File name: Pandora134s1_BristolPA_20220724_L2Fit_fout2c2d20210612p1-8.txt File generation date: 20240224T122321.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20220724_L1_smca1c2d20210612p1-8.txt Full location name: Franklin D. Roosevelt Middle School; Bristol, Pennsylvania Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20220724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0874 305.2288 305.3702 305.5115 305.6529 305.7942 305.9356 306.0769 306.2182 306.3595 306.5008 306.6420 306.7833 306.9246 307.0658 307.2070 307.3482 307.4894 307.6306 307.7718 307.9130 308.0541 308.1953 308.3364 308.4775 308.6187 308.7598 308.9008 309.0419 309.1830 309.3240 309.4651 309.6061 309.7471 309.8881 310.0291 310.1701 310.3111 310.4521 310.5930 310.7340 310.8749 311.0158 311.1567 311.2976 311.4385 311.5793 311.7202 311.8610 312.0019 312.1427 312.2835 312.4243 312.5651 312.7059 312.8466 312.9874 313.1281 313.2689 313.4096 313.5503 313.6910 313.8317 313.9724 314.1130 314.2537 314.3943 314.5349 314.6755 314.8161 314.9567 315.0973 315.2379 315.3784 315.5190 315.6595 315.8000 315.9406 316.0811 316.2215 316.3620 316.5025 316.6429 316.7834 316.9238 317.0642 317.2046 317.3450 317.4854 317.6258 317.7661 317.9065 318.0468 318.1871 318.3275 318.4678 318.6081 318.7483 318.8886 319.0289 319.1691 319.3093 319.4495 319.5898 319.7300 319.8701 320.0103 320.1505 320.2906 320.4308 320.5709 320.7110 320.8511 320.9912 321.1313 321.2713 321.4114 321.5514 321.6915 321.8315 321.9715 322.1115 322.2515 322.3915 322.5314 322.6714 322.8113 322.9513 323.0912 323.2311 323.3710 323.5109 323.6507 323.7906 323.9304 324.0703 324.2101 324.3499 324.4897 324.6295 324.7693 324.9090 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220724T103118.3Z 8240.438406 224 1 50.94 2 83.71 69.33 43.33 96.24 0.00 1 0.00 1 0 33 6.914e-01 7.557e-02 5.785e-01 6.600e-02 9.074605e-01 4.078197e-02 1.351451e-02 -6.000000e+00 4.250256e-01 232.54 -2.00 3.49 -2.00 322.15 0.00e+00 -3.144149e-02 1.464220e-02 1.068641e-02 -6.000000e+00 2.113521e-02 290.27 -2.00 20.00 -2.00 321.54 0.00e+00 8.205 0.010 302.00 328.00 3 1.3133e+00 1.3781e-01 1.0055e-01 -6.0000e+00 1.0690e+00 1.4127e+00 1.6965e-01 5.8512e-02 -6.0000e+00 1.1658e+00 -2.0508e+00 1.0546e-01 4.6037e-02 -6.0000e+00 6.9192e-01 8.6685e-01 5.6172e-02 2.5277e-02 -6.0000e+00 2.9412e-01 1.6352e-05 -7.0977e-03 1.8616e-03 4.1826e-04 -6.0000e+00 1.9856e-02 8.6099e-03 -5.5595e-04 12 8 8 10 0 0 -104.05 21.41 1.16 0.00861 -0.04473 14 2 1 5 0 3635.005 26.94 20.00 21.41 30.33 21.3 1032.53 900000 72367 -26783 900000 108539 22860 900000 900000 6131 900000 -85506 121664 900000 900000 137319 67259 117779 900000 900000 900000 -52697 900000 67153 900000 92114 211273 900000 -25963 11744 3709 900000 57336 900000 40248 48721 -66114 -31748 92839 900000 239695 95598 105362 900000 145665 335507 900000 38800 -823 44055 -82164 900000 -11517 26095 235894 -28679 7084 65872 94150 13689 900000 75531 900000 80317 51603 9334 111459 26163 59098 38201 42623 34302 149674 15706 112692 54355 900000 -45760 -6519 -27679 29216 -32101 48454 -3254 16051 -20804 12362 28592 18933 16518 13761 -6158 8288 28914 -3505 -5467 6771 3626 -5795 24940 -7584 -12022 -18408 18061 -14065 2835 -3876 8860 -12393 -5310 -3269 7155 -432 1323 1096 -3051 -1003 -2022 -6435 2441 874 2775 2547 -4062 2423 12007 10073 -143 -174 -3602 6167 -3904 556 8296 -16 -4121 1838 3198 -91 -4149 1358 624 -3390 900000 4634 -3258 900000 6951 1464 900000 900000 505 900000 -17839 7792 900000 900000 8794 4307 7543 900000 900000 900000 -6591 900000 4301 900000 5899 13530 900000 -2602 752 238 900000 3672 900000 2578 3120 -7801 -2923 5946 900000 15350 6122 6748 900000 9329 21486 900000 2485 -73 2821 -17610 900000 -1528 2598 15107 -5669 1057 5751 6029 1721 900000 4837 900000 5364 5045 1400 7138 3253 5738 5205 6389 6029 9585 3242 8242 6205 900000 -11629 -1185 -7109 5158 -12041 9578 -1164 5068 -10060 4585 9421 6880 6017 4847 -2470 2786 8061 -1478 -2739 3539 2261 -4530 15434 -6324 -9650 -13945 9039 -10126 1882 -2878 6208 -11674 -5298 -3715 8288 -576 1761 1429 -4004 -1266 -2661 -9356 3432 1258 3777 3296 -5462 2992 13190 10868 -170 -233 -5871 10434 -8019 1171 17366 -40 -11301 4926 8540 -252 -11570 3342 1414 -7447 SS 20220724T103335.7Z 8240.439996 226 1 51.57 2 83.30 69.68 42.90 96.64 0.00 1 0.00 1 0 17 6.642e-01 5.189e-02 5.154e-01 4.547e-02 8.993892e-01 2.713916e-02 1.110401e-02 -6.000000e+00 3.899997e-01 232.54 -2.00 3.49 -2.00 322.19 0.00e+00 -1.883641e-02 1.332434e-02 8.341093e-03 -6.000000e+00 1.928505e-02 290.27 -2.00 20.00 -2.00 321.61 0.00e+00 7.794 0.008 302.00 328.00 3 1.2220e+00 1.0435e-01 9.9014e-02 -6.0000e+00 9.8191e-01 1.3310e+00 1.3103e-01 6.5678e-02 -6.0000e+00 1.0689e+00 -1.7001e+00 8.7866e-02 3.5703e-02 -6.0000e+00 6.3226e-01 6.5036e-01 4.3876e-02 1.1830e-02 -6.0000e+00 2.6723e-01 2.5322e-05 -4.9314e-03 1.2586e-03 2.4772e-04 -6.0000e+00 1.7678e-02 6.1363e-03 -2.0780e-04 12 8 8 10 0 0 26.67 21.41 0.75 0.00614 -0.03092 18 3 1 5 0 2864.444 26.94 20.00 21.41 30.58 21.4 1034.49 -5423 -32991 210881 900000 900000 5084 75446 -95203 -49076 173479 29225 900000 -7879 99358 900000 900000 900000 -17799 39302 84634 900000 900000 -18361 26344 173962 900000 15715 166007 -11592 -91810 -88852 900000 -26170 -10765 900000 -9303 -25745 -3034 -20153 144225 71637 -68019 -20770 166452 7315 28370 44416 -8864 329123 -11331 -10856 74751 9500 73055 260975 -5879 -1677 145434 95545 61012 19913 225613 26905 6878 12224 24805 -14670 24767 36611 46686 -18905 8300 59759 25096 5881 50886 -19614 60817 -3780 35776 13655 3008 -2430 8363 9070 13601 29651 9031 16598 -11617 -10539 -14826 15376 -7623 17533 4045 -12322 2315 -2782 108 -2328 -13025 3999 4594 6420 -12804 -7871 -2402 629 -3045 492 -101 1532 -493 -1809 -2347 -2931 -4201 4452 1964 2840 3116 715 8000 2265 -3688 696 3652 -531 -698 506 1357 -1706 -1843 -144 714 2781 191 2118 553 -3962 -2182 -240 -1722 9329 900000 900000 225 3337 -7062 -2600 7674 1293 900000 -349 4395 900000 900000 900000 -1118 1739 3744 900000 900000 -1044 1165 7695 900000 783 7344 -557 -9494 -10107 900000 -2024 -722 900000 -528 -1878 -212 -2064 6380 3890 -14470 -2719 7363 636 1926 2501 -844 14559 -1227 -1308 4362 1122 5052 11545 -981 -274 6433 5382 4415 2124 9980 3267 1121 1946 3385 -2959 3652 5502 7280 -5982 2046 8634 4623 1150 5718 -4177 6310 -849 6547 3611 1010 -939 3077 3535 5381 10372 3907 6483 -5617 -4725 -6652 5226 -3579 7518 2321 -9647 1797 -2427 90 -1810 -9921 2415 2901 4307 -10854 -6773 -2142 622 -3626 632 -139 2109 -674 -2405 -3086 -4011 -6166 6374 2899 3975 4125 950 9611 2805 -4670 853 4876 -873 -1307 1035 2952 -4083 -4789 -395 2008 7759 551 5851 1443 -9943 -5051 SS 20220724T103551.0Z 8240.441562 228 1 51.34 2 82.90 70.02 42.48 97.05 0.00 1 0.00 1 0 25 5.695e-01 3.656e-02 4.436e-01 3.014e-02 8.695795e-01 1.760768e-02 1.112260e-02 -6.000000e+00 3.308099e-01 232.54 -2.00 3.49 -2.00 322.19 0.00e+00 -1.674298e-02 8.831134e-03 1.117254e-02 -6.000000e+00 1.722829e-02 290.27 -2.00 20.00 -2.00 321.65 0.00e+00 7.423 0.007 302.00 328.00 3 1.2181e+00 6.7781e-02 1.0290e-01 -6.0000e+00 8.3111e-01 1.1541e+00 8.5843e-02 8.1959e-02 -6.0000e+00 9.0095e-01 -1.7410e+00 5.6125e-02 3.9487e-02 -6.0000e+00 5.3265e-01 7.3452e-01 2.7461e-02 9.8884e-03 -6.0000e+00 2.2861e-01 4.1112e-05 -2.8098e-03 8.2972e-04 2.5758e-04 -6.0000e+00 1.4994e-02 7.3966e-03 -2.5350e-04 12 8 8 10 0 0 54.71 21.41 0.55 0.00740 -0.01372 26 5 1 5 0 1974.159 26.94 20.00 21.41 30.78 21.3 1036.11 -21605 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