File name: Pandora21s1_Bremen_20200904_L2Fit_fout2c2d20191026p1-8.txt File generation date: 20240830T050637.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v2d20191026.txt Level 1 file used: Pandora21s1_Bremen_20200904_L1_smca1c2d20191026p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20200904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 286 428 Nominal wavelengths inside fitting window [nm]: 305.1190 305.2593 305.3995 305.5398 305.6801 305.8203 305.9606 306.1008 306.2410 306.3812 306.5214 306.6616 306.8018 306.9419 307.0821 307.2222 307.3624 307.5025 307.6426 307.7827 307.9228 308.0629 308.2029 308.3430 308.4830 308.6231 308.7631 308.9031 309.0431 309.1831 309.3231 309.4631 309.6031 309.7430 309.8830 310.0229 310.1628 310.3027 310.4426 310.5825 310.7224 310.8623 311.0021 311.1420 311.2818 311.4216 311.5615 311.7013 311.8411 311.9809 312.1206 312.2604 312.4002 312.5399 312.6796 312.8194 312.9591 313.0988 313.2385 313.3781 313.5178 313.6575 313.7971 313.9368 314.0764 314.2160 314.3556 314.4952 314.6348 314.7744 314.9139 315.0535 315.1930 315.3325 315.4721 315.6116 315.7511 315.8906 316.0300 316.1695 316.3090 316.4484 316.5879 316.7273 316.8667 317.0061 317.1455 317.2849 317.4242 317.5636 317.7030 317.8423 317.9816 318.1209 318.2603 318.3995 318.5388 318.6781 318.8174 318.9566 319.0959 319.2351 319.3743 319.5135 319.6527 319.7919 319.9311 320.0703 320.2094 320.3486 320.4877 320.6268 320.7659 320.9050 321.0441 321.1832 321.3223 321.4613 321.6004 321.7394 321.8785 322.0175 322.1565 322.2955 322.4345 322.5734 322.7124 322.8513 322.9903 323.1292 323.2681 323.4070 323.5459 323.6848 323.8237 323.9625 324.1014 324.2402 324.3791 324.5179 324.6567 324.7955 324.9343 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200904T063020.8Z 7552.271074 258 1 5.64 2 74.45 99.22 89.06 263.39 0.00 1 0.00 1 0 25 9.102e-02 8.665e-03 8.671e-02 5.774e-03 4.653122e-01 3.026917e-03 6.035847e-03 -6.000000e+00 5.439996e-02 229.98 -2.00 3.88 -2.00 319.39 0.00e+00 9.783666e-04 7.214580e-04 2.331585e-04 -6.000000e+00 2.178671e-03 280.65 -2.00 20.00 -2.00 319.07 0.00e+00 3.662 0.001 302.00 328.00 3 3.2841e+00 8.3376e-03 4.5388e-02 -6.0000e+00 1.3677e-01 5.3934e-02 9.5572e-03 2.7014e-02 -6.0000e+00 1.4864e-01 -2.8280e-02 7.9172e-03 1.3616e-02 -6.0000e+00 8.7221e-02 3.7136e-03 4.2460e-03 3.9945e-03 -6.0000e+00 3.5884e-02 3.0379e-04 -1.3811e-03 1.7858e-04 4.8655e-05 -6.0000e+00 2.7401e-03 -7.7767e-03 -2.5964e-04 12 9 1 12 1 1 -5.41 22.47 0.26 -0.00778 -0.01815 5 11 1 5 0 910.709 25.39 20.00 22.47 22.48 19.9 1006.69 19401 5128 1732 -19727 37270 -32715 11072 -53086 35251 -38669 -20519 -3005 -8175 -2470 -7980 16708 3294 9554 -18066 -775 -3559 6462 3224 -2620 2150 -476 15830 -9270 9513 -5691 -3 -10665 3653 -11052 -6266 -513 1066 3682 -2086 3541 -4618 2227 -1574 -639 3602 591 3495 -4239 -2507 -134 4381 2467 3283 -207 386 1148 609 990 -2234 2516 -1515 1512 1794 1692 716 2300 1648 -408 3131 160 235 -1001 169 -1366 126 -1641 -1755 -469 -1103 472 -915 -1656 -2557 -584 -897 -329 1005 -12 417 -778 -158 -1393 -282 -244 462 247 654 1301 -184 331 -789 -169 -584 -183 -1671 -587 -227 117 1055 453 1037 497 1848 483 -48 276 -118 -403 -1133 -413 -254 373 -879 86 461 282 875 -127 -210 210 239 -522 -196 -231 -104 -437 -47 225 -378 57 361 211 17 299 98 35 -461 499 -827 207 -1970 652 -1460 -692 -97 -325 -111 -440 827 200 587 -1506 -58 -277 467 252 -231 193 -45 1300 -930 797 -576 0 -1420 467 -1658 -882 -70 159 628 -444 821 -1259 603 -456 -187 1026 175 1014 -1327 -791 -43 1464 907 1281 -88 170 518 281 454 -1040 1127 -726 759 975 980 424 1308 920 -235 1883 108 170 -755 125 -992 85 -1040 -1051 -277 -699 329 -716 -1417 -2339 -551 -890 -341 1071 -13 455 -834 -161 -1355 -261 -228 454 265 762 1631 -244 437 -1010 -203 -676 -213 -2052 -745 -298 159 1499 683 1633 805 2945 754 -72 401 -172 -601 -1765 -661 -409 592 -1379 131 681 406 1227 -182 -315 334 398 -904 -348 -422 -196 -857 -94 453 -766 114 699 398 32 SS 20200904T063532.5Z 7552.274682 261 1 51.00 2 73.68 100.30 89.80 264.41 0.00 1 0.00 1 0 25 3.162e-02 4.505e-03 1.150e-02 6.927e-04 4.411181e-01 3.641231e-04 5.630140e-03 -6.000000e+00 1.891063e-02 229.98 -2.00 3.88 -2.00 319.86 0.00e+00 6.938280e-04 9.747554e-05 2.538218e-04 -6.000000e+00 7.568742e-04 280.65 -2.00 20.00 -2.00 319.54 0.00e+00 3.500 0.001 302.00 328.00 3 1.0375e+00 1.0181e-03 4.3212e-02 -6.0000e+00 4.7545e-02 9.4902e-03 1.1879e-03 2.5579e-02 -6.0000e+00 5.1663e-02 3.2285e-03 1.0562e-03 1.3045e-02 -6.0000e+00 3.0315e-02 -9.2014e-03 5.6255e-04 3.9100e-03 -6.0000e+00 1.2476e-02 3.5127e-03 -8.3392e-04 2.2327e-05 4.7968e-05 -6.0000e+00 9.5172e-04 -3.9561e-03 3.5211e-05 10 0 0 10 0 0 94.83 22.47 0.16 -0.00396 -0.01022 849 167 1 5 0 58.949 25.39 20.00 22.47 22.64 19.9 1007.38 -5284 -8352 -9228 -15579 -15839 -2989 -19134 792 -10163 -3066 -5980 -6809 -1752 -561 -339 -2641 2106 -2556 189 -412 858 496 -316 573 -3223 -961 -3601 -557 -2217 292 67 2657 360 -1485 315 -1532 368 -307 -213 -1648 -1007 -1677 -1602 -1247 -1240 -696 -1558 -222 -491 538 315 964 868 779 887 618 481 20 714 531 1408 1458 1340 698 218 347 448 1188 952 572 -25 2 -389 -487 -384 -275 262 235 465 -208 -303 -1194 -1213 -1015 -830 -545 -246 -83 -63 293 510 610 1001 1211 891 847 881 217 -315 -479 -362 -397 408 -154 -813 -697 -642 -374 54 -18 -144 -42 23 186 356 672 431 263 -282 -703 -623 -298 -236 35 261 405 992 884 339 240 34 112 70 255 -298 -178 107 -60 -324 -15 -103 -64 37 -83 -149 -170 -291 -280 -47 -388 15 -237 -71 -149 -192 -52 -20 -14 -127 105 -144 11 -25 53 31 -21 38 -239 -72 -278 -43 -172 23 6 243 37 -160 32 -164 43 -43 -36 -329 -221 -393 -390 -308 -309 -174 -394 -56 -126 144 91 303 295 283 337 244 194 8 282 210 574 646 614 347 110 169 210 562 491 333 -16 1 -259 -310 -226 -146 137 122 260 -125 -208 -924 -1017 -903 -787 -518 -245 -85 -65 288 497 550 848 1025 815 870 962 266 -414 -630 -448 -453 435 -167 -947 -860 -835 -513 79 -27 -233 -70 37 290 521 986 630 401 -431 -1136 -1021 -479 -367 56 396 587 1379 1247 518 379 57 200 130 494 -584 -367 228 -130 -705 -32 -210 -125 74 SS 20200904T064051.4Z 7552.278372 264 1 50.74 2 72.90 101.41 90.56 265.45 0.00 1 0.00 1 0 25 2.383e-02 4.427e-03 1.131e-02 7.687e-04 4.222478e-01 4.072860e-04 5.447299e-03 -6.000000e+00 1.425637e-02 229.98 -2.00 3.88 -2.00 319.76 0.00e+00 4.113236e-04 1.050931e-04 2.341182e-04 -6.000000e+00 5.703807e-04 280.65 -2.00 20.00 -2.00 319.44 0.00e+00 3.350 0.001 302.00 328.00 3 1.3531e+00 1.1364e-03 4.1425e-02 -6.0000e+00 3.5844e-02 3.3784e-03 1.3139e-03 2.4592e-02 -6.0000e+00 3.8945e-02 7.6729e-03 1.1292e-03 1.2503e-02 -6.0000e+00 2.2852e-02 -9.5546e-03 6.0161e-04 3.7325e-03 -6.0000e+00 9.4069e-03 3.0313e-03 -5.3329e-04 2.4865e-05 4.7552e-05 -6.0000e+00 7.1725e-04 -4.4183e-03 9.2032e-05 10 0 0 10 0 0 99.97 22.47 0.18 -0.00442 -0.00843 799 157 1 5 0 62.635 25.39 19.99 22.47 22.89 19.9 1009.17 -4615 -4161 -14462 -2529 -13726 1758 -11902 341 -4194 -4025 -1356 -1837 2081 -4922 3476 -3454 1311 -1279 1139 -958 -1224 1089 -498 1969 -1808 -1002 -2948 -219 -809 1493 2608 817 -328 -1881 -28 -2057 104 -1058 18 -1468 -1324 -1264 -1801 -1127 -1349 -193 -1598 -491 -1041 670 234 857 1085 297 888 129 677 26 908 436 1518 1741 1467 657 31 386 138 1084 748 630 -195 -211 -265 -487 -73 -158 236 441 744 -98 -257 -1057 -1142 -1024 -864 -629 -283 -62 -119 424 303 578 1097 1225 903 638 888 52 -236 -487 -291 -414 442 -24 -877 -653 -587 -298 33 15 -173 -85 5 124 448 622 448 195 -169 -671 -572 -262 -283 121 293 403 926 893 304 311 12 175 91 276 -208 -165 179 -126 -327 -108 -94 -64 71 -89 -82 -321 -51 -290 32 -254 7 -104 -106 -36 -55 71 -201 154 -184 72 -78 71 -64 -84 74 -36 150 -153 -88 -262 -18 -66 125 239 86 -38 -229 -3 -249 14 -157 3 -307 -305 -309 -458 -290 -351 -50 -420 -128 -278 183 69 276 375 110 343 52 277 11 364 175 628 780 725 351 17 201 69 546 411 390 -125 -141 -176 -310 -46 -90 123 226 410 -62 -186 -806 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