File name: Pandora162s1_Brussels-Uccle_20210306_L2Fit_fout2c19d20200918p1-8.txt File generation date: 20250702T142519.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: C. Hermans Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 162 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora162_OF_v5d20191031.txt Instrument calibration file used: Pandora162s1_CF_v19d20200918.txt Level 1 file used: Pandora162s1_Brussels-Uccle_20210306_L1_smca1c19d20200918p1-8.txt Full location name: Uccle (BIRA-IASB, KMI-IRM) Short location name: Brussels-Uccle Country of location: Belgium Location latitude [deg]: 50.7980 Location longitude [deg]: 4.3580 Location altitude [m]: 107 Local noon date: 20210306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0788 305.2196 305.3605 305.5013 305.6422 305.7830 305.9238 306.0646 306.2054 306.3461 306.4869 306.6276 306.7683 306.9091 307.0498 307.1905 307.3311 307.4718 307.6125 307.7531 307.8937 308.0344 308.1750 308.3156 308.4561 308.5967 308.7373 308.8778 309.0183 309.1589 309.2994 309.4399 309.5803 309.7208 309.8613 310.0017 310.1422 310.2826 310.4230 310.5634 310.7038 310.8441 310.9845 311.1248 311.2652 311.4055 311.5458 311.6861 311.8264 311.9667 312.1069 312.2472 312.3874 312.5276 312.6679 312.8081 312.9483 313.0884 313.2286 313.3687 313.5089 313.6490 313.7891 313.9292 314.0693 314.2094 314.3495 314.4895 314.6296 314.7696 314.9096 315.0496 315.1896 315.3296 315.4696 315.6095 315.7495 315.8894 316.0293 316.1692 316.3091 316.4490 316.5889 316.7287 316.8686 317.0084 317.1482 317.2880 317.4278 317.5676 317.7074 317.8471 317.9869 318.1266 318.2663 318.4061 318.5458 318.6854 318.8251 318.9648 319.1044 319.2441 319.3837 319.5233 319.6629 319.8025 319.9421 320.0816 320.2212 320.3607 320.5003 320.6398 320.7793 320.9188 321.0583 321.1977 321.3372 321.4766 321.6161 321.7555 321.8949 322.0343 322.1737 322.3130 322.4524 322.5917 322.7311 322.8704 323.0097 323.1490 323.2883 323.4275 323.5668 323.7060 323.8453 323.9845 324.1237 324.2629 324.4021 324.5413 324.6804 324.8196 324.9587 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210306T064936.0Z 7735.284445 128 1 48.01 2 85.61 104.34 75.90 192.57 0.00 1 0.00 1 0 37 1.026e+00 6.356e-01 7.965e-01 5.276e-01 6.743843e-01 3.713261e-01 9.566645e-03 -6.000000e+00 6.749718e-01 224.73 -2.00 3.79 -2.00 313.87 0.00e+00 -1.596617e-02 1.910521e-02 1.832689e-03 -6.000000e+00 2.948142e-02 268.84 -2.00 20.00 -2.00 313.30 0.00e+00 10.807 0.027 302.00 328.00 3 8.7414e-01 9.2662e-01 1.1579e-01 -6.0000e+00 1.6833e+00 2.7135e+00 1.0479e+00 4.7840e-02 -6.0000e+00 1.8677e+00 -1.3181e+00 5.9464e-01 1.9378e-02 -6.0000e+00 1.0889e+00 1.5472e-01 2.3859e-01 1.4005e-02 -6.0000e+00 4.4353e-01 8.9844e-07 -1.7214e-02 1.6409e-02 2.3762e-04 -6.0000e+00 3.3669e-02 3.8497e-03 -9.8962e-05 12 9 8 11 8 0 -255.22 18.47 5.03 0.00385 -0.12550 12 2 4 8 0 4000.000 15.00 18.47 5.96 20.96 21.17 41.3 1021.65 900000 417153 900000 -111433 900000 -65485 900000 182451 900000 900000 -2763 -77579 900000 900000 57949 -23918 900000 900000 179466 45346 900000 74115 -24523 900000 173108 -38991 87647 -5048 -19906 900000 129757 900000 147523 900000 93502 -16291 900000 124364 900000 40088 91312 -5449 900000 76713 312707 -36232 900000 32710 -4798 41444 93432 900000 -67241 900000 900000 900000 -52199 900000 109684 18871 900000 -33694 900000 900000 900000 38438 900000 900000 900000 -13280 260062 -9956 19783 900000 -34979 44018 37143 -94640 900000 900000 900000 9790 -23232 900000 124637 -84594 900000 2074 900000 148228 900000 900000 1467 900000 124433 69910 24698 900000 103109 39138 63826 199361 11332 200264 27920 -18022 900000 102866 304753 3949 900000 16769 77672 2886 2030 12286 108950 900000 -5190 114571 -18045 29187 129584 117235 28498 -2073 -5778 21040 41612 -38857 21491 -2796 35645 -52791 76972 39345 40909 3417 -15144 21780 21433 -9511 13229 900000 212095 900000 -142427 900000 -38527 900000 92765 900000 900000 -1405 -74348 900000 900000 29463 -17132 900000 900000 91247 23055 900000 37683 -15725 900000 88014 -36858 44563 -3189 -12268 900000 65973 900000 75006 900000 47540 -8665 900000 63231 900000 20382 46426 -4689 900000 39003 158992 -34416 900000 16631 -2862 21072 47504 900000 -86132 900000 900000 900000 -66972 900000 55767 10446 900000 -27958 900000 900000 900000 19543 900000 900000 900000 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7.3792e-01 5.5750e-01 3.6049e-02 1.2624e-02 -6.0000e+00 3.0904e-01 3.0154e-05 -7.7701e-04 6.6813e-04 1.6914e-04 -6.0000e+00 2.2128e-02 8.9397e-04 -1.0641e-05 12 8 8 10 0 0 97.00 18.47 0.63 0.00089 -0.00494 35 7 4 8 0 1429.860 15.01 18.47 6.22 20.96 21.17 41.6 1021.69 900000 900000 900000 -110043 -211808 -61855 900000 -217069 -82182 900000 -146527 -93100 -141562 -2815 357740 900000 900000 900000 900000 104519 -73899 900000 -123466 900000 385809 -32100 900000 900000 900000 900000 93456 900000 900000 -12298 900000 -21094 -3831 -9750 76097 900000 17528 39095 160457 263270 99092 -3864 48621 -16553 159547 62639 156566 48439 24479 65211 65955 40830 88868 43859 57284 -5448 3544 31283 -9594 49699 -19757 69972 -7087 5263 -3609 3136 22305 -1489 31510 23033 -14235 6830 497 -5394 24499 3777 7717 20691 -2593 3376 14579 6691 8189 7057 -3324 -5083 -1179 -5638 3866 -239 -10022 3599 -4118 67 -2235 -1577 299 4241 -2250 -2960 7 -334 -5965 -2622 -2380 -2527 -2424 -1004 -3012 612 -206 -1796 -1420 771 499 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1.142e-02 9.462333e-01 6.889622e-03 1.055765e-02 -6.000000e+00 3.679792e-01 224.73 -2.00 3.79 -2.00 322.30 0.00e+00 -3.597565e-03 3.655824e-03 2.421498e-03 -6.000000e+00 1.870492e-02 268.84 -2.00 20.00 -2.00 321.91 0.00e+00 6.324 0.005 302.00 328.00 3 1.7060e+00 2.4992e-02 8.4159e-02 -6.0000e+00 9.1627e-01 5.7508e-01 4.0446e-02 5.9723e-02 -6.0000e+00 1.0076e+00 -8.2802e-01 4.6445e-02 3.4482e-02 -6.0000e+00 5.8211e-01 3.3048e-01 2.1137e-02 1.1713e-02 -6.0000e+00 2.4484e-01 7.5839e-05 -5.2007e-04 3.2948e-04 1.5391e-04 -6.0000e+00 1.8156e-02 5.2693e-04 -3.5606e-05 12 8 8 10 0 0 47.63 18.48 0.55 0.00053 -0.00338 59 12 4 8 0 847.840 15.01 18.48 6.56 20.96 21.17 41.5 1021.76 -271548 900000 -181078 900000 900000 900000 900000 900000 900000 -291915 900000 -243366 26122 -58590 900000 900000 63109 182254 187708 900000 -111341 900000 -128785 900000 900000 40035 -65194 900000 -74710 -84542 900000 192948 900000 -34559 -17329 -67657 -31921 20952 42907 8292 23678 29992 7805 117045 34636 101106 -15373 73551 -10494 32512 40737 28132 38580 15675 49587 4510 43390 20181 40298 2843 28691 32873 21667 16109 15501 23993 7823 21523 14963 12997 6208 9156 11452 5608 9177 -3240 10790 5846 14964 -2465 -1792 -758 -4655 4339 -2038 3458 -4388 2043 987 215 -2583 530 62 -5380 2447 -3433 162 -3801 1537 -543 -1278 -3957 -2030 3471 -3349 -3545 -2466 199 -1182 841 -516 23 -992 -691 -979 -659 103 -298 939 742 88 620 3043 2777 915 1784 -1396 1327 -598 360 476 74 -652 353 -215 -319 903 796 218 -644 107 -702 -1524 -4659 900000 -2010 900000 900000 900000 900000 900000 900000 -8839 900000 -5650 290 -651 900000 900000 701 2024 2084 900000 -2248 900000 -3250 900000 900000 445 -1119 900000 -1282 -1792 900000 2142 900000 -837 -332 -2117 -773 395 810 243 669 848 284 1559 1038 1572 -714 1633 -530 1299 1719 1530 2099 1076 2863 391 2891 1507 2550 227 1975 2409 1881 1707 1768 2519 995 2563 2160 2217 1241 1830 2162 1030 1445 -513 1569 954 2386 -572 -494 -241 -1706 1546 -825 1400 -1998 887 427 90 -1030 196 23 -2313 1141 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