File name: Pandora21s1_Bremen_20200708_L2Fit_fwvt1c14d20191026p1-8.txt File generation date: 20250507T103708.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v14d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200708_L1_smca1c14d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1712 1862 Nominal wavelengths inside fitting window [nm]: 492.0415 492.1620 492.2825 492.4029 492.5233 492.6437 492.7641 492.8844 493.0048 493.1251 493.2454 493.3657 493.4860 493.6063 493.7265 493.8468 493.9670 494.0872 494.2074 494.3275 494.4477 494.5678 494.6879 494.8081 494.9281 495.0482 495.1683 495.2883 495.4083 495.5283 495.6483 495.7683 495.8883 496.0082 496.1281 496.2480 496.3679 496.4878 496.6077 496.7275 496.8474 496.9672 497.0870 497.2067 497.3265 497.4463 497.5660 497.6857 497.8054 497.9251 498.0448 498.1644 498.2840 498.4037 498.5233 498.6429 498.7624 498.8820 499.0015 499.1210 499.2405 499.3600 499.4795 499.5990 499.7184 499.8378 499.9572 500.0766 500.1960 500.3154 500.4347 500.5540 500.6734 500.7927 500.9119 501.0312 501.1504 501.2697 501.3889 501.5081 501.6273 501.7464 501.8656 501.9847 502.1039 502.2230 502.3420 502.4611 502.5802 502.6992 502.8182 502.9372 503.0562 503.1752 503.2942 503.4131 503.5320 503.6509 503.7698 503.8887 504.0076 504.1264 504.2452 504.3641 504.4829 504.6016 504.7204 504.8391 504.9579 505.0766 505.1953 505.3140 505.4327 505.5513 505.6699 505.7886 505.9072 506.0258 506.1443 506.2629 506.3814 506.4999 506.6185 506.7369 506.8554 506.9739 507.0923 507.2107 507.3292 507.4476 507.5659 507.6843 507.8026 507.9210 508.0393 508.1576 508.2759 508.3941 508.5124 508.6306 508.7488 508.8670 508.9852 509.1034 509.2215 509.3397 509.4578 509.5759 509.6940 509.8121 509.9301 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200708T064723.9Z 7494.282916 287 1 11.83 2 60.73 91.06 93.28 243.35 0.00 1 0.00 1 0 15 2.724e-03 2.712e-03 1.715e-03 1.712e-03 2.203673e+03 9.780191e+01 1.625924e+02 -6.000000e+00 1.449326e+02 282.16 -2.00 20.00 -2.00 505.26 0.00e+00 7.757698e-04 4.613061e-05 4.105412e-05 -6.000000e+00 7.496257e-05 282.16 -2.00 20.00 -2.00 500.41 0.00e+00 2.303980e-01 3.337992e-02 1.651382e-02 -6.000000e+00 5.336922e-02 233.97 -2.00 3.88 -2.00 502.01 0.00e+00 2.036 0.000 489.00 513.00 1 7.6175e+00 2.5501e-03 3.3610e-03 -6.0000e+00 4.0778e-03 5.6187e-03 6.6871e-04 4.1443e-04 -6.0000e+00 1.0743e-03 7.0060e-04 2.3217e-03 1.4633e-04 2.4340e-05 -6.0000e+00 2.3885e-04 -1.7089e-03 -2.8699e-05 12 1 1 12 1 1 85.17 22.46 1.44 -0.00171 0.01440 3 3 1 4 0 2914.460 25.39 20.00 22.46 22.90 18.1 1007.22 -607 -266 -478 -138 75 108 275 210 220 448 251 -36 -9 8 -342 -369 -106 20 245 238 387 -183 131 129 335 446 198 81 32 -563 -384 172 -116 297 194 199 201 -248 -175 29 -340 -29 -27 132 191 -129 154 491 -66 66 -576 -385 -562 -554 -183 -59 -192 169 -408 233 196 286 428 345 179 245 161 60 45 137 -386 -329 -326 -187 60 100 7 98 -200 -181 -526 -133 -135 -384 -299 29 -101 -272 276 -269 -14 177 479 345 56 175 60 -45 -163 -227 -477 -312 -326 -280 -50 47 -156 152 -169 -637 80 23 -150 -107 408 319 341 458 448 38 -15 227 -27 90 473 144 -61 333 36 119 243 202 138 -147 -240 -345 -287 270 221 99 431 -114 133 75 215 -325 55 -153 -381 -440 -303 -590 -260 -476 -140 78 112 289 222 232 468 259 -37 -9 8 -345 -372 -108 21 255 250 406 -193 138 136 353 470 208 84 33 -571 -384 172 -117 304 203 210 210 -258 -181 30 -348 -30 -28 137 200 -136 161 508 -67 67 -576 -378 -546 -539 -180 -59 -196 173 -419 238 200 292 438 353 183 247 161 60 44 134 -375 -319 -318 -184 60 99 7 95 -193 -173 -506 -129 -131 -373 -293 28 -99 -269 271 -265 -14 176 479 348 56 174 60 -44 -156 -215 -447 -293 -311 -273 -49 47 -155 149 -164 -619 78 23 -149 -107 408 320 344 462 451 38 -15 223 -26 88 463 141 -60 327 35 117 238 196 132 -140 -227 -327 -274 261 216 97 425 -113 132 75 215 -324 54 -150 -366 -419 -289 SQ 20200708T065652.0Z 7494.289490 290 1 3.94 2 59.31 92.98 94.49 245.16 0.00 1 0.00 1 0 15 2.477e-03 2.457e-03 7.858e-04 7.844e-04 1.989070e+03 4.445909e+01 1.491473e+02 -6.000000e+00 1.317686e+02 282.16 -2.00 20.00 -2.00 505.25 0.00e+00 6.113593e-04 2.111401e-05 3.400202e-05 -6.000000e+00 6.815372e-05 282.16 -2.00 20.00 -2.00 500.40 0.00e+00 1.284497e-01 1.528133e-02 1.438862e-02 -6.000000e+00 4.851628e-02 233.97 -2.00 3.88 -2.00 502.00 0.00e+00 1.951 0.000 489.00 513.00 1 5.1292e+00 1.1675e-03 3.1385e-03 -6.0000e+00 3.7071e-03 1.1406e-02 3.0642e-04 3.7291e-04 -6.0000e+00 9.7645e-04 8.6261e-03 2.1293e-03 6.7119e-05 2.1695e-05 -6.0000e+00 2.1715e-04 4.7293e-04 -3.1097e-05 12 1 1 12 1 1 87.56 22.47 1.51 0.00047 0.01524 13 42 1 4 0 235.780 25.39 19.99 22.47 23.27 18.1 1008.60 -638 -495 -202 242 214 134 519 384 336 191 -104 -27 -44 -150 -360 -224 -3 -22 240 266 228 199 207 113 263 271 295 128 169 -85 -245 -415 -253 12 237 207 104 -97 -79 -188 -189 -95 -91 -53 149 125 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28 -91 -116 -21 -79 177 90 288 64 229 155 190 165 81 -149 -263 -399 -592 -410 SQ 20200708T070731.4Z 7494.296891 294 1 6.78 2 57.72 95.18 95.89 247.19 0.00 1 0.00 1 0 15 2.324e-03 2.308e-03 2.478e-04 2.473e-04 1.946478e+03 1.399739e+01 1.455620e+02 -6.000000e+00 1.236403e+02 282.16 -2.00 20.00 -2.00 505.26 0.00e+00 6.245246e-04 6.667699e-06 3.519730e-05 -6.000000e+00 6.394952e-05 282.16 -2.00 20.00 -2.00 500.43 0.00e+00 1.285129e-01 4.815291e-03 1.424342e-02 -6.000000e+00 4.552489e-02 233.97 -2.00 3.88 -2.00 502.02 0.00e+00 1.865 0.000 489.00 513.00 1 3.5696e+00 3.6790e-04 3.0326e-03 -6.0000e+00 3.4785e-03 8.3914e-03 9.6560e-05 3.6446e-04 -6.0000e+00 9.1629e-04 4.1529e-02 2.2047e-03 2.1168e-05 2.1533e-05 -6.0000e+00 2.0375e-04 8.0274e-04 -3.6360e-05 12 1 1 12 1 1 90.62 22.46 1.50 0.00080 0.01610 135 110 1 4 0 48.285 25.39 20.00 22.46 23.59 18.1 1010.27 -505 -396 -241 10 266 295 427 383 350 265 4 2 -103 -190 -215 -172 -12 9 155 275 235 225 171 154 235 320 347 135 82 -93 -391 -322 -196 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