File name: Pandora180s1_BronxNY_20230324_L2Fit_fwvt1c2d20210302p1-8.txt File generation date: 20260323T091228.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20230324_L1_smca1c2d20210302p1-8.txt.bz2 Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20230324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1787 Nominal wavelengths inside fitting window [nm]: 492.1095 492.2310 492.3525 492.4740 492.5954 492.7169 492.8383 492.9597 493.0811 493.2025 493.3238 493.4452 493.5665 493.6878 493.8091 493.9304 494.0516 494.1729 494.2941 494.4153 494.5365 494.6577 494.7788 494.9000 495.0211 495.1422 495.2633 495.3844 495.5054 495.6265 495.7475 495.8685 495.9895 496.1104 496.2314 496.3523 496.4733 496.5942 496.7150 496.8359 496.9568 497.0776 497.1984 497.3192 497.4400 497.5608 497.6815 497.8023 497.9230 498.0437 498.1644 498.2850 498.4057 498.5263 498.6469 498.7675 498.8881 499.0087 499.1292 499.2497 499.3702 499.4907 499.6112 499.7317 499.8521 499.9726 500.0930 500.2134 500.3337 500.4541 500.5744 500.6948 500.8151 500.9353 501.0556 501.1759 501.2961 501.4163 501.5365 501.6567 501.7769 501.8970 502.0172 502.1373 502.2574 502.3775 502.4975 502.6176 502.7376 502.8576 502.9776 503.0976 503.2176 503.3375 503.4574 503.5774 503.6972 503.8171 503.9370 504.0568 504.1766 504.2964 504.4162 504.5360 504.6558 504.7755 504.8952 505.0149 505.1346 505.2543 505.3739 505.4935 505.6132 505.7328 505.8523 505.9719 506.0914 506.2110 506.3305 506.4500 506.5694 506.6889 506.8083 506.9278 507.0472 507.1666 507.2859 507.4053 507.5246 507.6439 507.7632 507.8825 508.0018 508.1210 508.2403 508.3595 508.4787 508.5978 508.7170 508.8361 508.9553 509.0744 509.1935 509.3125 509.4316 509.5506 509.6696 509.7886 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230324T152725.2Z 8483.644042 195 1 48.22 2 44.79 145.38 57.33 97.73 0.00 1 0.00 1 0 15 4.444e-03 4.463e-03 1.867e-03 1.859e-03 9.848276e+02 1.078393e+02 7.623473e+01 -6.000000e+00 2.485074e+02 277.91 -2.00 20.00 -2.00 505.26 0.00e+00 5.816813e-04 5.122116e-05 2.961607e-05 -6.000000e+00 1.246028e-04 277.91 -2.00 20.00 -2.00 500.37 0.00e+00 1.119497e-01 3.752807e-02 8.260605e-03 -6.000000e+00 8.949409e-02 226.87 -2.00 3.51 -2.00 501.99 0.00e+00 1.407 0.000 489.00 513.00 1 8.3701e+00 2.8674e-03 2.2441e-03 -6.0000e+00 6.8563e-03 3.2391e-03 7.4818e-04 2.1115e-04 -6.0000e+00 1.7724e-03 3.6583e-04 -1.0352e-03 1.9982e-04 1.4951e-05 -6.0000e+00 4.8736e-04 5.8328e-02 -1.5920e-04 11 8 0 10 0 0 99.29 24.21 0.39 0.05833 0.05115 13 3 1 4 0 3708.550 28.10 19.99 24.21 14.03 34.8 1044.27 -667 -638 -871 59 -114 613 600 386 533 210 -267 116 -754 -677 -480 -406 287 -263 148 163 470 -196 495 439 500 1029 661 17 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-217 -45 -147 204 357 455 502 715 555 666 424 -80 -323 -151 -275 -219 1 124 9 133 322 -47 -186 -267 -156 -587 -721 -470 -61 -15 -41 294 -68 -98 280 850 655 249 -442 -38 -285 -788 SQ 20230324T153957.3Z 8483.652747 202 1 49.26 2 43.51 149.49 55.01 99.91 0.00 1 0.00 1 0 15 4.139e-03 4.167e-03 1.165e-03 1.161e-03 9.554012e+02 6.746619e+01 7.578435e+01 -6.000000e+00 2.314085e+02 277.91 -2.00 20.00 -2.00 505.28 0.00e+00 5.549544e-04 3.197201e-05 2.841102e-05 -6.000000e+00 1.160278e-04 277.91 -2.00 20.00 -2.00 500.41 0.00e+00 1.478146e-01 2.336211e-02 7.881473e-03 -6.000000e+00 8.331339e-02 226.87 -2.00 3.51 -2.00 502.03 0.00e+00 1.377 0.000 489.00 513.00 1 7.7124e+00 1.7855e-03 2.1868e-03 -6.0000e+00 6.3831e-03 2.0535e-03 4.6299e-04 2.0623e-04 -6.0000e+00 1.6495e-03 7.0762e-04 -1.6839e-03 1.2445e-04 1.4427e-05 -6.0000e+00 4.5376e-04 5.6918e-02 -1.3127e-04 11 8 0 10 0 0 99.89 24.21 0.34 0.05692 0.04524 18 4 1 4 0 2736.370 28.10 19.99 24.21 14.36 35.0 1047.87 -743 -747 -559 -240 119 379 478 631 523 230 -215 -342 -587 -660 -768 -592 -244 219 -25 275 424 300 430 704 509 812 466 -114 -601 -1099 -598 -336 324 564 174 37 345 -122 -232 -92 -65 322 155 688 649 460 300 231 -149 -452 -689 -864 -679 -213 68 105 106 49 -8 503 296 658 517 153 325 131 246 -253 -398 -175 -520 -623 124 203 3 -283 -421 -265 -631 -376 9 -277 8 -134 98 192 -136 -155 -141 -115 587 632 514 705 389 279 -275 -366 -588 -643 -617 -120 240 -67 -286 -354 -310 -243 -156 15 -109 498 179 493 386 566 442 286 370 71 -154 -124 77 -96 -81 41 202 119 293 -13 -260 -263 -606 -462 -331 -55 -197 -11 176 133 257 266 849 473 35 -272 -337 -742 -683 -723 -744 -573 -253 127 414 528 696 574 249 -230 -362 -615 -686 -800 -623 -261 238 -26 285 441 313 448 734 532 842 479 -115 -638 -1149 -621 -353 324 579 182 38 355 -125 -235 -93 -66 328 160 713 675 478 308 234 -147 -436 -697 -865 -682 -203 66 105 107 50 -8 507 300 667 524 155 324 129 238 -243 -379 -165 -492 -595 119 196 3 -270 -396 -246 -587 -350 8 -261 7 -129 95 186 -133 -151 -138 -114 583 635 519 705 385 270 -262 -342 -542 -591 -575 -115 235 -67 -287 -353 -304 -238 -153 15 -109 505 184 509 401 588 459 294 375 71 -153 -123 77 -96 -81 41 200 118 288 -13 -251 -250 -573 -437 -317 -54 -195 -11 167 126 246 256 814 454 33 -255 -330 -720 -660 SQ 20230324T154502.2Z 8483.656275 205 1 23.70 2 43.04 151.20 54.08 100.82 0.00 1 0.00 1 0 22 3.714e-03 3.708e-03 2.401e-04 2.398e-04 5.033419e+02 1.342405e+01 4.079258e+01 -6.000000e+00 2.076820e+02 277.92 -2.00 20.00 -2.00 505.26 0.00e+00 5.606355e-04 6.588428e-06 2.806402e-05 -6.000000e+00 1.041332e-04 277.92 -2.00 20.00 -2.00 500.48 0.00e+00 1.131777e-01 4.797700e-03 5.324616e-03 -6.000000e+00 7.479568e-02 226.87 -2.00 3.51 -2.00 502.07 0.00e+00 1.366 0.000 489.00 513.00 1 4.3502e+00 3.6785e-04 2.1128e-03 -6.0000e+00 5.7301e-03 2.0898e-04 9.5275e-05 1.4458e-04 -6.0000e+00 1.4814e-03 2.0519e-02 -1.5598e-03 2.5704e-05 1.2065e-05 -6.0000e+00 4.0730e-04 6.0624e-02 -1.7729e-04 12 1 1 12 1 1 99.76 24.21 0.29 0.06062 0.04980 174 88 1 4 0 134.470 28.10 20.00 24.21 14.75 35.1 1051.00 -1005 -584 -486 -242 19 406 533 515 372 264 105 -274 -412 -501 -638 -500 -95 101 91 83 219 275 439 570 608 567 448 -87 -473 -668 -625 -407 210 362 58 114 149 -66 -187 -105 38 115 267 448 485 517 409 254 -116 -431 -792 -779 -730 -292 -63 103 141 53 243 315 440 494 452 436 256 155 112 -162 -385 -409 -315 -295 -4 65 -95 -403 -411 -317 -278 -281 -242 -229 -92 74 135 33 32 -42 -107 64 392 504 381 410 438 289 -155 -423 -638 -663 -563 -93 171 57 -239 -246 -309 -276 -231 2 102 190 338 480 616 638 465 256 51 -146 -154 -21 138 30 119 196 192 273 274 118 -192 -330 -465 -508 -263 -201 -96 -9 165 147 243 436 534 467 106 -278 -698 -728 -510 -994 -589 -482 -247 20 429 569 551 396 277 109 -280 -417 -503 -643 -509 -99 107 98 86 227 285 455 591 631 585 458 -91 -487 -674 -629 -414 219 369 60 118 152 -67 -188 -106 38 117 274 463 503 533 417 255 -119 -433 -778 -756 -711 -289 -64 102 142 53 245 317 443 499 457 438 254 152 113 -162 -381 -402 -310 -293 -4 66 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