File name: Pandora165s1_BuckeyeAZ_20260222_L2Fit_fwvt1c6d20250529p1-8.txt
File generation date: 20260226T092854.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c6p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 165
Spectrometer number: 1
Processing software version used: BlickP v1.8.88
Instrument operation file used: Pandora165_OF_v2d20220302.txt
Instrument calibration file used: Pandora165s1_CF_v6d20250529.txt
Level 1 file used: Pandora165s1_BuckeyeAZ_20260222_L1_smca1c6d20250529p1-8.txt
Full location name: Buckeye, Arizona
Short location name: BuckeyeAZ
Country of location: United States
Location latitude [deg]: 33.3699
Location longitude [deg]: -112.6207
Location altitude [m]: 258
Local noon date: 20260222
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Creating OoB file using updated lab measurements from May 2025
First and last pixel inside fitting window: 1638 1787
Nominal wavelengths inside fitting window [nm]: 492.0495 492.1706 492.2917 492.4128 492.5338 492.6549 492.7759 492.8969 493.0179 493.1389 493.2598 493.3808 493.5017 493.6226 493.7435 493.8644 493.9852 494.1061 494.2269 494.3477 494.4685 494.5893 494.7100 494.8308 494.9515 495.0722 495.1929 495.3136 495.4342 495.5549 495.6755 495.7961 495.9167 496.0372 496.1578 496.2783 496.3988 496.5193 496.6398 496.7603 496.8807 497.0012 497.1216 497.2420 497.3624 497.4827 497.6031 497.7234 497.8437 497.9640 498.0843 498.2046 498.3248 498.4450 498.5652 498.6854 498.8056 498.9258 499.0459 499.1660 499.2861 499.4062 499.5263 499.6464 499.7664 499.8864 500.0064 500.1264 500.2464 500.3663 500.4863 500.6062 500.7261 500.8460 500.9658 501.0857 501.2055 501.3253 501.4451 501.5649 501.6847 501.8044 501.9241 502.0439 502.1635 502.2832 502.4029 502.5225 502.6422 502.7618 502.8813 503.0009 503.1205 503.2400 503.3595 503.4790 503.5985 503.7180 503.8374 503.9569 504.0763 504.1957 504.3151 504.4344 504.5538 504.6731 504.7924 504.9117 505.0310 505.1503 505.2695 505.3887 505.5079 505.6271 505.7463 505.8655 505.9846 506.1037 506.2228 506.3419 506.4610 506.5800 506.6991 506.8181 506.9371 507.0561 507.1750 507.2940 507.4129 507.5318 507.6507 507.7696 507.8884 508.0073 508.1261 508.2449 508.3637 508.4825 508.6012 508.7200 508.8387 508.9574 509.0761 509.1948 509.3134 509.4320 509.5506 509.6692 509.7878 509.9064
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20260222T150548.1Z 9549.629029 59 1 50.42 2 78.95 109.95 109.46 50.98 0.00 1 0.00 1 0 15 2.486e-03 2.475e-03 5.270e-04 5.260e-04 2.593762e+03 3.005090e+01 1.662474e+02 -6.000000e+00 1.311506e+02 280.60 -2.00 20.00 -2.00 505.28 0.00e+00 7.416278e-04 1.415240e-05 4.557075e-05 -6.000000e+00 6.828386e-05 280.60 -2.00 20.00 -2.00 500.54 0.00e+00 5.104573e-01 1.011685e-02 2.455181e-02 -6.000000e+00 4.842207e-02 225.55 -2.00 3.33 -2.00 502.12 0.00e+00 5.034 0.002 489.00 513.00 1 6.0541e+00 7.7125e-04 7.3690e-03 -6.0000e+00 3.6986e-03 -1.1897e-02 2.0301e-04 6.4529e-04 -6.0000e+00 9.7850e-04 2.1767e-03 1.9272e-05 4.4741e-05 2.6802e-05 -6.0000e+00 2.1619e-04 -2.5949e-03 -1.4975e-04 10 0 0 10 0 0 98.91 23.46 0.99 -0.00259 -0.00246 34 6 1 4 0 1482.910 26.83 20.00 23.46 15.14 28.2 907.49 -13 -88 -118 -235 212 235 145 17 -98 81 92 -139 -186 -58 -127 -14 155 -39 -176 -2 162 -138 82 63 -48 247 295 -195 -251 326 180 112 391 -367 -122 49 116 -44 470 662 179 -132 -18 -134 -155 10 21 222 -164 -260 -237 -193 116 67 -246 -423 -324 -56 244 315 233 10 56 -62 -114 -19 163 26 -354 -97 95 71 448 -229 -453 -359 226 152 -223 -68 -239 -254 -76 0 -177 -36 -22 -2 68 -14 134 32 -350 -331 -89 -28 -92 -196 -440 -108 197 214 166 -566 -453 -135 -225 42 220 55 -84 29 43 41 350 435 412 66 162 41 19 297 544 -14 75 150 -59 90 384 -167 -9 316 376 295 456 183 -324 113 56 -119 54 164 25 134 -167 -612 -866 -669 -139 596 -12 -84 -111 -230 214 242 146 17 -100 81 95 -142 -188 -57 -125 -14 155 -40 -179 -2 167 -142 84 65 -50 257 306 -202 -254 330 178 110 393 -370 -128 51 121 -46 476 663 180 -134 -19 -139 -163 11 22 230 -168 -260 -229 -190 112 65 -236 -421 -331 -58 251 322 238 10 58 -65 -118 -20 162 26 -347 -93 90 67 430 -225 -452 -357 219 145 -211 -64 -225 -242 -73 0 -174 -36 -21 -2 67 -14 134 33 -349 -332 -89 -28 -91 -190 -416 -100 180 198 160 -572 -453 -135 -222 42 219 55 -82 29 44 41 358 446 427 68 168 42 19 292 530 -14 74 149 -59 89 379 -167 -9 306 357 289 444 173 -318 113 57 -122 56 169 26 135 -169 -620 -862 -673 -135 574
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SQ 20260222T151645.6Z 9549.636638 65 1 49.91 2 76.81 111.63 107.71 52.84 0.00 1 0.00 1 0 15 2.500e-03 2.490e-03 5.047e-04 5.037e-04 2.105090e+03 2.830741e+01 1.360638e+02 -6.000000e+00 1.318675e+02 280.60 -2.00 20.00 -2.00 505.27 0.00e+00 7.239555e-04 1.357628e-05 4.399559e-05 -6.000000e+00 6.865735e-05 280.60 -2.00 20.00 -2.00 500.53 0.00e+00 4.172197e-01 9.692779e-03 2.037191e-02 -6.000000e+00 4.868919e-02 225.56 -2.00 3.33 -2.00 502.11 0.00e+00 4.274 0.001 489.00 513.00 1 6.0824e+00 7.4048e-04 6.2633e-03 -6.0000e+00 3.7190e-03 -1.0315e-02 1.9492e-04 5.3557e-04 -6.0000e+00 9.8396e-04 2.3701e-03 2.6570e-04 4.2783e-05 2.2591e-05 -6.0000e+00 2.1737e-04 -4.6368e-04 -1.6736e-04 10 0 0 10 0 0 79.86 23.50 1.00 -0.00046 0.00138 38 7 1 4 0 1313.360 26.94 20.00 23.50 16.05 28.2 915.78 -65 -100 -245 -231 275 312 83 237 -108 158 131 -142 -61 -76 -159 -72 110 -76 -267 -54 130 -41 170 -56 8 238 220 -313 -242 398 128 37 464 -443 -119 12 29 87 448 718 121 -83 -43 -140 -164 49 102 173 -132 -307 -215 -284 63 130 -242 -314 -360 -119 192 383 263 -33 101 2 -35 -3 126 -84 -367 -74 172 159 367 -74 -367 -387 79 134 -186 -136 -183 -271 21 52 -176 -1 -71 -46 76 109 218 -23 -288 -314 -85 52 -61 -252 -400 -157 241 301 222 -553 -433 -61 -225 -53 246 171 -182 -7 81 78 257 323 296 11 147 69 -2 317 482 -128 -16 235 -139 215 368 -266 -45 248 329 338 508 -7 -352 47 83 -49 107 161 37 148 -36 -558 -871 -683 -47 593 -60 -93 -236 -232 270 313 86 246 -113 162 132 -142 -60 -77 -160 -72 107 -76 -276 -57 137 -43 178 -59 8 252 232 -330 -249 391 123 35 454 -455 -127 12 29 91 461 729 124 -85 -45 -142 -168 50 104 174 -137 -312 -211 -271 59 122 -235 -317 -374 -120 192 396 261 -33 102 2 -35 -3 128 -84 -363 -72 166 153 357 -73 -371 -390 78 129 -178 -129 -175 -262 21 51 -175 -1 -72 -47 77 110 212 -23 -291 -320 -86 51 -59 -248 -385 -148 223 283 216 -544 -439 -61 -225 -52 237 165 -181 -7 83 81 266 336 298 11 148 71 -2 315 475 -128 -16 236 -140 216 367 -267 -45 243 316 321 478 -7 -348 48 85 -49 107 161 38 150 -36 -568 -872 -664 -46 575
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