File name: Pandora180s1_BronxNY_20220519_L2Fit_fout2c2d20210302p1-8.txt File generation date: 20260323T080648.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20220519_L1_smca1c2d20210302p1-8.txt Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20220519 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0771 305.2181 305.3590 305.5000 305.6409 305.7819 305.9228 306.0637 306.2046 306.3455 306.4864 306.6273 306.7681 306.9090 307.0498 307.1906 307.3315 307.4723 307.6131 307.7539 307.8946 308.0354 308.1762 308.3169 308.4577 308.5984 308.7391 308.8798 309.0205 309.1612 309.3019 309.4425 309.5832 309.7238 309.8644 310.0051 310.1457 310.2863 310.4269 310.5674 310.7080 310.8486 310.9891 311.1297 311.2702 311.4107 311.5512 311.6917 311.8322 311.9726 312.1131 312.2536 312.3940 312.5344 312.6749 312.8153 312.9557 313.0961 313.2364 313.3768 313.5172 313.6575 313.7978 313.9382 314.0785 314.2188 314.3591 314.4994 314.6396 314.7799 314.9201 315.0604 315.2006 315.3408 315.4810 315.6212 315.7614 315.9016 316.0418 316.1819 316.3221 316.4622 316.6023 316.7424 316.8825 317.0226 317.1627 317.3028 317.4428 317.5829 317.7229 317.8629 318.0029 318.1430 318.2829 318.4229 318.5629 318.7029 318.8428 318.9828 319.1227 319.2626 319.4025 319.5424 319.6823 319.8222 319.9620 320.1019 320.2417 320.3816 320.5214 320.6612 320.8010 320.9408 321.0806 321.2203 321.3601 321.4998 321.6396 321.7793 321.9190 322.0587 322.1984 322.3381 322.4778 322.6174 322.7571 322.8967 323.0363 323.1760 323.3156 323.4552 323.5947 323.7343 323.8739 324.0134 324.1530 324.2925 324.4320 324.5715 324.7110 324.8505 324.9900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220519T194334.0Z 8174.821921 544 1 5.82 2 41.95 253.17 162.55 320.81 0.00 1 0.00 1 0 17 1.527e-02 8.507e-03 9.138e-03 4.751e-03 2.114419e-01 2.497450e-03 2.551316e-03 -6.000000e+00 9.021929e-03 231.36 -2.00 3.51 -2.00 316.04 0.00e+00 5.135947e-04 2.611632e-04 1.619714e-04 -6.000000e+00 3.933396e-04 283.96 -2.00 20.00 -2.00 315.34 0.00e+00 1.343 0.000 302.00 328.00 3 5.1977e+00 6.5156e-03 1.7455e-02 -6.0000e+00 2.2599e-02 4.2987e-02 7.2293e-03 1.0946e-02 -6.0000e+00 2.4399e-02 -4.8051e-03 4.1676e-03 5.3190e-03 -6.0000e+00 1.4497e-02 -2.9940e-03 1.9202e-03 1.4657e-03 -6.0000e+00 6.1766e-03 5.8997e-04 -1.8309e-04 1.4046e-04 1.8827e-05 -6.0000e+00 4.3032e-04 3.7418e-02 -8.3219e-05 12 9 1 12 1 1 999.00 23.90 0.29 0.03742 0.03604 2 6 1 5 0 1883.430 27.78 20.00 23.90 28.09 28.3 1096.80 446 3902 -180 -9230 -4043 -1556 3639 774 683 -1709 -1830 -2420 -3263 1714 427 734 1455 198 844 1887 986 743 143 1383 -1773 1630 -707 -1789 -151 -1171 645 2796 481 -4101 -4162 -3154 -2570 -62 417 -158 -428 -391 15 745 183 -1305 784 -92 -747 470 -538 1440 1700 466 1074 1297 2181 338 -254 1234 329 1310 2457 914 1027 -995 -1297 -379 1243 570 -13 -143 1218 -95 -4 -1101 -1822 -1922 -2033 -1307 -1153 -1622 -1235 -970 -1443 167 578 404 81 473 7 -674 -1015 -830 -384 353 900 -213 824 -287 -416 -587 -471 -1086 -1121 -878 93 172 1015 961 714 704 122 379 -355 -115 112 137 489 361 699 436 612 305 -111 -742 568 191 616 -196 -401 -94 172 -551 -523 -509 530 27 -20 394 -497 -661 900000 98 871 -41 -2082 -781 -291 698 171 163 -424 -447 -624 -951 538 137 250 504 72 313 712 376 282 56 565 -779 704 -302 -717 -56 -441 252 1142 212 -1853 -1767 -1356 -1233 -34 248 -107 -309 -291 12 558 137 -980 559 -64 -512 324 -397 1102 1361 362 846 1036 1737 270 -201 974 275 1168 2318 900 962 -867 -1064 -309 1095 564 -12 -144 1194 -96 -4 -926 -1531 -1587 -1814 -1198 -1170 -1662 -1325 -1097 -1644 199 717 511 101 554 8 -710 -1072 -877 -403 406 1062 -274 1072 -361 -522 -687 -545 -1348 -1395 -1141 125 241 1394 1391 1065 1030 168 513 -446 -149 148 179 684 528 1028 630 855 406 -141 -961 705 246 841 -265 -562 -133 250 -793 -796 -803 847 44 -32 615 -757 -979 900000 SS 20220519T195707.1Z 8174.831332 550 1 14.78 2 44.42 256.11 163.92 329.52 0.00 1 0.00 1 0 17 1.032e-02 6.671e-03 2.490e-03 1.157e-03 2.187628e-01 6.048970e-04 2.613674e-03 -6.000000e+00 6.102966e-03 231.36 -2.00 3.51 -2.00 316.43 0.00e+00 4.373426e-04 6.957152e-05 1.418293e-04 -6.000000e+00 2.659652e-04 283.96 -2.00 20.00 -2.00 315.72 0.00e+00 1.398 0.000 302.00 328.00 3 3.5644e+00 1.5841e-03 1.8119e-02 -6.0000e+00 1.5287e-02 3.2245e-02 1.7608e-03 1.1321e-02 -6.0000e+00 1.6501e-02 -3.3815e-03 1.0225e-03 5.5056e-03 -6.0000e+00 9.8042e-03 -4.5913e-03 4.8038e-04 1.5249e-03 -6.0000e+00 4.1801e-03 2.8359e-03 3.7391e-04 3.4184e-05 1.8836e-05 -6.0000e+00 2.9078e-04 3.5662e-02 4.9039e-05 12 9 1 12 1 1 99.97 23.89 0.34 0.03566 0.03847 51 42 1 5 0 280.990 27.78 20.00 23.89 28.75 28.0 1098.31 -262 -33 -535 -3134 -1647 -3573 -1020 -564 -856 -2593 -2934 -1515 -1014 36 490 449 52 622 1291 1927 780 982 998 750 931 230 -730 -1216 -475 532 330 1502 329 -2258 -3663 -2948 -1792 -614 255 -459 -225 -240 -141 -53 -51 80 -189 -734 -832 274 544 1163 1101 983 846 1020 547 464 543 404 1171 1531 2146 1074 124 -535 -1020 -66 624 689 528 452 579 173 -104 -751 -1837 -1536 -1532 -1315 -1332 -1627 -1733 -1258 -672 -173 188 664 552 345 89 -417 -616 -288 -171 61 687 648 236 -246 -674 -866 -573 -524 -653 -813 -649 -228 514 642 740 624 397 -195 20 -39 64 222 447 93 277 352 507 588 440 25 221 353 133 267 -164 -430 -109 -234 -36 2 403 106 -61 -192 -474 -786 900000 -49 -6 -104 -568 -265 -580 -175 -108 -178 -558 -623 -333 -249 10 150 146 18 196 416 635 261 326 342 271 350 89 -276 -471 -172 191 126 607 129 -894 -1519 -1240 -760 -304 149 -278 -145 -160 -96 -36 -34 54 -123 -464 -563 187 359 809 805 749 658 806 437 367 422 317 956 1344 2007 966 117 -462 -831 -53 551 626 514 451 566 162 -97 -629 -1425 -1166 -1256 -1206 -1356 -1663 -1867 -1424 -813 -206 232 833 682 403 102 -439 -654 -306 -180 71 814 832 311 -311 -857 -1026 -669 -651 -811 -1059 -883 -322 761 934 1106 918 591 -267 25 -51 85 293 632 138 414 515 717 790 605 32 280 463 173 366 -234 -625 -162 -365 -55 2 656 175 -100 -307 -733 -1184 900000 SS 20220519T200553.8Z 8174.837428 553 1 47.80 2 46.04 257.92 164.63 335.84 0.00 1 0.00 1 0 17 1.075e-02 6.556e-03 6.387e-04 2.562e-04 2.229360e-01 1.331504e-04 2.672278e-03 -6.000000e+00 6.355291e-03 231.36 -2.00 3.51 -2.00 316.84 0.00e+00 5.564217e-04 1.681714e-05 1.678590e-04 -6.000000e+00 2.770306e-04 283.96 -2.00 20.00 -2.00 316.11 0.00e+00 1.438 0.000 302.00 328.00 3 1.5475e+00 3.5068e-04 1.8590e-02 -6.0000e+00 1.5919e-02 1.3299e-02 3.9111e-04 1.1576e-02 -6.0000e+00 1.7185e-02 -1.8994e-03 2.2898e-04 5.6404e-03 -6.0000e+00 1.0211e-02 -5.9284e-03 1.0961e-04 1.5757e-03 -6.0000e+00 4.3521e-03 2.0497e-02 3.1771e-05 7.6387e-06 1.8399e-05 -6.0000e+00 3.0294e-04 3.6336e-02 -1.7381e-05 11 8 0 10 0 0 93.41 23.89 0.20 0.03634 0.03657 1012 248 1 5 0 47.230 27.78 19.99 23.89 29.04 28.3 1100.00 -98 -243 -1197 -3775 -3644 -2934 -829 -97 -454 -2413 -3023 -2122 -1275 250 479 221 392 677 1061 1199 457 739 913 666 797 412 -534 -1201 -886 -3 665 1437 230 -2222 -3335 -3057 -2198 -735 74 -343 -464 -338 -288 -43 117 -119 -440 -630 -687 252 645 1006 1228 977 912 1059 641 365 248 622 1082 1788 2071 1333 141 -492 -1062 -201 722 742 668 531 513 190 -351 -1041 -1745 -1662 -1408 -1251 -1325 -1808 -1814 -1260 -761 -252 277 593 626 386 282 -445 -576 -221 -276 167 731 530 107 -217 -819 -991 -467 -617 -765 -789 -583 -286 476 635 705 531 326 -63 -100 -43 81 236 401 127 327 320 422 504 421 104 411 406 140 79 -201 -357 -225 -81 17 3 332 89 -5 -115 -490 -752 900000 -15 -39 -193 -566 -493 -391 -117 -15 -78 -428 -532 -390 -261 57 122 60 110 197 317 368 142 228 290 223 278 147 -187 -393 -273 -1 215 495 85 -825 -1177 -1101 -881 -343 37 -195 -281 -211 -184 -27 74 -75 -269 -375 -401 149 402 663 848 705 672 793 486 274 183 463 841 1490 1846 1235 127 -406 -828 -156 610 700 618 504 479 184 -314 -840 -1300 -1216 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