File name: Pandora134s1_BristolPA_20231109_L2Fit_fwvt1c2d20210612p1-8.txt File generation date: 20231110T051819.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20231109_L1_smca1c2d20210612p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20231109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1648 1797 Nominal wavelengths inside fitting window [nm]: 492.0184 492.1401 492.2618 492.3834 492.5051 492.6267 492.7484 492.8700 492.9916 493.1131 493.2347 493.3562 493.4778 493.5993 493.7208 493.8422 493.9637 494.0851 494.2066 494.3280 494.4494 494.5707 494.6921 494.8134 494.9347 495.0561 495.1773 495.2986 495.4199 495.5411 495.6623 495.7835 495.9047 496.0259 496.1471 496.2682 496.3893 496.5104 496.6315 496.7526 496.8737 496.9947 497.1157 497.2367 497.3577 497.4787 497.5996 497.7206 497.8415 497.9624 498.0833 498.2042 498.3250 498.4459 498.5667 498.6875 498.8083 498.9290 499.0498 499.1705 499.2913 499.4120 499.5326 499.6533 499.7740 499.8946 500.0152 500.1358 500.2564 500.3770 500.4975 500.6181 500.7386 500.8591 500.9796 501.1000 501.2205 501.3409 501.4613 501.5817 501.7021 501.8225 501.9428 502.0632 502.1835 502.3038 502.4241 502.5443 502.6646 502.7848 502.9050 503.0252 503.1454 503.2656 503.3857 503.5059 503.6260 503.7461 503.8662 503.9862 504.1063 504.2263 504.3463 504.4663 504.5863 504.7062 504.8262 504.9461 505.0660 505.1859 505.3058 505.4256 505.5455 505.6653 505.7851 505.9049 506.0247 506.1445 506.2642 506.3839 506.5036 506.6233 506.7430 506.8626 506.9823 507.1019 507.2215 507.3411 507.4607 507.5802 507.6998 507.8193 507.9388 508.0583 508.1777 508.2972 508.4166 508.5361 508.6555 508.7748 508.8942 509.0136 509.1329 509.2522 509.3715 509.4908 509.6101 509.7293 509.8485 509.9678 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231109T153500.2Z 8713.649308 307 1 4.58 2 59.19 160.89 45.75 213.77 0.00 1 0.00 1 0 15 2.938e-03 2.932e-03 1.143e-03 1.142e-03 2.769373e+03 6.945177e+01 2.060184e+02 -6.000000e+00 1.642569e+02 281.85 -2.00 20.00 -2.00 505.27 0.00e+00 1.277884e-03 3.143835e-05 6.868180e-05 -6.000000e+00 8.271715e-05 281.85 -2.00 20.00 -2.00 500.45 0.00e+00 9.972531e-02 2.251116e-02 2.076713e-02 -6.000000e+00 5.816798e-02 223.91 -2.00 3.49 -2.00 502.04 0.00e+00 1.945 0.000 489.00 513.00 1 5.2577e+00 1.7265e-03 3.6741e-03 -6.0000e+00 4.4656e-03 1.0362e-02 4.4184e-04 4.9418e-04 -6.0000e+00 1.1486e-03 7.5101e-03 8.6600e-04 1.1546e-04 3.5019e-05 -6.0000e+00 3.0540e-04 1.4066e-03 -7.4624e-05 12 1 1 12 1 1 97.63 21.32 0.32 0.00141 0.00741 6 14 1 4 0 652.979 26.83 20.00 21.32 22.62 29.8 1006.04 -609 -291 -167 -291 218 41 249 490 357 208 135 5 -56 -118 -446 -338 -212 -344 -191 -133 -267 -31 115 57 419 384 208 44 3 -5 48 133 -196 63 -92 -143 -137 142 213 -79 -128 52 290 221 356 588 295 191 163 400 -289 -135 -194 -333 -70 -152 -111 -206 73 395 393 346 221 40 137 158 -221 -243 -267 -431 -329 -366 -471 -286 -257 -394 -237 -299 -202 -220 -477 -133 -525 -140 241 51 291 263 344 511 692 560 656 441 178 -148 -154 -114 -268 -255 -336 -187 -512 -449 -514 -484 -167 -109 -56 -20 -272 211 244 374 515 519 583 213 -24 -224 114 28 144 61 153 -1 318 -93 -91 77 -33 -71 13 -141 -82 209 -19 -8 294 191 333 382 313 -105 47 -204 -467 -347 -354 -703 -593 -284 -167 -291 224 42 258 513 375 216 139 5 -57 -120 -451 -341 -217 -348 -197 -140 -282 -33 121 60 443 406 220 46 3 -5 48 133 -200 65 -96 -147 -141 148 219 -81 -130 54 300 231 364 602 301 199 166 399 -291 -132 -188 -325 -70 -151 -113 -212 75 405 404 357 222 40 141 160 -221 -240 -260 -429 -325 -362 -456 -280 -253 -386 -228 -293 -195 -212 -463 -129 -518 -135 233 49 284 257 336 500 682 560 663 447 179 -146 -149 -111 -255 -239 -315 -178 -491 -444 -518 -488 -166 -107 -55 -20 -272 206 242 373 517 523 589 216 -25 -222 111 27 142 60 152 -1 317 -90 -91 77 -32 -68 12 -133 -77 201 -19 -8 287 189 330 380 313 -105 47 -202 -453 -339 -341 -683 SQ 20231109T154313.5Z 8713.655018 313 1 5.89 2 58.71 163.12 46.66 216.27 0.00 1 0.00 1 0 15 2.727e-03 2.705e-03 1.250e-04 1.247e-04 2.747456e+03 7.579040e+00 2.037738e+02 -6.000000e+00 1.524328e+02 281.85 -2.00 20.00 -2.00 505.28 0.00e+00 1.203063e-03 3.436151e-06 6.502841e-05 -6.000000e+00 7.676044e-05 281.85 -2.00 20.00 -2.00 500.47 0.00e+00 7.814533e-02 2.454280e-03 2.080469e-02 -6.000000e+00 5.395523e-02 223.91 -2.00 3.49 -2.00 502.06 0.00e+00 1.918 0.000 489.00 513.00 1 1.0952e+00 1.8838e-04 3.6092e-03 -6.0000e+00 4.1425e-03 -2.5532e-03 4.8168e-05 4.9673e-04 -6.0000e+00 1.0649e-03 4.8562e-01 1.6671e-05 1.2616e-05 3.4141e-05 -6.0000e+00 2.8345e-04 2.8379e-03 -4.4021e-05 10 0 0 10 0 0 98.84 21.32 0.39 0.00284 0.00295 627 111 1 4 0 9.394 26.83 20.00 21.32 23.32 29.8 1010.25 -587 -460 -343 -152 -17 134 454 440 412 312 135 17 -61 -123 -241 -275 -262 -228 -172 -218 -260 15 129 94 258 253 125 4 125 -94 -110 28 -162 13 83 -100 -58 156 122 -36 16 87 215 260 327 364 378 266 173 164 -224 -271 -437 -375 -153 -158 -77 20 141 260 307 387 198 203 111 104 -86 -193 -217 -281 -314 -283 -244 -303 -288 -310 -306 -282 -272 -375 -419 -362 -379 -164 121 122 186 211 264 389 574 590 571 322 152 72 -27 -131 -90 -354 -368 -356 -445 -416 -489 -446 -196 -101 -9 60 -78 24 258 441 558 533 454 194 13 -55 73 58 97 138 -45 -25 124 18 -73 24 -76 -195 -158 -107 6 114 151 65 312 299 281 333 305 98 -72 -215 -364 -496 -509 -520 -564 -444 -340 -155 -17 137 470 461 432 325 139 17 -61 -121 -236 -270 -261 -231 -179 -230 -276 16 136 100 275 270 133 4 129 -94 -108 28 -161 14 87 -102 -62 164 126 -37 16 91 225 275 332 371 383 279 179 165 -221 -261 -416 -360 -150 -160 -79 20 147 270 320 385 198 203 116 107 -87 -194 -214 -275 -305 -275 -240 -302 -288 -309 -300 -272 -260 -358 -401 -350 -368 -161 119 121 186 211 264 389 578 574 561 318 148 73 -26 -126 -84 -329 -342 -337 -436 -401 -481 -438 -190 -102 -9 57 -76 24 258 444 564 542 463 198 13 -55 72 57 94 134 -44 -25 121 17 -71 23 -73 -184 -155 -104 5 107 145 64 309 298 282 336 309 100 -73 -216 -358 -478 -485 -497 SQ 20231109T154319.4Z 8713.655086 313 2 5.90 2 58.70 163.14 46.68 216.29 0.00 1 0.00 1 0 15 2.689e-03 2.686e-03 1.432e-04 1.430e-04 2.755801e+03 8.661491e+00 2.050313e+02 -6.000000e+00 1.503413e+02 281.85 -2.00 20.00 -2.00 505.29 0.00e+00 1.173350e-03 3.957199e-06 6.359103e-05 -6.000000e+00 7.570798e-05 281.85 -2.00 20.00 -2.00 500.52 0.00e+00 8.103792e-02 2.816514e-03 2.095200e-02 -6.000000e+00 5.321678e-02 223.91 -2.00 3.49 -2.00 502.11 0.00e+00 1.918 0.000 489.00 513.00 1 1.3251e+00 2.1625e-04 3.5992e-03 -6.0000e+00 4.0858e-03 -1.6849e-03 5.5168e-05 5.0244e-04 -6.0000e+00 1.0504e-03 3.8593e-01 5.7500e-05 1.4462e-05 3.3601e-05 -6.0000e+00 2.7956e-04 2.9762e-03 -4.7358e-05 10 0 0 10 0 0 99.09 21.32 0.38 0.00298 0.00338 627 111 1 4 0 9.394 26.83 20.00 21.32 23.32 29.9 1010.25 -575 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