File name: Pandora180s1_BronxNY_20211224_L2Fit_fout2c2d20210302p1-8.txt File generation date: 20260323T073928.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20211224_L1_smca1c2d20210302p1-8.txt Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20211224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0771 305.2181 305.3590 305.5000 305.6409 305.7819 305.9228 306.0637 306.2046 306.3455 306.4864 306.6273 306.7681 306.9090 307.0498 307.1906 307.3315 307.4723 307.6131 307.7539 307.8946 308.0354 308.1762 308.3169 308.4577 308.5984 308.7391 308.8798 309.0205 309.1612 309.3019 309.4425 309.5832 309.7238 309.8644 310.0051 310.1457 310.2863 310.4269 310.5674 310.7080 310.8486 310.9891 311.1297 311.2702 311.4107 311.5512 311.6917 311.8322 311.9726 312.1131 312.2536 312.3940 312.5344 312.6749 312.8153 312.9557 313.0961 313.2364 313.3768 313.5172 313.6575 313.7978 313.9382 314.0785 314.2188 314.3591 314.4994 314.6396 314.7799 314.9201 315.0604 315.2006 315.3408 315.4810 315.6212 315.7614 315.9016 316.0418 316.1819 316.3221 316.4622 316.6023 316.7424 316.8825 317.0226 317.1627 317.3028 317.4428 317.5829 317.7229 317.8629 318.0029 318.1430 318.2829 318.4229 318.5629 318.7029 318.8428 318.9828 319.1227 319.2626 319.4025 319.5424 319.6823 319.8222 319.9620 320.1019 320.2417 320.3816 320.5214 320.6612 320.8010 320.9408 321.0806 321.2203 321.3601 321.4998 321.6396 321.7793 321.9190 322.0587 322.1984 322.3381 322.4778 322.6174 322.7571 322.8967 323.0363 323.1760 323.3156 323.4552 323.5947 323.7343 323.8739 324.0134 324.1530 324.2925 324.4320 324.5715 324.7110 324.8505 324.9900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211224T170357.5Z 8028.711082 432 1 5.76 2 64.30 182.20 100.60 299.20 0.00 1 0.00 1 0 17 3.731e-02 8.410e-03 2.398e-02 4.687e-03 3.367158e-01 2.376882e-03 4.070709e-03 -6.000000e+00 2.140326e-02 223.06 -2.00 3.51 -2.00 318.04 0.00e+00 1.331782e-03 4.170072e-04 3.707911e-04 -6.000000e+00 9.321961e-04 276.53 -2.00 20.00 -2.00 317.45 0.00e+00 2.292 0.000 302.00 328.00 3 4.2130e+00 6.3036e-03 2.8421e-02 -6.0000e+00 5.2721e-02 4.1483e-02 7.1194e-03 1.6990e-02 -6.0000e+00 5.7298e-02 -2.7099e-03 4.6663e-03 8.6143e-03 -6.0000e+00 3.4117e-02 -6.5592e-03 2.4451e-03 2.7117e-03 -6.0000e+00 1.4724e-02 5.1495e-04 -4.4223e-05 1.3869e-04 3.0203e-05 -6.0000e+00 1.0484e-03 2.6561e-02 -6.2208e-06 12 9 1 12 1 1 99.11 24.13 0.38 0.02656 0.02623 4 11 1 5 0 1116.990 28.10 20.01 24.13 9.24 22.7 943.95 -1375 -3692 7975 -12765 13136 -23556 12568 -9842 -4011 -7822 -6420 -348 -4049 4248 -2319 10197 -7107 4463 -1554 -5102 3826 -560 3446 -1239 5557 -1719 -43 -2965 -1642 2677 -528 2529 -1171 2379 -6929 -3483 -6368 -609 87 -1012 1394 -584 -450 -913 1325 420 793 817 -1643 265 -1674 2632 -173 1584 675 2295 -524 111 2101 -1138 303 1974 3231 1580 770 384 -656 293 1129 901 376 851 -385 92 82 -2569 -804 -1661 -913 -2475 -35 -1308 -840 -1889 -961 56 6 1154 91 611 369 -1318 -1305 -194 626 -518 649 157 887 -601 -558 -1152 -427 -764 216 -711 -991 -171 146 564 776 797 423 38 35 -25 384 -453 545 -61 555 723 -41 1139 -531 -67 -131 709 495 -80 -445 -497 -179 -289 131 -48 18 -135 212 238 -688 -89 900000 -84 -250 485 -881 636 -1636 661 -729 -308 -647 -528 -29 -413 470 -317 1356 -1189 702 -271 -956 661 -101 622 -249 1100 -377 -9 -610 -320 518 -116 594 -310 608 -1837 -909 -1918 -187 32 -428 622 -278 -220 -451 643 206 382 389 -803 131 -911 1476 -97 921 408 1397 -331 69 1253 -705 194 1356 2393 1254 602 281 -462 208 874 725 326 754 -338 76 67 -1942 -554 -1151 -689 -2159 -31 -1284 -870 -2090 -1048 64 7 1393 110 691 415 -1382 -1290 -193 673 -585 811 202 1167 -772 -712 -1359 -487 -921 277 -965 -1324 -238 216 895 1205 1234 670 56 48 -35 553 -647 824 -97 872 1107 -61 1601 -775 -93 -177 993 702 -123 -716 -822 -285 -486 233 -89 32 -242 376 432 -1207 -149 900000 SS 20211224T170827.8Z 8028.714210 435 1 48.31 2 64.34 183.35 101.33 299.97 0.00 1 0.00 1 0 17 3.198e-02 6.928e-03 2.509e-02 3.199e-03 3.399032e-01 1.612499e-03 4.112935e-03 -6.000000e+00 1.835275e-02 223.06 -2.00 3.51 -2.00 318.88 0.00e+00 1.018660e-03 3.611075e-04 6.138684e-04 -6.000000e+00 7.990031e-04 276.53 -2.00 20.00 -2.00 318.28 0.00e+00 2.295 0.000 302.00 328.00 3 4.7820e+00 4.3744e-03 2.8649e-02 -6.0000e+00 4.5207e-02 4.9387e-02 5.0357e-03 1.7411e-02 -6.0000e+00 4.9128e-02 4.7236e-03 3.6639e-03 8.9325e-03 -6.0000e+00 2.9252e-02 -1.3057e-02 1.9484e-03 2.7519e-03 -6.0000e+00 1.2628e-02 2.8781e-04 6.5200e-05 9.6850e-05 3.1588e-05 -6.0000e+00 8.9855e-04 2.6003e-02 4.6402e-05 11 8 0 10 0 0 99.92 24.15 0.35 0.02600 0.02649 46 11 1 5 0 1050.090 28.10 20.00 24.15 9.58 22.7 946.18 -2736 9636 -8318 -5265 -17523 -9336 -13137 -4995 4776 -12305 -8686 -5251 -3274 -4506 792 1855 5 2554 1584 7083 -5517 1497 -4324 -1180 -1657 4963 -3214 -2217 -2211 -2113 660 -1847 -768 -379 -1423 -4504 -2797 795 920 -1381 -1583 -1266 -887 -1016 212 315 229 -1106 -794 -95 487 241 1657 1453 302 977 1129 -221 846 215 663 2433 3053 2415 358 0 -588 -924 659 723 651 1372 1044 566 -109 -704 -1626 -1326 -1411 -245 -992 -1317 -1995 -1535 -677 -280 450 581 1423 74 -208 380 -705 111 -597 -268 211 474 -351 -277 -843 -584 -803 -1287 -938 -1285 -548 -276 663 841 795 621 147 -46 -194 -211 -223 406 799 -82 343 315 459 376 89 -275 106 686 396 127 -464 -405 -352 -88 -69 91 489 401 438 -112 -460 -862 900000 -103 350 -366 -208 -711 -347 -551 -218 209 -663 -456 -289 -206 -339 65 167 1 256 168 735 -655 166 -530 -149 -244 707 -489 -315 -301 -297 99 -314 -141 -69 -249 -826 -565 184 255 -450 -559 -466 -335 -387 80 118 85 -413 -296 -36 200 106 768 711 154 507 591 -116 430 110 356 1397 1903 1598 236 0 -349 -557 431 531 514 1102 825 426 -75 -440 -950 -770 -898 -176 -806 -1177 -1905 -1541 -722 -317 527 692 1656 83 -214 357 -630 100 -591 -295 260 638 -490 -373 -1057 -671 -899 -1526 -1190 -1715 -763 -403 1026 1268 1255 980 245 -71 -279 -293 -315 602 1261 -136 565 507 713 558 126 -372 139 938 588 202 -783 -702 -630 -164 -124 171 932 775 836 -207 -901 -1634 900000 SS 20211224T171719.1Z 8028.720360 441 1 3.03 2 64.47 185.59 102.74 301.52 0.00 1 0.00 1 0 17 3.843e-02 1.141e-02 3.725e-02 8.013e-03 3.465951e-01 4.068301e-03 4.217171e-03 -6.000000e+00 2.203496e-02 223.06 -2.00 3.51 -2.00 317.90 0.00e+00 1.091107e-03 6.906020e-04 3.319942e-04 -6.000000e+00 9.601146e-04 276.53 -2.00 20.00 -2.00 317.31 0.00e+00 2.306 0.000 302.00 328.00 3 4.2061e+00 1.0743e-02 2.8867e-02 -6.0000e+00 5.4276e-02 6.6011e-02 1.2136e-02 1.7533e-02 -6.0000e+00 5.8997e-02 -1.2329e-02 7.8232e-03 8.8237e-03 -6.0000e+00 3.5128e-02 -8.5177e-03 4.0678e-03 2.6318e-03 -6.0000e+00 1.5156e-02 5.0012e-04 -8.5462e-04 2.3444e-04 3.0372e-05 -6.0000e+00 1.0799e-03 2.6591e-02 -1.1354e-04 12 9 9 12 1 1 999.00 24.15 0.09 0.02659 0.02017 1 8 1 5 0 1430.560 28.10 20.00 24.15 10.34 22.6 951.36 557 -11806 -14604 -8252 -13234 -13856 -7809 17375 -10935 -771 -5261 7574 -3509 6197 10829 4263 3135 2576 -668 -1199 -6165 -363 -920 184 2323 996 3402 1635 -4499 3588 -6699 2728 -2250 1177 -2233 -3796 -5377 -5725 3263 1735 1194 -1445 -2226 923 -315 2078 -745 568 -2371 -767 198 2886 3153 1182 446 -2312 -35 -722 149 391 -39 1027 5877 1113 1542 42 -431 1585 52 372 739 2949 774 -935 -908 -1932 -2691 -2492 -4049 -554 -210 -330 -3913 -1474 -2580 -47 943 927 1257 174 98 251 396 151 124 -247 1959 398 58 -501 -400 -1596 -5 110 -707 -1755 -874 167 109 997 1229 144 528 -203 -233 628 509 1055 -1019 362 -397 653 326 -3 72 752 709 689 -648 -525 293 -1132 -500 -988 592 236 491 590 -90 -32 -368 -471 900000 36 -932 -1198 -587 -900 -942 -543 1059 -974 -64 -465 639 -387 731 1413 656 517 451 -126 -236 -1169 -71 -190 40 474 212 766 353 -991 754 -1561 639 -602 305 -566 -995 -1604 -2033 1270 722 540 -702 -1120 453 -157 1011 -368 274 -1181 -389 107 1637 1897 764 277 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