File name: Pandora180s1_BronxNY_20230422_L2Fit_fwvt1c2d20210302p1-8.txt File generation date: 20260323T091826.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20230422_L1_smca1c2d20210302p1-8.txt.bz2 Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20230422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1639 1787 Nominal wavelengths inside fitting window [nm]: 492.1095 492.2310 492.3525 492.4740 492.5954 492.7169 492.8383 492.9597 493.0811 493.2025 493.3238 493.4452 493.5665 493.6878 493.8091 493.9304 494.0516 494.1729 494.2941 494.4153 494.5365 494.6577 494.7788 494.9000 495.0211 495.1422 495.2633 495.3844 495.5054 495.6265 495.7475 495.8685 495.9895 496.1104 496.2314 496.3523 496.4733 496.5942 496.7150 496.8359 496.9568 497.0776 497.1984 497.3192 497.4400 497.5608 497.6815 497.8023 497.9230 498.0437 498.1644 498.2850 498.4057 498.5263 498.6469 498.7675 498.8881 499.0087 499.1292 499.2497 499.3702 499.4907 499.6112 499.7317 499.8521 499.9726 500.0930 500.2134 500.3337 500.4541 500.5744 500.6948 500.8151 500.9353 501.0556 501.1759 501.2961 501.4163 501.5365 501.6567 501.7769 501.8970 502.0172 502.1373 502.2574 502.3775 502.4975 502.6176 502.7376 502.8576 502.9776 503.0976 503.2176 503.3375 503.4574 503.5774 503.6972 503.8171 503.9370 504.0568 504.1766 504.2964 504.4162 504.5360 504.6558 504.7755 504.8952 505.0149 505.1346 505.2543 505.3739 505.4935 505.6132 505.7328 505.8523 505.9719 506.0914 506.2110 506.3305 506.4500 506.5694 506.6889 506.8083 506.9278 507.0472 507.1666 507.2859 507.4053 507.5246 507.6439 507.7632 507.8825 508.0018 508.1210 508.2403 508.3595 508.4787 508.5978 508.7170 508.8361 508.9553 509.0744 509.1935 509.3125 509.4316 509.5506 509.6696 509.7886 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230422T144829.9Z 8512.617013 212 1 18.43 2 39.68 127.13 54.49 89.42 0.00 1 0.00 1 0 15 4.155e-03 4.140e-03 1.755e-03 1.748e-03 6.773531e+02 1.006158e+02 4.344151e+01 -6.000000e+00 2.351997e+02 281.02 -2.00 20.00 -2.00 505.22 0.00e+00 4.929602e-04 4.825763e-05 2.372337e-05 -6.000000e+00 1.173394e-04 281.02 -2.00 20.00 -2.00 500.34 0.00e+00 1.026296e-01 3.531837e-02 7.426238e-03 -6.000000e+00 8.372413e-02 229.17 -2.00 3.51 -2.00 501.93 0.00e+00 1.298 0.000 489.00 513.00 1 7.7054e+00 2.7129e-03 2.0373e-03 -6.0000e+00 6.4202e-03 7.4899e-03 7.0181e-04 1.7735e-04 -6.0000e+00 1.6586e-03 7.2386e-04 -1.5647e-03 1.8799e-04 9.8674e-06 -6.0000e+00 4.5566e-04 5.8563e-02 -1.4566e-04 12 9 1 12 1 1 99.89 24.27 0.25 0.05856 0.04771 6 4 1 4 0 2608.240 28.21 20.00 24.27 19.90 34.7 1049.94 -612 -659 -724 -269 200 254 417 277 254 350 -120 -260 -680 -505 -449 -600 -278 442 290 85 515 -13 484 585 602 651 455 -162 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74 72 694 506 285 565 484 323 248 191 -181 160 -209 120 -238 -145 -37 264 636 126 51 -244 -148 -850 -350 -23 -178 -218 -93 -40 252 173 236 507 405 293 -501 -496 -508 -646 SQ 20230422T145605.2Z 8512.622283 218 1 48.66 2 38.55 129.46 53.08 90.60 0.00 1 0.00 1 0 15 4.058e-03 4.063e-03 1.462e-03 1.456e-03 9.921888e+02 8.442543e+01 7.814504e+01 -6.000000e+00 2.297316e+02 281.02 -2.00 20.00 -2.00 505.18 0.00e+00 3.606927e-04 3.989717e-05 1.653083e-05 -6.000000e+00 1.146117e-04 281.02 -2.00 20.00 -2.00 500.35 0.00e+00 9.132850e-02 2.919144e-02 6.772647e-03 -6.000000e+00 8.178123e-02 229.17 -2.00 3.51 -2.00 501.92 0.00e+00 1.278 0.000 489.00 513.00 1 8.0552e+00 2.2333e-03 1.9634e-03 -6.0000e+00 6.2712e-03 6.7109e-03 5.8384e-04 1.9396e-04 -6.0000e+00 1.6202e-03 5.1275e-04 -1.4968e-03 1.5583e-04 1.1697e-05 -6.0000e+00 4.4508e-04 5.8832e-02 -1.5056e-04 11 8 0 10 0 0 99.95 24.27 0.34 0.05883 0.04845 16 4 1 4 0 3041.060 28.21 20.00 24.27 20.13 34.8 1052.64 -973 -698 -564 -200 -26 364 612 502 504 78 -293 -180 -605 -386 -803 -364 75 -82 57 -311 415 237 621 716 331 362 418 157 -795 -570 -749 -597 72 582 1 220 473 -353 -334 -59 171 209 345 543 489 953 65 286 -386 -208 -806 -609 -603 -246 -72 -12 314 51 172 291 351 646 478 348 234 141 24 -103 -447 -284 -457 -372 -12 60 86 -733 -365 -245 -247 -296 -401 326 48 299 -206 443 178 228 1 -36 468 233 501 343 643 85 78 -486 -708 -275 -469 38 -50 145 -380 -395 -379 -25 -35 -206 369 260 556 342 438 467 350 260 -164 -293 -266 -36 -453 469 72 207 366 10 205 -451 9 -489 -356 -772 -42 -452 -364 -337 -20 278 407 491 324 574 210 -378 -392 -632 -459 -981 -719 -599 -218 -27 382 648 532 531 81 -303 -183 -609 -384 -804 -366 77 -86 60 -335 443 254 665 768 357 387 442 163 -811 -568 -746 -603 74 613 1 235 500 -372 -348 -62 178 220 365 579 523 1009 69 296 -393 -205 -780 -581 -578 -240 -73 -12 324 53 178 301 365 671 496 359 239 142 23 -101 -435 -274 -443 -363 -12 59 85 -717 -351 -233 -234 -281 -384 313 47 293 -204 439 177 227 1 -36 476 240 517 353 648 84 76 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34.8 1055.92 -1331 -236 96 -223 153 768 -281 586 431 95 197 186 -669 -497 -514 -88 -355 -225 -340 179 497 40 401 451 339 393 84 160 -480 -742 -511 -789 221 590 437 113 -473 275 -23 -266 -122 169 217 962 497 825 814 198 3 -482 -1348 -541 -464 -680 -193 -645 -46 -166 992 358 241 586 831 745 305 25 -314 -220 212 -632 -490 -161 133 -82 -278 -167 -606 352 -501 -594 -206 -168 206 164 180 -83 -260 -291 154 65 520 289 463 361 666 -24 -18 -437 -682 203 -676 -117 0 108 -253 -547 893 -409 116 -93 -58 646 -1 563 628 621 31 40 -281 -420 -160 -422 -46 -324 343 -136 99 100 531 -406 198 -501 -638 -235 -85 189 114 -427 -146 188 510 660 490 661 26 -21 -883 -827 -263 -1338 -241 97 -233 158 802 -300 621 454 99 203 195 -696 -512 -530 -92 -364 -236 -363 192 531 42 416 469 353 407 89 166 -487 -739 -524 -796 227 620 451 117 -487 287 -23 -276 -127 176 222 985 513 844 849 204 3 -475 -1351 -532 -457 -663 -193 -662 -48 -172 1015 368 241 586 855 762 309 25 -311 -215 204 -608 -471 -156 130 -81 -273 -162 -580 341 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