File name: Pandora21s1_Bremen_20200722_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T044955.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200722_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200722T092203.6Z 7508.390319 12 1 51.15 2 41.24 130.44 55.79 107.24 0.00 1 0.00 1 0 17 7.883e-03 5.183e-03 4.186e-04 1.956e-04 1.851777e-01 1.040124e-04 2.453630e-03 -6.000000e+00 4.781601e-03 233.71 -2.00 3.88 -2.00 316.41 0.00e+00 1.342754e-04 1.071616e-05 3.218907e-05 -6.000000e+00 1.886035e-04 282.77 -2.00 20.00 -2.00 316.08 0.00e+00 1.328 0.000 302.00 328.00 3 1.1659e+00 2.7463e-04 1.7188e-02 -6.0000e+00 1.2133e-02 1.6818e-03 3.0457e-04 1.0739e-02 -6.0000e+00 1.3143e-02 5.2620e-03 1.7607e-04 5.2233e-03 -6.0000e+00 7.6893e-03 -3.6782e-03 7.9633e-05 1.4417e-03 -6.0000e+00 3.1421e-03 3.6413e-02 2.7043e-04 6.1387e-06 1.8997e-05 -6.0000e+00 2.3742e-04 -4.6150e-03 1.9233e-04 10 0 0 10 0 0 99.92 22.52 0.23 -0.00462 -0.00258 4111 806 1 5 0 11.848 25.47 19.99 22.52 27.19 18.7 1028.29 -892 -2076 -3109 -3540 -1869 -526 962 1265 231 -653 -164 761 760 824 180 -309 -67 303 442 316 324 833 945 703 352 -258 -946 -593 633 1126 1513 1698 365 -992 -702 -18 156 644 171 -554 -758 -874 -976 -847 -832 -974 -918 -921 -317 525 667 907 911 710 599 718 488 415 712 1044 1275 1305 1053 198 -262 -154 -30 634 879 379 -150 -208 -305 -424 -227 -39 160 573 429 -113 -571 -1243 -1304 -1051 -878 -745 -400 -301 -180 -74 219 261 835 1038 829 678 693 160 -335 -358 -334 -227 389 41 -653 -516 -528 -347 69 -15 -113 -128 -59 35 277 553 433 346 -28 -422 -435 -105 -167 279 463 548 1085 925 537 339 123 95 150 255 -175 -173 58 -132 -358 -117 -273 -254 -237 -173 -427 -634 -667 -316 -86 165 240 48 -139 -35 165 180 218 53 -97 -22 100 150 110 114 291 337 263 137 -103 -371 -218 216 374 519 617 141 -386 -260 -7 63 302 95 -352 -520 -624 -661 -620 -605 -702 -643 -624 -208 342 452 648 683 554 445 543 374 316 575 843 988 1077 931 184 -239 -130 -25 515 754 337 -146 -210 -307 -414 -206 -34 128 433 335 -98 -512 -1224 -1367 -1158 -1031 -872 -492 -380 -227 -90 264 287 835 997 827 736 828 195 -432 -457 -432 -272 447 49 -834 -653 -699 -478 99 -23 -177 -202 -89 49 357 716 554 459 -37 -601 -642 -154 -239 383 602 726 1361 1151 700 469 167 131 211 370 -267 -278 96 -211 -578 -198 -450 -406 -371 SS 20200722T093156.6Z 7508.397183 18 1 51.25 2 40.14 133.57 54.44 109.48 0.00 1 0.00 1 0 17 7.732e-03 5.125e-03 4.914e-04 2.298e-04 1.818494e-01 1.221722e-04 2.412782e-03 -6.000000e+00 4.690366e-03 233.71 -2.00 3.88 -2.00 316.41 0.00e+00 1.622508e-04 1.257114e-05 3.165036e-05 -6.000000e+00 1.849935e-04 282.77 -2.00 20.00 -2.00 316.07 0.00e+00 1.307 0.000 302.00 328.00 3 1.4491e+00 3.2286e-04 1.6902e-02 -6.0000e+00 1.1902e-02 -1.3603e-03 3.5785e-04 1.0554e-02 -6.0000e+00 1.2892e-02 5.8112e-03 2.0688e-04 5.1363e-03 -6.0000e+00 7.5425e-03 -3.9004e-03 9.3702e-05 1.4197e-03 -6.0000e+00 3.0823e-03 2.8235e-02 3.5048e-04 7.2303e-06 1.8821e-05 -6.0000e+00 2.3288e-04 -4.6899e-03 2.0206e-04 10 0 0 10 0 0 99.99 22.53 0.22 -0.00469 -0.00206 3629 712 1 5 0 13.469 25.47 20.00 22.53 27.31 18.6 1028.86 -953 -1525 -3054 -3425 -1740 -259 1335 1182 438 -744 164 693 1022 567 228 -278 -123 381 256 322 147 949 793 703 283 -354 -931 -654 545 920 1583 1557 298 -1172 -722 -78 168 685 81 -596 -834 -880 -1076 -856 -801 -978 -903 -927 -215 495 725 879 1026 673 668 744 587 472 707 1077 1252 1389 1046 267 -307 -77 -65 618 902 375 -114 -244 -283 -454 -231 -110 145 499 345 -159 -646 -1167 -1335 -1032 -930 -692 -373 -265 -193 -105 227 162 724 924 796 600 698 175 -312 -343 -366 -235 364 42 -673 -480 -513 -332 69 14 -14 -72 -29 6 277 524 451 343 -7 -408 -452 -95 -159 292 430 567 1059 929 515 347 101 61 112 202 -170 -210 78 -125 -315 -76 -273 -256 -232 -186 -313 -626 -648 -295 -42 229 225 91 -159 35 150 242 151 67 -87 -40 125 87 112 52 330 282 261 110 -141 -364 -239 185 305 539 562 114 -453 -265 -31 67 319 45 -375 -567 -622 -777 -620 -577 -697 -626 -621 -139 318 484 620 758 519 527 598 477 382 563 858 1030 1136 917 245 -277 -64 -53 494 761 329 -109 -243 -282 -438 -208 -96 114 371 266 -136 -613 -1134 -1382 -1121 -1078 -855 -454 -332 -241 -136 270 177 716 939 783 642 821 226 -398 -433 -466 -278 412 49 -848 -641 -672 -452 97 21 -21 -112 -44 8 377 667 567 448 -10 -574 -659 -137 -226 396 590 738 1308 1138 660 472 144 88 156 289 -258 -334 127 -210 -534 -127 -444 -404 -358 SS 20200722T093700.7Z 7508.400703 21 1 27.42 2 39.60 135.22 53.75 110.66 0.00 1 0.00 1 0 17 7.896e-03 5.329e-03 3.133e-04 1.617e-04 1.804074e-01 8.580053e-05 2.397206e-03 -6.000000e+00 4.789425e-03 233.71 -2.00 3.88 -2.00 316.14 0.00e+00 1.476073e-04 8.340134e-06 2.811123e-05 -6.000000e+00 1.889066e-04 282.77 -2.00 20.00 -2.00 315.82 0.00e+00 1.297 0.000 302.00 328.00 3 4.1145e-01 2.2605e-04 1.6764e-02 -6.0000e+00 1.2153e-02 -6.4507e-03 2.5057e-04 1.0462e-02 -6.0000e+00 1.3165e-02 4.8099e-03 1.4386e-04 5.0846e-03 -6.0000e+00 7.7019e-03 -3.2351e-03 6.4202e-05 1.3997e-03 -6.0000e+00 3.1473e-03 8.0928e-02 2.9082e-04 5.0247e-06 1.8926e-05 -6.0000e+00 2.3781e-04 -4.6990e-03 1.9548e-04 10 0 0 10 0 0 99.96 22.53 0.27 -0.00470 -0.00251 3189 626 1 5 0 8.215 25.47 19.99 22.53 27.36 18.6 1028.37 -925 -1956 -3169 -3437 -2008 -376 927 1237 84 -746 -158 693 691 711 256 -257 -48 351 518 361 428 940 950 655 365 -249 -931 -502 500 1155 1503 1757 345 -1042 -690 -1 183 655 118 -655 -828 -920 -1078 -902 -819 -949 -946 -895 -310 505 675 883 873 693 616 721 527 385 718 1056 1267 1320 1017 157 -305 -184 -37 674 867 342 -164 -256 -319 -418 -248 -69 153 563 424 -181 -611 -1231 -1311 -1051 -915 -771 -406 -314 -211 -107 210 204 799 1013 817 643 710 179 -326 -356 -299 -231 395 68 -632 -497 -526 -365 27 -30 -91 -129 -70 25 312 570 471 355 -3 -427 -434 -117 -144 260 472 557 1117 948 547 360 115 81 128 253 -187 -184 41 -159 -349 -123 -287 -280 -222 -198 -443 -714 -714 -409 -74 191 282 19 -175 -40 180 180 207 82 -88 -17 126 191 137 164 358 369 266 155 -108 -398 -200 185 416 559 691 144 -439 -277 0 80 332 71 -414 -566 -655 -784 -657 -593 -681 -660 -603 -219 354 454 626 649 537 489 582 430 313 575 846 1048 1164 960 144 -296 -165 -31 541 735 323 -156 -256 -318 -404 -240 -60 121 456 328 -155 -582 -1287 -1355 -1142 -1059 -953 -493 -392 -263 -138 251 222 850 1033 866 688 836 231 -414 -447 -380 -274 447 80 -797 -664 -686 -496 38 -44 -141 -201 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