File name: Pandora180s1_BronxNY_20211231_L2Fit_fout2c2d20210302p1-8.txt File generation date: 20260323T074019.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20211231_L1_smca1c2d20210302p1-8.txt Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20211231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0771 305.2181 305.3590 305.5000 305.6409 305.7819 305.9228 306.0637 306.2046 306.3455 306.4864 306.6273 306.7681 306.9090 307.0498 307.1906 307.3315 307.4723 307.6131 307.7539 307.8946 308.0354 308.1762 308.3169 308.4577 308.5984 308.7391 308.8798 309.0205 309.1612 309.3019 309.4425 309.5832 309.7238 309.8644 310.0051 310.1457 310.2863 310.4269 310.5674 310.7080 310.8486 310.9891 311.1297 311.2702 311.4107 311.5512 311.6917 311.8322 311.9726 312.1131 312.2536 312.3940 312.5344 312.6749 312.8153 312.9557 313.0961 313.2364 313.3768 313.5172 313.6575 313.7978 313.9382 314.0785 314.2188 314.3591 314.4994 314.6396 314.7799 314.9201 315.0604 315.2006 315.3408 315.4810 315.6212 315.7614 315.9016 316.0418 316.1819 316.3221 316.4622 316.6023 316.7424 316.8825 317.0226 317.1627 317.3028 317.4428 317.5829 317.7229 317.8629 318.0029 318.1430 318.2829 318.4229 318.5629 318.7029 318.8428 318.9828 319.1227 319.2626 319.4025 319.5424 319.6823 319.8222 319.9620 320.1019 320.2417 320.3816 320.5214 320.6612 320.8010 320.9408 321.0806 321.2203 321.3601 321.4998 321.6396 321.7793 321.9190 322.0587 322.1984 322.3381 322.4778 322.6174 322.7571 322.8967 323.0363 323.1760 323.3156 323.4552 323.5947 323.7343 323.8739 324.0134 324.1530 324.2925 324.4320 324.5715 324.7110 324.8505 324.9900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211231T135836.8Z 8035.582370 156 1 47.94 2 76.37 137.96 65.27 168.26 0.00 1 0.00 1 0 17 1.722e-01 6.465e-03 1.023e-01 3.371e-03 5.087248e-01 1.779849e-03 6.005784e-03 -6.000000e+00 9.887156e-02 223.28 -2.00 3.51 -2.00 320.66 0.00e+00 3.299405e-03 6.911024e-04 1.363292e-03 -6.000000e+00 4.296248e-03 276.11 -2.00 20.00 -2.00 320.15 0.00e+00 4.144 0.001 302.00 328.00 3 2.6257e+00 5.4451e-03 4.8923e-02 -6.0000e+00 2.4369e-01 3.4004e-02 6.9373e-03 2.7196e-02 -6.0000e+00 2.6484e-01 -3.2616e-02 6.8160e-03 1.5437e-02 -6.0000e+00 1.5763e-01 4.0044e-03 3.4321e-03 5.9206e-03 -6.0000e+00 6.7965e-02 3.5620e-04 -5.5221e-04 1.0318e-04 7.5677e-05 -6.0000e+00 4.8402e-03 2.7083e-02 -2.7031e-05 11 8 0 10 0 0 99.93 24.13 0.35 0.02708 0.02293 152 37 1 5 0 315.390 28.10 20.00 24.13 19.00 23.6 1016.83 -80117 -45764 -71414 -47656 -67185 -77053 -39263 -16303 -56912 -36941 -32377 -25806 -15132 -26734 -33538 -33260 -16258 5005 -6546 -14499 -14827 -5608 -7750 -3850 -12861 -4863 -13160 -18856 -10212 -12970 -5006 -8980 -2746 -6889 -3409 -11838 -7890 -1603 -1834 1304 -788 2102 -2657 1023 -2466 2758 1349 -1177 180 -652 2447 1395 4259 2407 1982 971 -950 574 -1769 2352 367 3676 3260 4025 1588 1108 259 745 1769 1584 956 192 1452 -51 -1010 201 -2306 -1218 -2217 -959 -663 -1138 -1876 -1158 -1035 -527 1022 300 1452 -61 743 146 -584 -412 -694 262 419 744 195 -589 -1005 -1184 -893 -1620 -1044 -1328 -265 -279 172 696 693 766 222 48 -520 -180 -64 88 -22 -190 516 243 660 524 116 -342 309 521 42 -154 -164 -235 -282 -13 -88 -11 401 284 89 108 -245 -570 900000 -957 -438 -917 -456 -723 -921 -352 -132 -765 -430 -377 -324 -212 -527 -862 -984 -447 121 -190 -476 -496 -173 -257 -132 -515 -187 -550 -806 -400 -570 -236 -510 -164 -438 -201 -778 -563 -129 -179 144 -97 295 -408 154 -391 423 213 -195 30 -118 474 300 964 594 513 262 -265 156 -482 618 104 1121 1119 1486 603 405 94 279 734 746 488 101 738 -25 -450 80 -893 -481 -999 -497 -393 -755 -1345 -874 -836 -450 898 271 1276 -52 579 107 -416 -306 -580 248 451 888 244 -720 -1140 -1224 -883 -1689 -1161 -1559 -326 -367 246 1087 1158 1303 369 76 -773 -259 -94 136 -36 -323 858 392 1029 784 167 -475 422 758 69 -275 -313 -469 -588 -29 -206 -25 902 645 199 255 -551 -1234 900000 SS 20211231T145427.5Z 8035.621151 187 1 22.53 2 70.13 149.68 64.54 181.98 0.00 1 0.00 1 0 17 5.578e-02 7.461e-03 3.329e-02 3.264e-03 3.706456e-01 1.684322e-03 4.482192e-03 -6.000000e+00 3.204150e-02 223.28 -2.00 3.51 -2.00 319.28 0.00e+00 1.405844e-03 4.178110e-04 8.588769e-04 -6.000000e+00 1.391327e-03 276.11 -2.00 20.00 -2.00 318.70 0.00e+00 2.910 0.000 302.00 328.00 3 3.7422e+00 4.6559e-03 3.4563e-02 -6.0000e+00 7.8975e-02 2.0964e-02 5.3927e-03 1.9212e-02 -6.0000e+00 8.5816e-02 3.7972e-04 4.1148e-03 9.9824e-03 -6.0000e+00 5.1076e-02 -7.2601e-03 2.1730e-03 3.2033e-03 -6.0000e+00 2.2032e-02 4.4407e-04 1.9816e-06 1.0027e-04 3.8589e-05 -6.0000e+00 1.5674e-03 2.5164e-02 3.5162e-05 12 9 1 12 1 1 99.99 24.14 0.24 0.02516 0.02518 50 27 1 5 0 438.430 28.10 19.99 24.14 18.97 23.5 1016.38 -1989 -21452 -5786 -19820 -13903 -12007 -39064 -14520 -19045 3395 -15233 111 -13307 -3455 2542 -3934 -197 -3919 737 -4266 1922 2593 3651 -3423 -3131 907 -7023 1123 -6507 3651 -4976 -125 2074 -2954 -4403 -6598 -2104 -2735 3290 -1118 1803 -635 -522 -90 -792 -43 -1715 828 -1589 2359 -154 1252 3110 1404 1760 107 1686 -220 1069 823 1927 1542 2558 2727 305 275 82 910 1208 449 339 554 920 45 -334 -1289 -1730 -1802 -2183 -1391 -2230 -1101 -1799 -475 -596 -514 249 418 924 5 134 -1761 -732 -905 -417 -133 1058 759 329 129 -862 -797 -1535 -43 -764 -1185 -475 -65 943 934 1025 698 679 -71 -330 -668 -142 -101 268 -311 74 532 669 571 42 -260 549 -321 546 -116 -405 -644 -401 88 -393 120 257 439 76 184 -286 -584 900000 -50 -720 -169 -619 -374 -316 -1469 -483 -733 120 -659 5 -733 -206 167 -307 -16 -347 65 -414 177 239 347 -374 -361 104 -860 120 -727 385 -635 -17 301 -454 -652 -1018 -349 -543 740 -303 516 -195 -166 -29 -256 -14 -558 262 -519 772 -56 484 1262 613 792 50 790 -104 488 379 923 811 1463 1652 186 158 45 507 742 313 254 426 692 32 -220 -771 -969 -1013 -1357 -983 -1794 -965 -1689 -466 -570 -523 263 449 975 5 137 -1691 -659 -834 -420 -150 1204 953 430 162 -1018 -951 -1788 -52 -909 -1487 -624 -90 1385 1478 1706 1169 1092 -108 -465 -912 -196 -148 416 -505 120 834 1014 828 58 -346 781 -440 806 -185 -686 -1128 -725 166 -795 250 549 948 163 379 -566 -1119 900000 SS 20211231T150316.2Z 8035.627271 190 1 47.66 2 69.31 151.66 64.65 184.15 0.00 1 0.00 1 0 17 3.068e-02 5.625e-03 4.551e-03 5.150e-04 3.558302e-01 2.620862e-04 4.268084e-03 -6.000000e+00 1.761178e-02 223.28 -2.00 3.51 -2.00 319.07 0.00e+00 9.004935e-04 6.131527e-05 4.603959e-04 -6.000000e+00 7.653420e-04 276.11 -2.00 20.00 -2.00 318.50 0.00e+00 2.803 0.000 302.00 328.00 3 1.1544e+00 7.1607e-04 3.3174e-02 -6.0000e+00 4.3408e-02 3.4859e-03 8.2514e-04 1.8262e-02 -6.0000e+00 4.7178e-02 7.0381e-03 6.1775e-04 9.2673e-03 -6.0000e+00 2.8079e-02 -1.1680e-02 3.2782e-04 2.8074e-03 -6.0000e+00 1.2106e-02 6.7543e-03 -4.7510e-04 1.5675e-05 3.3405e-05 -6.0000e+00 8.6229e-04 2.6693e-02 -6.2529e-05 10 0 0 10 0 0 89.77 24.13 0.22 0.02669 0.02312 852 209 1 5 0 55.930 28.10 20.00 24.13 19.87 23.8 1024.98 -4527 -9015 -6733 -11715 -15462 -11940 -12357 -5057 -7086 -7420 -9694 -6751 -5900 -3595 -1017 -1793 60 -513 605 -307 69 -355 -468 -620 -1024 -954 -2303 -2269 -2649 -678 -319 546 -204 -3234 -3599 -4294 -2609 -1516 315 -470 -732 -244 -425 9 40 434 -374 -141 -650 422 933 810 1530 1003 1153 1051 673 160 13 379 1041 1897 2335 1969 599 106 -642 35 1016 840 803 544 671 138 -227 -866 -1625 -1528 -1275 -1041 -1135 -1637 -1911 -1363 -794 -261 299 644 824 489 516 -281 -320 -174 -225 107 668 520 30 -235 -935 -983 -552 -624 -885 -958 -613 -345 408 573 645 538 337 -114 -168 -52 -34 184 267 -54 166 254 338 435 324 -106 391 374 149 99 -159 -293 -261 -68 -34 -2 340 172 9 -14 -370 -559 900000 -136 -309 -229 -426 -534 -398 -452 -195 -308 -338 -459 -339 -345 -244 -78 -154 5 -49 60 -32 7 -38 -52 -74 -130 -125 -302 -281 -317 -83 -43 81 -33 -546 -578 -710 -477 -327 80 -139 -235 -82 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