File name: Pandora165s1_BuckeyeAZ_20260219_L2Fit_fout2c6d20250529p1-8.txt File generation date: 20260223T100637.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 165 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora165_OF_v2d20220302.txt Instrument calibration file used: Pandora165s1_CF_v6d20250529.txt Level 1 file used: Pandora165s1_BuckeyeAZ_20260219_L1_smca1c6d20250529p1-8.txt Full location name: Buckeye, Arizona Short location name: BuckeyeAZ Country of location: United States Location latitude [deg]: 33.3699 Location longitude [deg]: -112.6207 Location altitude [m]: 258 Local noon date: 20260219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Creating OoB file using updated lab measurements from May 2025 First and last pixel inside fitting window: 219 360 Nominal wavelengths inside fitting window [nm]: 305.0930 305.2340 305.3750 305.5159 305.6569 305.7979 305.9388 306.0797 306.2206 306.3616 306.5024 306.6433 306.7842 306.9251 307.0659 307.2068 307.3476 307.4884 307.6292 307.7700 307.9108 308.0516 308.1923 308.3331 308.4738 308.6145 308.7553 308.8960 309.0367 309.1773 309.3180 309.4587 309.5993 309.7400 309.8806 310.0212 310.1618 310.3024 310.4430 310.5836 310.7241 310.8647 311.0052 311.1457 311.2862 311.4267 311.5672 311.7077 311.8482 311.9886 312.1291 312.2695 312.4099 312.5504 312.6908 312.8312 312.9715 313.1119 313.2523 313.3926 313.5329 313.6733 313.8136 313.9539 314.0942 314.2344 314.3747 314.5150 314.6552 314.7954 314.9357 315.0759 315.2161 315.3562 315.4964 315.6366 315.7767 315.9169 316.0570 316.1971 316.3372 316.4773 316.6174 316.7575 316.8975 317.0376 317.1776 317.3177 317.4577 317.5977 317.7377 317.8776 318.0176 318.1576 318.2975 318.4375 318.5774 318.7173 318.8572 318.9971 319.1370 319.2768 319.4167 319.5565 319.6963 319.8362 319.9760 320.1158 320.2556 320.3953 320.5351 320.6748 320.8146 320.9543 321.0940 321.2337 321.3734 321.5131 321.6528 321.7924 321.9321 322.0717 322.2113 322.3509 322.4905 322.6301 322.7697 322.9093 323.0488 323.1884 323.3279 323.4674 323.6069 323.7464 323.8859 324.0254 324.1648 324.3043 324.4437 324.5832 324.7226 324.8620 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260219T205706.6Z 9546.872994 109 1 50.48 2 47.68 204.51 32.74 164.03 0.00 1 0.00 1 0 67 1.726e-02 1.428e-02 4.875e-04 2.136e-04 2.307437e-01 1.126443e-04 2.757425e-03 -6.000000e+00 1.029164e-02 225.39 -2.00 3.33 -2.00 316.50 0.00e+00 -5.038285e-05 1.321507e-05 1.161302e-04 -6.000000e+00 4.494268e-04 280.48 -2.00 20.00 -2.00 315.88 0.00e+00 1.483 0.000 302.00 328.00 3 1.1122e+00 2.9170e-04 1.8338e-02 -6.0000e+00 2.5432e-02 2.5247e-02 3.2498e-04 1.1326e-02 -6.0000e+00 2.7521e-02 -1.1815e-02 1.8950e-04 5.6332e-03 -6.0000e+00 1.6402e-02 4.1510e-03 8.9982e-05 1.6107e-03 -6.0000e+00 7.0423e-03 3.1086e-02 -4.3717e-04 6.6697e-06 2.2206e-05 -6.0000e+00 5.1597e-04 -1.4320e-02 0.0000e+00 12 8 8 10 0 0 6.87 23.17 0.22 -0.01432 -0.01761 1369 259 1 5 0 36.870 26.62 19.96 23.17 24.85 28.6 977.61 -3362 -3586 -5407 -4718 -482 580 2004 1072 -559 -2294 815 2608 916 972 -241 -1563 72 368 361 247 -400 1835 1618 717 348 -879 -1766 82 2206 3341 2062 2785 -181 -2646 1512 2809 2289 2148 0 -1981 -1833 -1114 -1768 -1312 -821 -1763 -1095 -869 255 1759 1203 732 1311 214 811 971 -29 310 1342 1948 2284 1155 321 -1881 -2181 674 1294 3464 2721 -531 -1001 -1489 -1160 -1008 -578 1222 2373 4112 2831 178 -552 -2121 -1526 -190 -1056 -1145 -1344 -1438 -1909 -1197 93 679 3105 3810 2163 1234 741 -1343 -2018 -997 -379 1529 3413 1287 -1542 -409 -878 -254 312 -495 -1467 -1449 -701 228 1844 2974 2131 1607 -186 -1489 -1291 -664 -876 248 638 661 3260 2220 336 -39 -681 146 857 715 -694 -1092 -550 -1238 -942 340 180 787 -582 -667 -1025 -827 -73 84 302 182 -106 -457 157 509 201 242 -68 -481 23 119 121 85 -140 627 565 265 124 -324 -642 30 753 1105 722 1040 -74 -1110 581 1061 949 950 0 -1233 -1236 -714 -1164 -864 -536 -1150 -755 -581 165 1133 817 531 914 157 608 742 -23 239 1009 1457 1764 966 290 -1811 -2066 577 1024 2651 2253 -505 -952 -1471 -1134 -1022 -541 1014 1776 3186 2144 154 -536 -2104 -1600 -208 -1241 -1436 -1649 -1805 -2385 -1532 109 719 3218 3862 2356 1374 915 -1707 -2686 -1287 -489 1799 3838 1539 -2026 -522 -1177 -353 454 -767 -2221 -2186 -1074 320 2362 3867 2806 2069 -260 -2220 -1957 -987 -1263 339 826 876 4059 2835 464 -54 -972 211 1262 1101 -1064 -1755 -903 -2076 -1572 547 280 1262 SS 20260219T210238.5Z 9546.876835 112 1 50.48 2 48.17 206.22 32.43 166.49 0.00 1 0.00 1 0 38 1.727e-02 1.427e-02 4.968e-04 2.155e-04 2.324482e-01 1.134750e-04 2.777770e-03 -6.000000e+00 1.030349e-02 225.39 -2.00 3.33 -2.00 316.53 0.00e+00 -5.280820e-05 1.341404e-05 1.164082e-04 -6.000000e+00 4.499406e-04 280.48 -2.00 20.00 -2.00 315.90 0.00e+00 1.497 0.000 302.00 328.00 3 1.1126e+00 2.9398e-04 1.8500e-02 -6.0000e+00 2.5461e-02 2.5474e-02 3.2769e-04 1.1419e-02 -6.0000e+00 2.7553e-02 -1.1656e-02 1.9116e-04 5.6772e-03 -6.0000e+00 1.6421e-02 4.2118e-03 9.0914e-05 1.6197e-03 -6.0000e+00 7.0506e-03 3.0557e-02 -4.2425e-04 6.7218e-06 2.2575e-05 -6.0000e+00 5.1655e-04 -1.4431e-02 0.0000e+00 12 8 8 10 0 0 2.05 23.17 0.20 -0.01443 -0.01762 1348 255 1 5 0 37.440 26.51 20.02 23.17 24.90 28.7 978.83 -3241 -3687 -5308 -4966 -809 600 1570 1324 -701 -2142 739 2431 1016 916 -191 -1713 244 212 549 211 -423 1837 1589 716 296 -824 -1855 -13 2223 3340 2286 2634 -166 -2731 1697 2793 2268 2208 -47 -1859 -1805 -1068 -1806 -1283 -837 -1793 -1032 -869 250 1786 1162 712 1307 225 771 974 -37 298 1340 1927 2263 1177 333 -1919 -2167 623 1349 3414 2773 -529 -991 -1472 -1169 -1049 -577 1232 2386 4076 2869 172 -537 -2108 -1503 -203 -983 -1156 -1318 -1392 -1902 -1174 93 657 3093 3889 2176 1229 769 -1358 -1988 -1007 -398 1530 3435 1228 -1509 -439 -894 -240 289 -477 -1456 -1462 -703 192 1858 2961 2139 1611 -178 -1499 -1297 -638 -894 261 600 677 3268 2258 339 -39 -677 117 905 691 -683 -1091 -529 -1236 -951 326 150 800 -552 -677 -991 -860 -122 85 234 221 -131 -421 141 470 220 225 -53 -522 76 68 181 72 -147 622 550 263 104 -301 -670 -5 752 1097 793 979 -67 -1139 647 1049 935 971 -25 -1150 -1211 -681 -1184 -840 -544 -1165 -708 -579 161 1147 786 515 909 165 577 742 -29 229 1005 1439 1745 982 301 -1845 -2050 533 1066 2613 2294 -503 -942 -1454 -1143 -1063 -540 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5.1700e-04 -1.4306e-02 0.0000e+00 12 8 8 10 0 0 3.84 23.17 0.21 -0.01431 -0.01760 1340 253 1 5 0 37.660 26.51 20.02 23.17 25.16 28.7 981.11 -3119 -3704 -5586 -4844 -828 738 1376 1297 -781 -2132 632 2659 1168 832 -179 -1657 105 262 447 219 -494 1839 1630 793 335 -822 -1891 113 2153 3270 2215 2640 -108 -2771 1664 2810 2242 2232 13 -1868 -1857 -1064 -1768 -1321 -851 -1797 -1023 -847 322 1724 1215 694 1269 244 793 1020 -72 270 1280 1988 2243 1123 353 -1884 -2135 570 1329 3483 2741 -512 -1025 -1471 -1151 -1032 -598 1233 2441 4070 2834 154 -495 -2092 -1502 -180 -1018 -1167 -1343 -1419 -1917 -1180 94 716 3099 3842 2168 1232 802 -1306 -1969 -1002 -373 1514 3404 1263 -1545 -397 -893 -254 300 -493 -1445 -1462 -673 202 1851 2943 2145 1603 -218 -1503 -1314 -636 -908 257 622 682 3251 2255 333 -79 -676 123 873 702 -664 -1092 -557 -1235 -947 339 156 833 -520 -666 -1025 -821 -122 103 202 213 -143 -411 118 504 248 201 -49 -497 32 83 146 73 -169 615 557 287 116 -296 -675 41 720 1063 761 972 -43 -1146 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