File name: Pandora162s1_Brussels-Uccle_20200520_L2Fit_fout2c2d20200309p1-8.txt File generation date: 20250630T092014.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: C. Hermans Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora162_OF_v5d20191031.txt Instrument calibration file used: Pandora162s1_CF_v2d20200309.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20200520_L1_smca1c2d20200309p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20200520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0904 305.2313 305.3722 305.5130 305.6538 305.7947 305.9355 306.0763 306.2171 306.3579 306.4986 306.6394 306.7801 306.9208 307.0616 307.2023 307.3429 307.4836 307.6243 307.7649 307.9056 308.0462 308.1868 308.3274 308.4680 308.6086 308.7492 308.8897 309.0303 309.1708 309.3113 309.4518 309.5923 309.7328 309.8733 310.0137 310.1542 310.2946 310.4350 310.5754 310.7158 310.8562 310.9966 311.1369 311.2773 311.4176 311.5579 311.6982 311.8385 311.9788 312.1191 312.2593 312.3996 312.5398 312.6801 312.8203 312.9605 313.1007 313.2408 313.3810 313.5211 313.6613 313.8014 313.9415 314.0816 314.2217 314.3618 314.5018 314.6419 314.7819 314.9220 315.0620 315.2020 315.3420 315.4819 315.6219 315.7619 315.9018 316.0417 316.1817 316.3216 316.4615 316.6013 316.7412 316.8811 317.0209 317.1607 317.3006 317.4404 317.5802 317.7199 317.8597 317.9995 318.1392 318.2789 318.4187 318.5584 318.6981 318.8378 318.9774 319.1171 319.2567 319.3964 319.5360 319.6756 319.8152 319.9548 320.0944 320.2339 320.3735 320.5130 320.6526 320.7921 320.9316 321.0711 321.2105 321.3500 321.4895 321.6289 321.7683 321.9078 322.0472 322.1866 322.3259 322.4653 322.6047 322.7440 322.8833 323.0227 323.1620 323.3013 323.4405 323.5798 323.7191 323.8583 323.9975 324.1368 324.2760 324.4152 324.5544 324.6935 324.8327 324.9718 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200520T041539.0Z 7445.177535 258 1 48.01 2 86.88 61.52 81.10 89.82 0.00 1 0.00 1 0 121 1.185e+00 8.726e-01 9.151e-01 6.921e-01 6.612905e-01 4.722940e-01 1.493071e-02 -6.000000e+00 9.314872e-01 231.45 -2.00 3.79 -2.00 311.67 0.00e+00 6.832962e-02 3.243398e-02 3.132344e-03 -6.000000e+00 4.638295e-02 277.60 -2.00 20.00 -2.00 311.75 0.00e+00 13.275 0.050 302.00 328.00 3 -1.5534e+00 1.1776e+00 1.4859e-01 -6.0000e+00 2.3148e+00 3.4866e+00 1.3227e+00 6.0143e-02 -6.0000e+00 2.5103e+00 -1.8685e+00 7.7420e-01 2.9676e-02 -6.0000e+00 1.5054e+00 3.5366e-01 3.2440e-01 2.6709e-02 -6.0000e+00 6.4422e-01 3.0758e-07 1.8617e-02 1.2648e-02 5.2858e-04 -6.0000e+00 4.6115e-02 2.1915e-02 -1.3283e-03 12 8 8 10 0 0 68.55 19.06 13.60 0.02191 0.16181 12 2 4 8 0 4000.000 15.00 19.06 19.24 21.38 21.58 30.3 1007.66 900000 900000 -15792 900000 16206 99708 900000 30307 900000 900000 900000 -95789 74794 47369 900000 900000 147880 -47031 26693 -38368 72185 900000 900000 900000 94678 900000 -26457 900000 4936 900000 145833 419135 -8365 900000 138250 743 900000 900000 900000 900000 900000 900000 900000 -58211 -27445 900000 900000 900000 5052 900000 14065 66413 -108433 29161 -45257 900000 900000 144385 130231 -85340 900000 900000 900000 -37570 -17575 900000 900000 900000 31770 15010 47342 900000 -73117 900000 52997 59962 900000 78360 900000 -77526 900000 900000 900000 900000 900000 900000 900000 900000 208024 900000 900000 900000 900000 900000 212844 136605 900000 900000 900000 30110 900000 -34705 121338 102108 900000 103961 81822 100087 900000 60216 111396 56667 -11491 -61697 -3379 900000 -28592 900000 277529 -24803 900000 -5159 900000 -42437 900000 -68858 900000 20099 187757 -20833 900000 144395 379715 900000 -1207 900000 -35966 114864 200227 900000 12243 176975 900000 900000 900000 -21590 900000 10673 65668 900000 19960 900000 900000 900000 -109618 49259 31197 900000 900000 97393 -79083 20165 -45228 47541 900000 900000 900000 62355 900000 -17425 900000 3251 900000 96045 276040 -5509 900000 91051 489 900000 900000 900000 900000 900000 900000 900000 -54262 -20194 900000 900000 900000 3327 900000 9263 43739 -178261 19205 -32172 900000 900000 95091 85770 -90281 900000 900000 900000 -32464 -11763 900000 900000 900000 20924 9885 31179 900000 -67729 900000 34903 39491 900000 51607 900000 -99211 900000 900000 900000 900000 900000 900000 900000 900000 137004 900000 900000 900000 900000 900000 140178 89968 900000 900000 900000 19830 900000 -32929 79912 67248 900000 68468 53887 65917 900000 39658 73365 37320 -13583 -112339 -3510 900000 -42329 900000 182779 -35881 900000 -5732 900000 -62643 900000 -129071 900000 20553 123656 -38205 900000 95098 250078 900000 -2370 900000 -102378 75649 131869 900000 18885 116555 900000 SS 20200520T042820.0Z 7445.186343 262 1 48.01 2 85.10 63.91 79.11 92.19 0.00 1 0.00 1 0 25 9.224e-01 3.794e-01 7.383e-01 3.423e-01 6.588656e-01 1.978059e-01 7.644733e-03 -6.000000e+00 5.630216e-01 231.45 -2.00 3.79 -2.00 317.43 0.00e+00 -3.201881e-02 2.180384e-02 5.435707e-03 -6.000000e+00 2.730233e-02 277.60 -2.00 20.00 -2.00 316.20 0.00e+00 9.969 0.021 302.00 328.00 3 1.7340e+00 5.2181e-01 1.1526e-01 -6.0000e+00 1.4211e+00 1.8885e+00 5.9022e-01 8.7792e-02 -6.0000e+00 1.5698e+00 -1.4853e+00 3.3733e-01 1.6165e-02 -6.0000e+00 9.1793e-01 4.2804e-01 1.5465e-01 2.9252e-02 -6.0000e+00 3.7597e-01 1.9679e-06 3.9507e-03 9.9918e-03 3.0772e-04 -6.0000e+00 2.7433e-02 7.8397e-03 -7.5856e-05 12 8 8 10 0 0 -210.79 19.06 1.83 0.00784 0.03753 12 2 4 8 0 4000.000 15.00 19.06 19.66 21.38 21.58 30.4 1010.80 900000 900000 53040 900000 -28390 15912 96588 103523 70672 900000 2223 91 900000 136640 -86860 22333 29723 124335 900000 900000 17391 -17828 169799 45247 102888 900000 -80329 42668 900000 -38991 23705 900000 900000 900000 -75528 -18812 -85055 12567 -9432 -42739 900000 900000 509810 900000 -34956 132573 12159 204150 -82142 92334 -5247 122143 -90875 900000 40206 83627 200100 -43517 900000 21401 89616 -1877 98246 900000 -17794 900000 -15054 109977 94925 170890 -16750 900000 301638 900000 900000 -34764 -56302 63705 900000 900000 19899 82145 900000 75683 900000 258454 107566 900000 26068 175083 13798 -26820 -49716 114555 17726 -12597 27043 13004 22006 -20948 174062 23503 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35026 16405 4673 -27573 43625 -35785 16502 -7618 -8867 6697 55717 26049 -27215 -1400 33072 22027 -57881 -6244 -6755 12559 -3068 47201 72 SS 20200520T044701.3Z 7445.199321 265 1 50.69 2 82.41 67.39 76.19 95.72 0.00 1 0.00 1 0 25 6.534e-01 3.293e-02 4.621e-01 2.539e-02 8.910983e-01 1.565318e-02 1.037144e-02 -6.000000e+00 3.872723e-01 231.45 -2.00 3.79 -2.00 322.32 0.00e+00 2.969765e-03 9.151135e-03 4.073576e-03 -6.000000e+00 2.248955e-02 277.60 -2.00 20.00 -2.00 321.89 0.00e+00 7.030 0.007 302.00 328.00 3 1.9685e+00 6.1066e-02 9.0373e-02 -6.0000e+00 9.7384e-01 9.0308e-01 8.3359e-02 5.9818e-02 -6.0000e+00 1.0664e+00 -1.2621e+00 7.7645e-02 3.0360e-02 -6.0000e+00 6.2630e-01 5.1512e-01 3.5817e-02 8.8924e-03 -6.0000e+00 2.6679e-01 2.8615e-05 -1.6820e-03 7.5646e-04 1.4662e-04 -6.0000e+00 1.8751e-02 1.5311e-03 4.9937e-05 12 8 8 10 0 0 7.94 19.06 0.86 0.00153 -0.01111 27 5 4 8 0 1877.060 15.00 19.06 20.34 21.38 21.69 30.7 1015.31 900000 900000 -170789 900000 900000 900000 -79386 -217397 -10677 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