File name: Pandora21s1_Bremen_20221231_L2Fit_fwvt1c1d20201116p1-8.txt File generation date: 20240830T132135.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 21 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora21_OF_v4d20190904.txt Instrument calibration file used: Pandora21s1_CF_v1d20201116.txt Level 1 file used: Pandora21s1_Bremen_20221231_L1_smca1c1d20201116p1-8.txt Full location name: Bremen University Short location name: Bremen Country of location: Germany Location latitude [deg]: 53.0813 Location longitude [deg]: 8.8126 Location altitude [m]: 50 Local noon date: 20221231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1712 1862 Nominal wavelengths inside fitting window [nm]: 492.0351 492.1557 492.2762 492.3967 492.5172 492.6377 492.7581 492.8785 492.9990 493.1194 493.2397 493.3601 493.4805 493.6008 493.7211 493.8414 493.9617 494.0820 494.2022 494.3225 494.4427 494.5629 494.6830 494.8032 494.9234 495.0435 495.1636 495.2837 495.4038 495.5238 495.6439 495.7639 495.8839 496.0039 496.1239 496.2439 496.3638 496.4837 496.6036 496.7235 496.8434 496.9633 497.0831 497.2029 497.3227 497.4425 497.5623 497.6821 497.8018 497.9215 498.0412 498.1609 498.2806 498.4002 498.5199 498.6395 498.7591 498.8787 498.9983 499.1178 499.2373 499.3569 499.4764 499.5958 499.7153 499.8347 499.9542 500.0736 500.1930 500.3124 500.4317 500.5511 500.6704 500.7897 500.9090 501.0283 501.1475 501.2668 501.3860 501.5052 501.6244 501.7436 501.8627 501.9818 502.1010 502.2201 502.3391 502.4582 502.5773 502.6963 502.8153 502.9343 503.0533 503.1722 503.2912 503.4101 503.5290 503.6479 503.7668 503.8857 504.0045 504.1233 504.2421 504.3609 504.4797 504.5984 504.7172 504.8359 504.9546 505.0733 505.1919 505.3106 505.4292 505.5478 505.6664 505.7850 505.9035 506.0221 506.1406 506.2591 506.3776 506.4961 506.6145 506.7330 506.8514 506.9698 507.0882 507.2065 507.3249 507.4432 507.5615 507.6798 507.7981 507.9163 508.0346 508.1528 508.2710 508.3892 508.5074 508.6255 508.7437 508.8618 508.9799 509.0980 509.2160 509.3341 509.4521 509.5701 509.6881 509.8061 509.9240 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221231T112549.5Z 8400.476268 212 1 49.87 2 76.16 179.55 92.65 72.22 0.00 1 0.00 1 0 15 2.554e-03 2.516e-03 1.199e-03 1.194e-03 4.339434e+03 6.905084e+01 3.388595e+02 -6.000000e+00 1.274706e+02 266.61 -2.00 20.00 -2.00 505.26 0.00e+00 5.746541e-04 3.103406e-05 3.542358e-05 -6.000000e+00 6.775833e-05 266.61 -2.00 20.00 -2.00 500.28 0.00e+00 4.147041e-01 2.339905e-02 2.976667e-02 -6.000000e+00 4.973599e-02 220.69 -2.00 3.88 -2.00 501.90 0.00e+00 4.088 0.001 489.00 513.00 1 7.6553e+00 1.7795e-03 6.3916e-03 -6.0000e+00 3.7843e-03 1.6628e-02 4.6626e-04 8.3653e-04 -6.0000e+00 1.0006e-03 4.9858e-04 9.3767e-04 1.0074e-04 5.2695e-05 -6.0000e+00 2.2370e-04 -2.6881e-02 1.1814e-05 10 0 0 10 0 0 99.99 22.22 1.38 -0.02688 -0.02038 35 7 1 4 0 1424.557 25.28 20.00 22.22 18.81 30.9 1011.96 -641 -539 -388 -27 146 9 493 204 293 373 72 -21 -66 43 -106 -182 -76 3 -36 323 202 257 121 222 114 271 213 60 -54 -120 -212 -101 -177 -161 241 284 81 -71 -66 -241 -139 -180 -142 44 220 97 160 -84 -1 130 -269 -606 -468 -480 -649 -128 -126 167 273 319 456 261 167 379 240 219 216 129 -296 -268 -278 -424 -122 -57 -316 -16 -170 -259 -395 -345 -42 -238 -91 -71 -245 150 66 42 145 -47 -46 200 350 118 399 221 364 258 -210 -504 -419 -668 -308 -299 -93 27 1 -133 -192 -382 -278 -360 68 89 64 151 304 251 434 273 216 -44 98 144 338 267 64 327 83 130 94 111 -37 -252 -41 -27 52 -27 116 139 227 183 119 79 130 99 23 -337 -307 -412 -474 -617 -521 -383 -28 151 9 524 220 315 398 76 -22 -68 43 -107 -184 -78 3 -38 346 217 276 130 238 123 293 230 65 -58 -123 -213 -100 -179 -166 255 305 87 -75 -69 -251 -144 -187 -148 47 233 104 170 -89 -1 134 -271 -597 -452 -462 -634 -128 -129 173 283 329 469 269 173 392 248 224 218 128 -292 -262 -268 -408 -118 -56 -312 -16 -167 -250 -377 -327 -39 -226 -87 -68 -237 146 64 41 142 -46 -45 196 348 119 399 219 353 245 -196 -462 -379 -604 -282 -282 -90 27 1 -130 -185 -366 -267 -351 67 88 64 150 304 253 437 274 215 -43 95 138 327 259 62 317 81 126 91 106 -35 -235 -38 -25 48 -26 112 136 222 181 117 78 129 98 23 -330 -294 -388 -445 SQ 20221231T113159.0Z 8400.480544 217 1 1.56 2 76.17 181.01 91.77 73.41 0.00 1 0.00 1 0 15 2.774e-03 2.752e-03 3.187e-04 3.183e-04 5.025883e+03 1.831427e+01 3.868880e+02 -6.000000e+00 1.384748e+02 266.61 -2.00 20.00 -2.00 505.27 0.00e+00 6.459794e-04 8.276326e-06 4.317946e-05 -6.000000e+00 7.360161e-05 266.61 -2.00 20.00 -2.00 500.45 0.00e+00 3.343163e-01 6.180183e-03 3.573474e-02 -6.000000e+00 5.400733e-02 220.69 -2.00 3.88 -2.00 502.04 0.00e+00 4.089 0.001 489.00 513.00 1 1.9865e+00 4.6975e-04 6.6402e-03 -6.0000e+00 4.1096e-03 4.2353e-03 1.2299e-04 9.7015e-04 -6.0000e+00 1.0860e-03 1.4492e-01 7.1260e-05 2.6696e-05 6.3837e-05 -6.0000e+00 2.4303e-04 -3.2217e-02 8.2775e-05 12 1 1 12 1 1 88.48 22.22 1.34 -0.03222 -0.03172 74 102 1 4 0 17.005 25.28 20.00 22.22 18.93 31.1 1013.82 -543 -454 -303 -6 287 404 509 473 428 336 163 26 23 -213 -221 -258 -166 -14 134 284 279 298 252 206 284 326 402 233 40 -95 -409 -410 -248 -203 14 104 232 -12 -210 -211 -332 -222 -49 -4 115 188 164 102 56 -114 -331 -572 -651 -596 -426 -194 8 211 195 213 205 246 345 288 229 144 95 -65 -230 -226 -384 -386 -285 -182 -75 4 -76 -198 -303 -338 -279 -373 -263 -191 -178 -107 -111 -35 -35 -95 31 104 190 321 437 366 221 76 -175 -372 -615 -716 -442 -416 -156 -46 -60 -153 -237 -342 -224 -141 48 200 260 364 388 470 385 368 190 132 58 60 219 259 280 195 277 213 224 158 46 -32 -157 -103 -47 42 114 141 243 182 233 181 155 118 44 -218 -330 -504 -476 -521 -439 -295 -6 293 412 530 490 445 346 168 26 23 -215 -221 -258 -168 -14 137 296 292 311 264 216 299 344 423 245 41 -96 -412 -410 -246 -208 15 109 241 -12 -218 -216 -338 -227 -51 -4 119 196 170 105 58 -115 -333 -559 -636 -579 -421 -194 8 217 201 219 210 253 350 293 233 148 96 -64 -226 -223 -375 -375 -279 -181 -74 4 -75 -194 -292 -329 -271 -358 -255 -186 -176 -105 -110 -34 -35 -94 31 103 188 321 436 365 216 74 -166 -351 -571 -666 -419 -404 -155 -46 -60 -151 -235 -336 -218 -139 48 198 260 364 390 477 392 373 190 132 57 59 214 256 276 193 273 209 220 154 45 -31 -149 -99 -46 41 111 139 243 183 231 180 156 118 44 -217 -321 -490 -461 SQ 20221231T113554.6Z 8400.483271 220 1 1.17 2 76.18 181.94 91.21 74.16 0.00 1 0.00 1 0 15 2.810e-03 2.791e-03 3.122e-04 3.118e-04 4.989838e+03 1.787468e+01 3.831487e+02 -6.000000e+00 1.402527e+02 266.61 -2.00 20.00 -2.00 505.27 0.00e+00 6.454169e-04 8.114906e-06 4.308094e-05 -6.000000e+00 7.454665e-05 266.61 -2.00 20.00 -2.00 500.45 0.00e+00 3.392442e-01 6.052673e-03 3.582730e-02 -6.000000e+00 5.470095e-02 220.69 -2.00 3.88 -2.00 502.04 0.00e+00 4.093 0.001 489.00 513.00 1 1.6660e+00 4.6025e-04 6.6467e-03 -6.0000e+00 4.1624e-03 3.8079e-03 1.2045e-04 9.6849e-04 -6.0000e+00 1.0999e-03 1.9949e-01 8.9997e-05 2.6135e-05 6.2775e-05 -6.0000e+00 2.4615e-04 -3.2493e-02 8.4118e-05 12 1 1 12 1 1 94.60 22.22 1.35 -0.03249 -0.03187 77 102 1 4 0 12.392 25.28 20.00 22.22 19.09 31.2 1015.01 -601 -490 -329 15 280 395 523 511 385 380 123 -1 -102 -190 -276 -230 -129 -21 76 333 354 222 241 228 295 312 395 222 97 -17 -406 -391 -295 -189 41 169 162 9 -142 -246 -273 -207 -124 57 168 185 197 137 -31 -185 -351 -510 -605 -583 -441 -221 36 137 201 210 205 230 331 323 284 231 76 -8 -188 -288 -356 -444 -280 -204 -95 -76 -85 -141 -332 -304 -362 -341 -275 -216 -164 -69 -71 -48 -61 -105 -13 83 209 316 426 349 254 61 -191 -401 -592 -636 -500 -408 -143 -63 -1 -193 -224 -304 -259 -125 0 188 283 397 431 468 449 388 204 113 119 109 135 213 304 226 272 286 239 143 38 -96 -161 -110 8 17 150 300 181 159 207 123 90 110 -6 -210 -383 -493 -470 -575 -472 -326 15 285 401 542 538 399 397 127 -1 -105 -191 -275 -230 -130 -21 79 345 368 231 252 238 310 328 415 232 100 -18 -408 -390 -297 -193 42 176 168 9 -146 -251 -277 -211 -127 59 173 192 205 141 -32 -187 -353 -507 -589 -565 -434 -220 36 141 207 216 210 236 341 327 287 236 76 -8 -187 -284 -346 -430 -273 -202 -94 -75 -85 -138 -325 -296 -351 -333 -266 -211 -162 -69 -70 -47 -60 -103 -12 82 211 316 424 348 247 59 -184 -377 -558 -602 -473 -395 -142 -62 -1 -190 -221 -297 -256 -123 0 190 281 396 432 473 456 391 203 112 116 108 132 209 300 223 267 280 234 139 37 -92 -153 -104 8 17 149 296 180 160 208 123 91 111 -6 -209 -379 -478 -454 SQ 20221231T113950.6Z 8400.486003 223 1 27.49 2 76.21 182.87 90.64 74.91 0.00 1 0.00 1 0 15 2.523e-03 2.496e-03 1.427e-04 1.425e-04 4.985652e+03 8.227189e+00 3.829038e+02 -6.000000e+00 1.259313e+02 266.61 -2.00 20.00 -2.00 505.27 0.00e+00 6.063664e-04 3.709044e-06 4.126707e-05 -6.000000e+00 6.693859e-05 266.61 -2.00 20.00 -2.00 500.42 0.00e+00 3.579516e-01 2.770339e-03 3.548262e-02 -6.000000e+00 4.912963e-02 220.69 -2.00 3.88 -2.00 502.02 0.00e+00 4.100 0.001 489.00 513.00 1 3.2484e+00 2.1067e-04 6.6367e-03 -6.0000e+00 3.7382e-03 7.0721e-03 5.5097e-05 9.6256e-04 -6.0000e+00 9.8822e-04 4.0920e-02 5.6447e-04 1.1913e-05 6.1486e-05 -6.0000e+00 2.2100e-04 -2.7996e-02 3.0920e-05 10 0 0 10 0 0 99.99 22.22 1.30 -0.02800 -0.02408 637 125 1 4 0 41.197 25.28 20.00 22.22 19.33 31.3 1015.69 -527 -444 -295 -29 261 381 456 466 394 311 110 27 -48 -169 -171 -225 -70 3 112 286 287 238 191 214 220 289 318 202 54 -70 -342 -335 -250 -139 50 123 138 -59 -143 -236 -221 -212 -105 21 100 138 151 141 -27 -154 -272 -540 -531 -531 -394 -162 1 191 142 180 205 217 272 244 243 175 92 -65 -218 -273 -303 -362 -257 -163 -55 -50 -50 -172 -280 -287 -290 -341 -265 -198 -174 -84 -95 -3 -52 -68 -1 52 200 264 391 330 206 72 -212 -316 -572 -618 -484 -394 -146 -68 -37 -87 -241 -270 -211 -127 14 163 247 326 354 392 363 331 210 101 105 107 139 215 256 256 244 227 232 192 76 -34 -144 -100 -5 32 153 214 225 161 151 123 122 117 -29 -180 -342 -433 -476 -501 -425 -291 -29 264 392 479 497 422 330 115 28 -49 -170 -170 -224 -70 3 118 295 298 247 199 223 230 302 332 210 57 -72 -341 -332 -250 -143 51 130 145 -61 -147 -240 -232 -215 -108 22 104 145 159 146 -28 -155 -276 -532 -512 -510 -385 -163 1 194 146 183 207 221 278 251 249 178 92 -64 -220 -272 -298 -354 -253 -163 -54 -49 -50 -170 -272 -276 -278 -329 -258 -194 -173 -81 -93 -3 -51 -66 -1 51 200 267 393 326 199 70 -202 -293 -524 -566 -453 -384 -144 -68 -37 -86 -235 -261 -206 -126 14 166 243 322 351 393 365 330 215 101 103 104 137 213 254 254 242 225 229 188 73 -32 -136 -94 -5 32 153 208 222 160 150 124 123 118 -30 -177 -328 -422 -463 SQ 20221231T114006.4Z 8400.486185 223 2 2.53 2 76.21 182.93 90.61 74.96 0.00 1 0.00 1 0 15 2.598e-03 2.578e-03 4.084e-04 4.078e-04 4.990773e+03 2.339147e+01 3.835713e+02 -6.000000e+00 1.296768e+02 266.61 -2.00 20.00 -2.00 505.26 0.00e+00 6.245092e-04 1.061188e-05 4.221544e-05 -6.000000e+00 6.892690e-05 266.61 -2.00 20.00 -2.00 500.43 0.00e+00 3.550130e-01 7.926098e-03 3.551166e-02 -6.000000e+00 5.058235e-02 220.69 -2.00 3.88 -2.00 502.03 0.00e+00 4.100 0.001 489.00 513.00 1 3.0522e+00 6.0276e-04 6.6414e-03 -6.0000e+00 3.8489e-03 6.2066e-03 1.5778e-04 9.6302e-04 -6.0000e+00 1.0172e-03 4.9783e-02 2.1828e-04 3.4192e-05 6.2757e-05 -6.0000e+00 2.2757e-04 -2.9707e-02 5.6132e-05 12 1 1 12 1 1 99.44 22.22 1.30 -0.02971 -0.02819 54 125 1 4 0 41.197 25.28 20.00 22.22 19.33 31.3 1015.69 -518 -408 -264 -30 210 399 460 462 486 338 71 15 -83 -225 -150 -204 15 21 147 238 311 234 230 274 181 309 333 200 48 27 -391 -340 -202 -190 49 150 120 -18 -134 -205 -256 -270 -164 36 66 124 141 136 -25 -165 -308 -479 -678 -583 -355 -187 35 131 80 220 173 232 250 238 175 195 126 -47 -143 -306 -347 -404 -218 -156 -102 -8 -14 -108 -288 -278 -285 -307 -246 -87 -131 -96 -99 -49 -62 -109 23 85 175 269 343 270 237 76 -166 -330 -587 -618 -430 -383 -191 -86 -120 -112 -239 -323 -215 -213 22 115 277 352 379 467 418 363 286 41 204 42 140 233 267 270 210 263 229 216 54 -38 -196 -94 -92 35 191 228 224 186 152 138 201 120 -34 -209 -323 -479 -455 -497 -394 -262 -30 214 406 478 487 504 355 74 15 -85 -227 -150 -204 15 22 153 248 325 245 241 286 190 326 351 209 49 27 -393 -340 -204 -194 51 156 125 -19 -138 -209 -260 -275 -169 38 68 129 147 140 -26 -167 -310 -476 -660 -564 -350 -187 35 134 83 226 177 238 258 242 181 199 127 -46 -142 -301 -337 -391 -213 -154 -101 -8 -14 -105 -282 -270 -276 -300 -237 -85 -128 -95 -97 -48 -60 -106 22 84 176 268 341 269 235 74 -160 -309 -553 -583 -406 -370 -189 -86 -120 -110 -235 -316 -211 -210 22 116 274 350 379 471 424 365 288 41 202 42 137 229 262 265 205 257 225 210 52 -36 -186 -89 -89 34 189 224 222 186 153 139 201 120 -33 -208 -318 -462 -438 SQ 20221231T114402.6Z 8400.488919 226 1 0.54 2 76.24 183.86 90.04 75.72 0.00 1 0.00 1 0 22 3.097e-03 3.075e-03 1.315e-03 1.313e-03 4.855427e+03 7.523143e+01 3.774451e+02 -6.000000e+00 1.546082e+02 266.61 -2.00 20.00 -2.00 505.27 0.00e+00 6.750691e-04 3.416036e-05 4.318107e-05 -6.000000e+00 8.218275e-05 266.61 -2.00 20.00 -2.00 500.43 0.00e+00 3.675479e-01 2.550432e-02 3.374454e-02 -6.000000e+00 6.032093e-02 220.69 -2.00 3.88 -2.00 502.03 0.00e+00 4.110 0.001 489.00 513.00 1 3.3498e+00 1.9389e-03 6.5937e-03 -6.0000e+00 4.5897e-03 7.7320e-03 5.0769e-04 9.3071e-04 -6.0000e+00 1.2134e-03 3.6867e-02 8.1160e-04 1.1019e-04 6.1594e-05 -6.0000e+00 2.7131e-04 -3.5301e-02 6.7975e-05 12 1 1 12 1 1 43.08 22.23 1.30 -0.03530 -0.02967 4 134 1 4 0 71.643 25.28 20.00 22.23 19.57 31.1 1016.57 -800 -410 -221 -126 298 686 602 451 304 422 43 -109 -55 -370 -337 -388 -77 136 205 587 269 174 218 -66 110 606 252 190 65 31 -238 -587 -311 -269 122 202 217 -39 -335 -193 -99 -149 34 165 73 -61 115 166 -9 -6 -277 -573 -448 -684 -312 -135 7 191 171 216 81 240 192 94 623 199 227 -35 -207 -227 -335 -715 -189 -88 -75 47 -131 -268 -314 -271 -608 -333 -142 -66 -31 70 -29 -140 -92 -105 -208 91 148 276 120 615 293 254 -214 -273 -479 -803 -513 -667 -144 -35 151 -153 -351 -373 -105 -91 169 196 285 537 471 596 432 451 208 -108 77 88 124 256 166 336 279 41 75 -14 150 -140 -354 -275 -71 -44 -47 240 333 132 88 336 133 170 233 -249 -267 -534 -406 -774 -398 -217 -126 302 708 625 469 317 435 44 -111 -57 -373 -336 -387 -77 139 213 611 282 182 229 -69 115 630 262 199 68 32 -238 -585 -313 -274 127 212 226 -40 -348 -197 -100 -152 35 169 76 -64 120 172 -9 -6 -278 -567 -440 -671 -305 -135 7 196 174 222 84 246 195 96 632 203 228 -34 -206 -223 -326 -694 -184 -87 -74 46 -131 -261 -305 -261 -588 -323 -139 -64 -30 70 -28 -138 -90 -103 -205 90 149 277 121 610 289 244 -204 -258 -447 -752 -482 -644 -143 -35 150 -151 -346 -365 -101 -90 168 195 285 538 475 596 435 457 208 -108 75 86 121 253 164 331 274 40 74 -13 146 -134 -336 -261 -68 -43 -46 238 333 131 88 337 134 172 233 -246 -260 -518 -392