File name: Pandora134s1_BristolPA_20231115_L2Fit_fout2c2d20210612p1-8.txt File generation date: 20231116T060725.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 134 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora134_OF_v6d20200325.txt Instrument calibration file used: Pandora134s1_CF_v2d20210612.txt Level 1 file used: Pandora134s1_BristolPA_20231115_L1_smca1c2d20210612p1-8.txt Full location name: Bristol, Pennsylvania; Philadelphia-Camden-Wilmington, PA-NJ-DE-MD; A420170012 Short location name: BristolPA Country of location: United States Location latitude [deg]: 40.1074 Location longitude [deg]: -74.8824 Location altitude [m]: 10 Local noon date: 20231115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0874 305.2288 305.3702 305.5115 305.6529 305.7942 305.9356 306.0769 306.2182 306.3595 306.5008 306.6420 306.7833 306.9246 307.0658 307.2070 307.3482 307.4894 307.6306 307.7718 307.9130 308.0541 308.1953 308.3364 308.4775 308.6187 308.7598 308.9008 309.0419 309.1830 309.3240 309.4651 309.6061 309.7471 309.8881 310.0291 310.1701 310.3111 310.4521 310.5930 310.7340 310.8749 311.0158 311.1567 311.2976 311.4385 311.5793 311.7202 311.8610 312.0019 312.1427 312.2835 312.4243 312.5651 312.7059 312.8466 312.9874 313.1281 313.2689 313.4096 313.5503 313.6910 313.8317 313.9724 314.1130 314.2537 314.3943 314.5349 314.6755 314.8161 314.9567 315.0973 315.2379 315.3784 315.5190 315.6595 315.8000 315.9406 316.0811 316.2215 316.3620 316.5025 316.6429 316.7834 316.9238 317.0642 317.2046 317.3450 317.4854 317.6258 317.7661 317.9065 318.0468 318.1871 318.3275 318.4678 318.6081 318.7483 318.8886 319.0289 319.1691 319.3093 319.4495 319.5898 319.7300 319.8701 320.0103 320.1505 320.2906 320.4308 320.5709 320.7110 320.8511 320.9912 321.1313 321.2713 321.4114 321.5514 321.6915 321.8315 321.9715 322.1115 322.2515 322.3915 322.5314 322.6714 322.8113 322.9513 323.0912 323.2311 323.3710 323.5109 323.6507 323.7906 323.9304 324.0703 324.2101 324.3499 324.4897 324.6295 324.7693 324.9090 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231115T122940.5Z 8719.520607 60 1 48.72 2 83.22 121.18 108.69 110.98 0.00 1 0.00 1 0 17 4.742e-01 2.340e-02 4.633e-01 2.027e-02 8.530057e-01 1.151150e-02 1.015117e-02 -6.000000e+00 2.626330e-01 223.41 -2.00 3.49 -2.00 322.25 0.00e+00 -6.841143e-03 6.759153e-03 9.341506e-03 -6.000000e+00 1.293784e-02 281.14 -2.00 20.00 -2.00 321.80 0.00e+00 7.731 0.008 302.00 328.00 3 5.1273e-01 4.6181e-02 1.0162e-01 -6.0000e+00 6.4663e-01 7.8262e-01 6.2035e-02 7.4908e-02 -6.0000e+00 7.0463e-01 -1.1173e+00 5.6108e-02 3.3868e-02 -6.0000e+00 4.2095e-01 4.5523e-01 2.6239e-02 8.3521e-03 -6.0000e+00 1.8415e-01 6.7369e-05 -2.3910e-03 5.6140e-04 2.1694e-04 -6.0000e+00 1.2396e-02 6.7237e-03 -2.0204e-04 12 9 9 12 1 1 38.03 21.25 0.47 0.00672 -0.01124 36 7 1 5 0 1316.553 26.83 20.00 21.25 6.06 28.6 902.70 -138427 -175128 -171778 900000 -163563 89488 -149786 -82783 -57170 -52576 900000 900000 -20234 -16225 900000 69984 -14913 151496 -54482 -17420 57380 900000 110976 -61706 130875 -70438 -25829 -81594 1796 -53614 -75 16288 -11788 6935 -2419 27295 -62121 8287 98884 -31359 49573 14591 8052 55923 20235 52267 78033 16181 25557 71293 14501 7711 -11478 18241 30599 74681 46537 56227 28015 28144 19407 47793 18183 31641 21132 18807 22660 22787 14506 22491 11661 -3036 10352 -3673 -1017 15171 -8461 -15113 -14421 -10704 5648 204 2747 2009 2354 1448 8874 894 456 -3916 3200 -3487 -4195 -3436 441 -890 -683 3994 843 121 -3435 -1048 -5424 -652 -5097 -1758 -926 -1865 -2278 -2380 -1863 -760 -976 1829 -2502 -1874 -2349 168 328 1023 825 3051 3433 2709 2380 2689 -1325 1768 691 2021 -165 191 -610 -398 328 655 510 805 -104 -1046 -898 -1946 -2960 -5762 -5369 900000 -3816 1767 -3226 -1634 -1129 -1038 900000 900000 -399 -320 900000 1382 -294 2991 -1564 -344 1133 900000 2191 -2104 2584 -2907 -649 -3221 35 -1636 -2 386 -419 205 -72 593 -3345 294 1952 -2195 1859 807 477 1987 999 1857 2157 862 1312 2533 1031 655 -1292 1656 2597 4275 3583 3774 2323 2222 1724 3585 2118 3623 2753 2450 2908 3149 2520 4129 2555 -779 2207 -819 -195 2216 -1537 -3192 -3616 -3127 1650 72 1025 801 999 654 3872 425 213 -1793 1276 -1432 -1772 -1614 236 -571 -512 3272 752 105 -2787 -731 -3737 -455 -4015 -1409 -789 -1771 -2500 -3026 -2629 -1113 -1433 2523 -3453 -2545 -3339 247 506 1563 1204 4138 4521 3492 2993 3244 -1692 2509 1168 3831 -350 431 -1489 -1045 914 1866 1472 2327 -292 -2760 -2179 -4482 SS 20231115T124012.3Z 8719.527920 63 1 51.02 2 81.51 123.02 106.91 112.41 0.00 1 0.00 1 0 17 5.735e-01 1.343e-02 3.186e-01 7.625e-03 7.267229e-01 4.226349e-03 8.289991e-03 -6.000000e+00 3.204022e-01 223.41 -2.00 3.49 -2.00 321.89 0.00e+00 -6.015345e-05 2.385483e-03 4.760467e-03 -6.000000e+00 1.545454e-02 281.14 -2.00 20.00 -2.00 321.41 0.00e+00 6.381 0.005 302.00 328.00 3 5.5318e-01 1.6104e-02 7.8980e-02 -6.0000e+00 7.8802e-01 1.9337e-01 2.3865e-02 5.3758e-02 -6.0000e+00 8.5876e-01 -3.5247e-01 2.5218e-02 2.5063e-02 -6.0000e+00 5.1045e-01 1.5156e-01 1.1569e-02 7.0668e-03 -6.0000e+00 2.2142e-01 2.8019e-04 -1.7379e-03 2.1784e-04 1.0285e-04 -6.0000e+00 1.4675e-02 5.9117e-03 -2.8820e-06 12 8 8 10 0 0 97.40 21.25 0.33 0.00591 -0.00715 96 17 1 5 0 531.434 26.83 20.00 21.25 7.27 28.5 909.94 2707 -122250 -128645 -244810 -203451 900000 -210393 -140634 -158847 900000 -250008 -91311 -153424 -93462 -91529 -9617 -102089 -26031 -78726 -26622 -80380 900000 -97113 211399 -39975 900000 -146 -5162 -67432 -5379 -46464 -25136 20491 -9094 46127 -6821 11559 -10623 19487 -4936 25362 -679 30870 -4049 30868 1234 37234 2019 10165 5124 19019 5627 8118 6359 21855 7448 12132 12928 3474 5293 12980 4477 4654 10384 4948 11275 402 5207 4234 7411 3433 6685 4087 -314 -520 2274 -5762 142 -2981 558 -2699 -1459 -2882 44 -1332 3160 500 681 782 1127 -971 570 -1734 -2679 -980 -1053 969 -101 141 -1519 725 -1694 -320 -2668 -1074 -1915 -562 -1718 163 -309 57 225 815 -905 -383 -1097 -410 -929 -488 -165 168 1663 1140 2046 977 583 354 1103 534 292 -127 619 -482 136 -16 198 430 299 164 -234 -799 -1281 20 -908 -956 -4092 -2199 900000 -2700 -1045 -1609 900000 -6501 -678 -2487 -1073 -1298 -71 -2138 -281 -1542 -324 -1683 900000 -2558 1571 -729 900000 -2 -66 -1594 -76 -1224 -645 388 -240 720 -166 265 -373 632 -243 1028 -38 1314 -246 1334 73 1584 128 632 367 1349 513 795 691 2155 890 1418 1467 415 611 1464 623 748 1774 916 1904 77 1009 958 1872 974 1874 1132 -84 -125 478 -1276 32 -817 178 -1041 -633 -1368 22 -710 1710 291 400 451 611 -501 275 -857 -1469 -618 -779 818 -98 144 -1516 642 -1360 -242 -2197 -939 -1774 -548 -1849 195 -422 85 348 1237 -1334 -534 -1517 -585 -1415 -782 -265 258 2411 1616 2779 1298 745 456 1590 896 552 -261 1334 -1116 338 -41 538 1182 828 442 -593 -1899 -2894 SS 20231115T125545.2Z 8719.538718 68 1 50.99 2 79.06 125.82 104.32 114.53 0.00 1 0.00 1 0 25 3.878e-01 7.732e-03 1.917e-01 3.555e-03 6.032683e-01 1.869852e-03 6.947444e-03 -6.000000e+00 2.144954e-01 223.41 -2.00 3.49 -2.00 321.25 0.00e+00 -3.084758e-04 8.987025e-04 2.552974e-03 -6.000000e+00 9.532096e-03 281.14 -2.00 20.00 -2.00 320.72 0.00e+00 5.080 0.002 302.00 328.00 3 8.1343e-01 6.3735e-03 6.0962e-02 -6.0000e+00 5.2843e-01 5.2902e-03 8.8817e-03 3.7011e-02 -6.0000e+00 5.7541e-01 -5.7470e-02 9.2766e-03 1.7959e-02 -6.0000e+00 3.4337e-01 2.6853e-02 4.4410e-03 5.3987e-03 -6.0000e+00 1.4912e-01 8.3336e-04 -8.0439e-04 1.0084e-04 6.6397e-05 -6.0000e+00 9.8495e-03 5.2815e-03 7.4699e-05 11 8 0 10 0 0 99.60 21.25 0.20 0.00528 -0.00076 155 27 1 5 0 328.913 26.83 19.99 21.25 9.35 28.8 924.51 -92564 -151106 162365 -162846 164398 -78444 -115937 -113211 -52260 -114611 -103147 -95387 -51654 -46973 -50805 -35282 -18894 37713 -49469 29124 -27141 55305 -34691 22328 -32114 17711 -20275 9703 -35141 -411 -14342 4287 -6650 2462 -18906 -11672 1692 2372 429 2670 2032 4532 6903 -1933 6867 -3883 5250 -4681 6135 -2795 9809 -816 8701 1824 6605 1046 2814 -1759 5636 -1997 2275 622 2897 2603 1572 -1525 -524 -1362 -514 1128 496 978 130 2163 -1028 744 -4385 -714 -2985 -101 -2568 -354 -3003 -427 -1064 931 228 1295 482 1440 810 147 -402 -83 -549 -35 816 733 778 62 -97 -1113 195 -1146 -531 -1433 -74 -918 512 -134 894 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