File name: Pandora165s1_BuckeyeAZ_20260509_L2Fit_fout2c11d20251203p1-8.txt File generation date: 20260511T185418.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 165 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora165_OF_v2d20220302.txt Instrument calibration file used: Pandora165s1_CF_v11d20251203.txt Level 1 file used: Pandora165s1_BuckeyeAZ_20260509_L1_smca1c11d20251203p1-8.txt Full location name: Buckeye, Arizona Short location name: BuckeyeAZ Country of location: United States Location latitude [deg]: 33.3699 Location longitude [deg]: -112.6207 Location altitude [m]: 258 Local noon date: 20260509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 219 361 Nominal wavelengths inside fitting window [nm]: 305.0471 305.1885 305.3298 305.4712 305.6125 305.7538 305.8951 306.0364 306.1777 306.3189 306.4602 306.6014 306.7426 306.8838 307.0250 307.1662 307.3073 307.4484 307.5896 307.7307 307.8718 308.0129 308.1539 308.2950 308.4360 308.5771 308.7181 308.8591 309.0001 309.1410 309.2820 309.4229 309.5639 309.7048 309.8457 309.9865 310.1274 310.2683 310.4091 310.5499 310.6908 310.8316 310.9723 311.1131 311.2539 311.3946 311.5354 311.6761 311.8168 311.9575 312.0981 312.2388 312.3794 312.5201 312.6607 312.8013 312.9419 313.0825 313.2230 313.3636 313.5041 313.6447 313.7852 313.9257 314.0661 314.2066 314.3471 314.4875 314.6279 314.7683 314.9087 315.0491 315.1895 315.3299 315.4702 315.6105 315.7509 315.8912 316.0315 316.1717 316.3120 316.4523 316.5925 316.7327 316.8729 317.0131 317.1533 317.2935 317.4336 317.5738 317.7139 317.8540 317.9941 318.1342 318.2743 318.4144 318.5544 318.6945 318.8345 318.9745 319.1145 319.2545 319.3945 319.5344 319.6744 319.8143 319.9542 320.0941 320.2340 320.3739 320.5138 320.6536 320.7934 320.9333 321.0731 321.2129 321.3527 321.4924 321.6322 321.7720 321.9117 322.0514 322.1911 322.3308 322.4705 322.6102 322.7498 322.8895 323.0291 323.1687 323.3083 323.4479 323.5875 323.7271 323.8666 324.0062 324.1457 324.2852 324.4247 324.5642 324.7037 324.8432 324.9826 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260509T132045.4Z 9625.556081 174 1 50.16 2 81.76 74.49 52.22 175.98 0.00 1 0.00 1 0 25 7.804e-01 2.233e-02 4.383e-01 1.180e-02 9.855531e-01 7.125555e-03 1.118181e-02 -6.000000e+00 4.737660e-01 230.69 -2.00 3.33 -2.00 322.23 0.00e+00 2.467201e-02 4.664063e-03 3.452619e-03 -6.000000e+00 2.339201e-02 286.25 -2.00 20.00 -2.00 321.75 0.00e+00 6.544 0.004 302.00 328.00 3 4.2077e-01 3.0082e-02 9.6496e-02 -6.0000e+00 1.1944e+00 9.7330e-01 4.1979e-02 9.7264e-02 -6.0000e+00 1.2993e+00 -1.0654e+00 3.9425e-02 2.6595e-02 -6.0000e+00 7.6127e-01 4.1399e-01 1.7674e-02 2.6512e-02 -6.0000e+00 3.1454e-01 1.7041e-04 -2.0270e-03 3.2051e-04 3.6797e-04 -6.0000e+00 2.4330e-02 2.1077e-04 0.0000e+00 12 9 8 11 8 0 13.40 23.12 0.21 0.00021 -0.01502 46 9 1 5 0 1090.400 26.51 19.96 23.12 28.46 28.1 983.94 -71361 -227708 -196865 900000 -284870 -120795 -249878 900000 900000 900000 -105422 900000 57209 -131165 900000 99879 257215 26053 160078 482384 -53771 -38044 119209 -44720 -17453 32166 -76458 71759 900000 -49409 107350 5924 134957 -10468 34996 900000 77424 72056 33676 9057 81760 53259 62451 92879 141766 18569 55377 27733 115483 88190 53733 27208 21307 27359 17577 41734 18825 18255 17144 15238 26919 15930 28753 20339 14014 23952 18112 23734 5809 5470 6345 7032 6168 -2039 3104 8741 4922 5626 10796 1139 4921 920 1144 -1161 -1918 444 -401 -324 306 -2321 -2397 1349 2598 -442 -3304 -1454 -1654 -2799 -3081 -1307 -616 5332 2834 -551 -5163 -2870 -4089 -1128 -7 -2173 -2074 -2510 -1600 -657 -165 1954 2371 1991 -129 360 1229 1550 -1346 960 248 2250 3770 2172 1075 600 -530 996 1475 1014 -817 -448 -62 -970 -1327 437 -191 354 -458 -820 -5368 -3775 900000 -10794 -1388 -5692 900000 900000 900000 -1211 900000 657 -2147 900000 1148 2955 299 1839 5542 -1046 -606 1370 -702 -206 370 -1498 824 900000 -967 1233 114 1551 -293 625 900000 929 1015 774 293 1472 1331 1513 1773 1782 762 1719 1190 2397 2578 2400 1727 1557 2015 1466 2810 1550 1467 1342 1204 2003 1470 2734 2390 1897 3035 2482 3265 1049 1113 1377 1547 1318 -434 565 1365 774 945 2033 286 1418 315 430 -474 -830 197 -186 -153 142 -1058 -1033 537 1026 -195 -1752 -909 -1229 -2426 -2930 -1231 -539 3928 1945 -385 -3927 -2260 -3471 -1020 -7 -2596 -2788 -3647 -2368 -954 -232 2658 3276 2886 -199 557 1819 2165 -1844 1246 315 2723 4523 2879 1667 1078 -1073 2154 3403 2512 -2178 -1233 -172 -2716 -3657 1126 -460 788 -1005 SS 20260509T133607.3Z 9625.566751 179 1 50.60 2 78.65 76.46 52.08 180.51 0.00 1 0.00 1 0 33 4.716e-01 1.311e-02 1.955e-01 3.216e-03 7.671016e-01 1.821384e-03 8.092723e-03 -6.000000e+00 2.818620e-01 230.69 -2.00 3.33 -2.00 321.46 0.00e+00 7.658794e-03 9.755119e-04 2.228597e-03 -6.000000e+00 1.251088e-02 286.25 -2.00 20.00 -2.00 320.88 0.00e+00 4.909 0.002 302.00 328.00 3 4.3158e-01 6.5809e-03 6.4978e-02 -6.0000e+00 7.0349e-01 2.5422e-01 9.3701e-03 4.8585e-02 -6.0000e+00 7.6209e-01 -1.9178e-01 9.4411e-03 2.0607e-02 -6.0000e+00 4.5418e-01 6.1907e-02 4.3692e-03 1.2453e-02 -6.0000e+00 1.8847e-01 1.1375e-03 -1.1846e-03 9.1559e-05 1.1476e-04 -6.0000e+00 1.4076e-02 -6.2320e-04 0.0000e+00 12 8 8 10 0 0 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-677 -76 -117 -575 -288 -768 291 -543 70 -52 -55 472 17 -391 -305 -166 109 -203 0 -86 321 -163 652 -81 305 537 827 493 426 766 26 527 -55 71 -20 425 796 481 762 289 153 1010 1166 1035 1360 -49 9 -69 -541 -231 -149 333 608 794 704 21 166 -1027 -642 -530 -651 -533 -1313 -997 -2031 -84 73 838 1869 1694 878 -36 877 -1138 -1553 -711 28 2171 3148 860 -2869 -826 -1632 -299 46 -1124 -2072 -2625 -579 420 3127 4328 3605 2355 -1002 -2363 -1670 -187 -1330 -554 -726 573 4539 3034 260 -436 -462 1122 2182 1413 -1601 -1939 -746 -3114 -3405 456 645 2274 2075 SS 20260509T134302.6Z 9625.571558 182 1 50.47 2 77.24 77.34 52.09 182.55 0.00 1 0.00 1 0 25 2.542e-01 1.252e-02 1.319e-01 2.141e-03 6.938720e-01 1.200303e-03 7.384176e-03 -6.000000e+00 1.519807e-01 230.69 -2.00 3.33 -2.00 321.14 0.00e+00 6.879453e-03 5.840263e-04 1.616514e-03 -6.000000e+00 6.807820e-03 286.25 -2.00 20.00 -2.00 320.53 0.00e+00 4.406 0.001 302.00 328.00 3 3.9006e-01 4.1248e-03 5.7537e-02 -6.0000e+00 3.7931e-01 1.9404e-01 5.6363e-03 4.1169e-02 -6.0000e+00 4.1091e-01 -1.1825e-01 5.5270e-03 1.8422e-02 -6.0000e+00 2.4500e-01 3.0789e-02 2.6159e-03 1.1322e-02 -6.0000e+00 1.0216e-01 2.0588e-03 -7.7502e-04 6.3090e-05 9.6987e-05 -6.0000e+00 7.5936e-03 -1.2883e-03 0.0000e+00 12 8 8 10 0 0 9.35 23.10 0.19 -0.00129 -0.00711 179 34 1 5 0 281.910 26.41 20.00 23.10 30.36 28.1 997.31 -107714 900000 -22985 -95074 -94505 -112204 -32045 -104020 -60046 -92941 -85702 -77857 -5435 -10221 -40193 15066 -28276 8446 -18378 -85 -365 -31970 -7710 -36363 97 -21701 -17115 -6314 5850 2900 1531 5920 -4122 -1485 2868 8661 -4127 -7389 -506 -6439 -2048 -4372 -3574 195 135 1399 2911 3374 3081 5603 2159 4854 1536 952 161 -1271 334 -1816 -174 1132 4515 1290 1542 -576 519 4577 2850 4959 2707 170 -827 -2109 -1031 -982 693 1826 2838 2960 1678 -422 -223 -1747 -2078 342 -1026 -1174 -1400 -1571 -1626 -1056 1236 559 2830 2907 1373 925 833 -906 -1645 -334 178 2225 3771 1213 -2311 -1197 -851 -262 51 -647 -1252 -1475 -576 422 1819 3287 2272 1588 -546 -1446 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