03 7.526e-03 6.708e-03 4.967e-03 1.759014e-01 2.699511e-03 2.353657e-03 -6.000000e+00 5.815914e-03 233.86 -2.00 3.88 -2.00 314.56 0.00e+00 -2.599703e-04 1.905690e-04 1.592863e-05 -6.000000e+00 2.294864e-04 281.54 -2.00 20.00 -2.00 314.30 0.00e+00 1.159 0.000 302.00 328.00 3 2.9701e+00 7.0106e-03 1.5558e-02 -6.0000e+00 1.4763e-02 2.5863e-02 7.7298e-03 1.0167e-02 -6.0000e+00 1.5993e-02 -1.1891e-03 4.3911e-03 4.9423e-03 -6.0000e+00 9.3551e-03 -1.2625e-03 1.8505e-03 1.3523e-03 -6.0000e+00 3.8202e-03 7.1517e-03 -8.8080e-04 1.5180e-04 2.0594e-05 -6.0000e+00 2.8887e-04 -5.9716e-03 -6.4484e-06 12 9 1 12 1 1 999.00 22.55 0.22 -0.00597 -0.01259 1 52 1 5 0 188.485 25.47 20.01 22.55 27.09 18.2 1001.27 -632 -1353 -1667 -3507 -891 1186 698 597 -2759 -565 -1126 1857 1258 1701 -1200 972 134 273 -78 785 392 217 2017 621 642 -467 -582 -508 1267 1585 1408 2288 -828 -1717 140 -883 491 499 2015 -1152 107 -1282 -1801 -1448 -468 -730 -98 -1135 -947 -415 937 1302 1848 528 218 -88 93 1039 757 1610 1446 1027 1539 -726 -856 -352 550 274 -899 41 124 -1084 -617 -450 -203 -136 -420 1068 906 -90 -810 -1390 -1204 -806 -940 -1369 171 -232 89 521 454 389 695 1123 871 1181 -92 369 -65 -136 397 -572 628 -447 -76 -981 -219 -799 -178 -892 110 -336 176 429 -9 569 132 536 134 -269 -681 -591 192 40 850 603 910 1387 361 102 880 149 -37 585 -377 89 -127 113 -671 -385 -668 21 -368 -242 -537 -656 -1322 -311 402 248 228 -1136 -233 -464 766 551 796 -608 503 71 147 -43 435 219 121 1131 361 383 -284 -348 -293 695 855 776 1297 -492 -1023 80 -510 297 331 1456 -911 88 -1084 -1543 -1241 -398 -618 -81 -929 -763 -333 763 1091 1586 466 195 -80 85 942 683 1447 1325 976 1511 -737 -859 -338 504 247 -843 41 128 -1149 -653 -467 -203 -129 -378 925 798 -84 -803 -1448 -1296 -890 -1075 -1626 207 -287 109 630 529 431 733 1155 914 1292 -106 446 -81 -168 477 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