File name: Pandora180s1_BronxNY_20230504_L2Fit_fout2c2d20210302p1-8.txt File generation date: 20260323T091833.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 180 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora180_OF_v3d20201002.txt Instrument calibration file used: Pandora180s1_CF_v2d20210302.txt Level 1 file used: Pandora180s1_BronxNY_20230504_L1_smca1c2d20210302p1-8.txt.bz2 Full location name: New York State DEC Bronx-Pfizer PAMS station (36-005-0133) Short location name: BronxNY Country of location: USA Location latitude [deg]: 40.8679 Location longitude [deg]: -73.8781 Location altitude [m]: 31 Local noon date: 20230504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 222 364 Nominal wavelengths inside fitting window [nm]: 305.0771 305.2181 305.3590 305.5000 305.6409 305.7819 305.9228 306.0637 306.2046 306.3455 306.4864 306.6273 306.7681 306.9090 307.0498 307.1906 307.3315 307.4723 307.6131 307.7539 307.8946 308.0354 308.1762 308.3169 308.4577 308.5984 308.7391 308.8798 309.0205 309.1612 309.3019 309.4425 309.5832 309.7238 309.8644 310.0051 310.1457 310.2863 310.4269 310.5674 310.7080 310.8486 310.9891 311.1297 311.2702 311.4107 311.5512 311.6917 311.8322 311.9726 312.1131 312.2536 312.3940 312.5344 312.6749 312.8153 312.9557 313.0961 313.2364 313.3768 313.5172 313.6575 313.7978 313.9382 314.0785 314.2188 314.3591 314.4994 314.6396 314.7799 314.9201 315.0604 315.2006 315.3408 315.4810 315.6212 315.7614 315.9016 316.0418 316.1819 316.3221 316.4622 316.6023 316.7424 316.8825 317.0226 317.1627 317.3028 317.4428 317.5829 317.7229 317.8629 318.0029 318.1430 318.2829 318.4229 318.5629 318.7029 318.8428 318.9828 319.1227 319.2626 319.4025 319.5424 319.6823 319.8222 319.9620 320.1019 320.2417 320.3816 320.5214 320.6612 320.8010 320.9408 321.0806 321.2203 321.3601 321.4998 321.6396 321.7793 321.9190 322.0587 322.1984 322.3381 322.4778 322.6174 322.7571 322.8967 323.0363 323.1760 323.3156 323.4552 323.5947 323.7343 323.8739 324.0134 324.1530 324.2925 324.4320 324.5715 324.7110 324.8505 324.9900 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230504T125537.1Z 8524.538624 290 1 48.00 2 56.45 97.86 131.04 294.26 0.00 1 0.00 1 0 17 4.239e-02 8.641e-03 3.529e-02 6.280e-03 3.007768e-01 3.239096e-03 3.596384e-03 -6.000000e+00 2.486475e-02 230.17 -2.00 3.51 -2.00 318.67 0.00e+00 7.565126e-04 6.567903e-04 5.838938e-04 -6.000000e+00 1.084145e-03 282.32 -2.00 20.00 -2.00 317.95 0.00e+00 1.804 0.000 302.00 328.00 3 6.0013e+00 8.8268e-03 2.4092e-02 -6.0000e+00 6.2128e-02 6.5717e-02 1.0058e-02 1.5758e-02 -6.0000e+00 6.7235e-02 -7.4188e-03 6.6144e-03 7.7640e-03 -6.0000e+00 3.9952e-02 -6.4844e-03 3.4060e-03 2.2007e-03 -6.0000e+00 1.6969e-02 1.4226e-04 2.9444e-04 1.9192e-04 2.5270e-05 -6.0000e+00 1.1954e-03 6.3074e-02 -2.3729e-05 11 8 0 10 0 0 99.99 24.17 0.04 0.06307 0.06529 41 10 1 5 0 1170.540 28.10 20.00 24.17 16.21 35.3 1022.13 -324 -15812 -9614 -637 12783 13574 -25081 4780 -19884 -9146 -12320 -7425 -4761 -1680 7117 327 -1027 -674 -1685 1224 -3450 -1708 1933 659 1320 3592 -1411 442 -2148 -3556 77 4878 5661 -1844 -1196 -5572 -4363 -3004 3547 -57 770 536 517 -104 174 1568 -2232 -1872 14 111 483 2116 1186 1852 -68 -829 1668 2216 1664 2483 -187 1673 3089 2092 -899 -1311 -1149 1407 2436 796 356 1470 -310 -1780 -2133 -1598 -2346 -2897 -1160 -13 -859 -1755 -2293 -1109 -535 207 1413 1035 741 -158 63 -739 -2258 -842 -327 -93 468 685 18 272 -1243 -153 -625 -1031 -747 -1228 -65 -165 920 277 1346 417 471 -707 -328 556 -456 248 132 204 117 867 507 204 546 109 540 -327 -260 189 -12 -272 -507 230 -466 224 -227 -55 -215 340 -12 -362 900000 -18 -1105 -618 -34 548 589 -1766 281 -1613 -738 -1036 -653 -472 -187 820 43 -144 -99 -259 188 -555 -272 311 114 237 640 -254 73 -353 -618 14 926 1131 -385 -236 -1207 -1066 -865 1133 -21 302 218 214 -43 72 638 -925 -760 6 46 214 984 588 952 -37 -457 900 1168 869 1306 -107 1023 2009 1412 -594 -805 -678 835 1597 589 280 1159 -242 -1322 -1440 -1063 -1471 -1855 -809 -10 -753 -1527 -2112 -1071 -550 224 1568 1164 814 -181 65 -711 -2099 -798 -338 -107 595 935 26 357 -1526 -173 -710 -1259 -969 -1676 -91 -246 1444 465 2299 705 748 -1049 -451 743 -635 365 207 330 189 1347 761 292 740 142 690 -444 -380 292 -19 -447 -865 410 -885 435 -452 -110 -424 642 -21 -644 900000 SS 20230504T125942.0Z 8524.541458 293 1 4.92 2 55.69 98.60 131.72 295.16 0.00 1 0.00 1 0 17 1.684e-02 7.245e-03 1.038e-02 3.347e-03 2.912249e-01 1.733282e-03 3.431543e-03 -6.000000e+00 9.886066e-03 230.17 -2.00 3.51 -2.00 317.21 0.00e+00 6.581700e-04 2.441548e-04 1.642947e-04 -6.000000e+00 4.306812e-04 282.32 -2.00 20.00 -2.00 316.49 0.00e+00 1.769 0.000 302.00 328.00 3 4.0462e+00 4.5861e-03 2.3346e-02 -6.0000e+00 2.4703e-02 3.6866e-02 5.1387e-03 1.4969e-02 -6.0000e+00 2.6727e-02 -2.5183e-03 3.0930e-03 7.3250e-03 -6.0000e+00 1.5882e-02 -5.4292e-03 1.5225e-03 2.1002e-03 -6.0000e+00 6.7499e-03 1.0696e-03 1.0812e-03 9.8802e-05 2.2945e-05 -6.0000e+00 4.7490e-04 6.2452e-02 1.2839e-04 12 9 1 12 1 1 99.15 24.17 0.29 0.06245 0.07058 5 15 1 5 0 791.400 28.10 20.00 24.17 16.51 35.3 1024.41 -3166 -4555 1053 -4139 -4640 -7562 -6721 766 4807 -3928 -5146 -167 -1760 552 -487 237 1578 -549 996 178 1717 126 2906 1055 401 262 -427 -3016 -2852 722 1390 654 325 -3061 -3780 -3279 -2105 -655 903 -910 884 -564 557 346 -8 -986 448 -220 -255 1300 358 1152 1547 1242 846 226 668 -317 -181 937 899 1852 2475 1068 652 -673 -1493 -45 1069 496 381 363 1145 -552 -944 -908 -1704 -1660 -1546 -962 -1642 -1545 -1252 -1106 -799 -197 226 766 433 674 431 -156 -259 117 -410 143 424 667 -70 -162 -1048 -718 -112 -711 -442 -938 -420 -412 800 442 1522 160 -55 -473 11 93 175 -14 283 -191 423 600 454 610 51 -326 877 80 52 59 -418 -277 73 -14 38 52 332 253 215 73 -778 -1012 900000 -362 -557 119 -446 -463 -792 -770 91 596 -540 -720 -24 -301 107 -107 51 346 -129 239 44 421 32 743 291 116 77 -122 -829 -756 192 399 206 109 -1029 -1219 -1103 -799 -292 432 -498 504 -338 336 209 -5 -600 263 -128 -148 772 231 724 1023 859 601 165 487 -230 -129 671 683 1517 2015 905 527 -549 -1180 -36 881 457 372 359 1093 -504 -845 -731 -1293 -1277 -1316 -855 -1635 -1552 -1321 -1236 -956 -233 275 940 520 806 472 -169 -266 124 -446 173 531 899 -95 -211 -1267 -861 -134 -858 -567 -1265 -591 -573 1172 651 2281 238 -81 -649 15 123 239 -19 412 -289 632 872 636 862 69 -420 1106 107 76 85 -627 -424 115 -22 63 90 579 423 372 122 -1261 -1598 900000 SS 20230504T131918.2Z 8524.555071 308 1 48.15 2 52.04 102.30 134.93 299.72 0.00 1 0.00 1 0 17 6.919e-02 1.532e-02 5.041e-02 1.052e-02 2.852682e-01 5.443964e-03 3.365604e-03 -6.000000e+00 4.059669e-02 230.17 -2.00 3.51 -2.00 318.23 0.00e+00 1.025060e-03 9.670338e-04 1.524539e-04 -6.000000e+00 1.769197e-03 282.33 -2.00 20.00 -2.00 317.46 0.00e+00 1.622 0.000 302.00 328.00 3 6.9726e+00 1.4727e-02 2.2129e-02 -6.0000e+00 1.0144e-01 1.1042e-01 1.6677e-02 1.4792e-02 -6.0000e+00 1.0976e-01 -1.2954e-02 1.0566e-02 7.2822e-03 -6.0000e+00 6.5223e-02 -6.4916e-03 5.3295e-03 2.2221e-03 -6.0000e+00 2.7714e-02 6.4485e-05 5.2949e-04 3.2631e-04 2.5757e-05 -6.0000e+00 1.9509e-03 6.1593e-02 2.0945e-05 12 8 8 10 0 0 99.96 24.18 0.81 0.06159 0.06557 13 3 1 5 0 3703.800 28.10 20.00 24.18 17.57 35.2 1030.96 -6499 -27856 47491 5659 35904 -8737 -1800 541 -18126 2911 -5380 -5331 -12352 616 -1876 3195 -8669 -2411 -1307 10022 9755 2946 6671 2622 -10059 -3591 5187 -2758 50 -1401 7630 10556 -1596 -7777 -7487 -11953 -5569 8070 4109 8228 3943 -2869 223 543 5754 -484 -2224 -99 -2574 882 -1949 2233 1364 4806 -297 -2874 -2218 -1498 1118 2440 2741 1946 3349 -187 2053 429 -2350 2327 -794 109 -1070 2018 -30 -436 -1307 -4741 -2682 -3043 -2114 -4475 -2942 -1821 -1171 -1836 201 506 2512 840 1493 1329 -530 162 -2601 -1136 -1955 1725 2266 -546 1300 -1432 -654 -401 -1021 -638 426 46 -1403 -257 1798 1637 1582 779 255 428 878 -2038 -1769 161 -715 -1057 542 1114 927 119 -965 -667 -2389 -23 -321 1323 55 208 -280 340 388 -238 883 234 52 -1183 203 -380 900000 -528 -2953 2314 377 1627 -627 -132 43 -1890 249 -501 -542 -1552 78 -276 478 -1519 -414 -230 1619 1576 511 1163 502 -2279 -774 1074 -576 10 -289 1558 2274 -411 -2060 -1878 -3277 -1631 2454 1537 3307 1754 -1413 108 263 2640 -234 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