File name: Pandora114s1_BuenosAires_20170407_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003650.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170407_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170407T101647.0Z 6306.428322 376 1 32.00 2 89.74 81.33 134.19 249.33 0.00 1 0.00 1 0 29 9.500e-02 9.176e-02 8.401e-02 8.231e-02 1.080641e+04 5.721343e+03 7.080025e+02 -6.000000e+00 5.280053e+03 287.10 -2.00 20.00 -2.00 505.35 0.00e+00 -5.431274e-04 2.211265e-03 7.612732e-05 -6.000000e+00 2.661106e-03 287.10 -2.00 20.00 -2.00 500.40 0.00e+00 5.970496e-01 1.594779e+00 6.673589e-02 -6.000000e+00 1.850496e+00 226.71 -2.00 3.16 -2.00 501.99 0.00e+00 19.995 0.075 489.00 513.00 1 9.5648e+00 1.2144e-01 3.1129e-02 -6.0000e+00 1.4206e-01 8.7692e-02 3.1468e-02 2.3333e-03 -6.0000e+00 3.6899e-02 7.4592e-06 -3.5864e-03 7.5217e-03 6.6594e-05 -6.0000e+00 9.3425e-03 -8.7744e-02 8.0647e-04 12 8 8 10 0 0 12.88 22.21 3.31 -0.08774 -0.11262 8 2 1 4 0 4000.000 26.21 20.00 22.21 -10129 -11146 -15071 264 4036 -3472 -2279 1169 6456 19752 19018 -4219 4901 17388 4519 7352 -14204 25689 -14610 7091 3840 -1628 15876 -4525 -5518 -3459 -1905 14277 -13810 5472 13809 11589 -8115 8936 295 -3056 8044 -6929 3242 -8166 10085 -5846 -4531 -467 4703 6900 -1765 7617 -2089 8564 11759 -7481 9177 -7779 3367 12142 -8021 13017 -13480 -10341 -5350 2824 -8920 11289 -5773 -5091 8033 -2551 2915 -9494 -1937 -10829 18501 -3191 409 12136 -3465 5150 -5806 -205 9666 5546 -3350 -2984 16704 3797 17903 2298 -1808 -1025 1959 5576 6530 18161 633 3162 120 209 15072 -18629 8105 -17198 793 12217 1623 -1206 1463 14515 -6045 -10959 -13429 -19496 -3310 -14991 16857 2455 3218 7431 14452 18793 7846 1147 8025 -120 -4747 -777 -5641 1236 7736 2900 1671 11 12569 -12676 -11467 15351 -6293 12777 4093 18724 -2204 -4002 2032 8515 12946 -9048 -4884 -7349 -2441 -9107 -1385 8535 -798 -10565 -12012 -17457 271 4093 -3882 -2561 1280 6697 17757 16988 -4693 4914 15232 4480 7118 -16196 21615 -17603 6980 3924 -1760 14431 -5063 -6262 -3852 -2081 13132 -16491 5239 11884 10161 -8817 8460 314 -3419 8048 -7975 3330 -9312 9547 -6510 -5021 -503 4857 7014 -1956 7621 -2270 8199 10626 -7968 8095 -8075 3169 10776 -8974 12042 -16386 -12181 -5986 2916 -10411 10808 -6552 -5696 7777 -2703 2885 -10520 -1969 -11940 15225 -3295 414 11032 -3442 4931 -5709 -188 8526 4783 -3176 -2844 13224 3465 14354 2167 -1777 -998 1847 5090 5960 14927 622 2997 114 193 11629 -19633 6416 -17345 672 9487 1465 -1174 1431 12589 -6401 -12047 -15034 -23299 -3405 -17537 14450 2439 3180 7082 12972 16300 7596 1174 7527 -120 -4907 -772 -5916 1215 7138 2807 1635 11 10965 -13236 -11647 12540 -6379 10824 3859 15579 -2165 -4065 1968 7800 11428 -10005 -5192 -7987 -2502 -9811 -1354 7454 -765 SO 20170407T102051.0Z 6306.431146 380 1 31.99 2 88.91 80.75 134.93 248.48 0.00 1 0.00 1 0 15 4.177e-02 4.083e-02 4.328e-02 4.286e-02 -3.848626e+02 2.471633e+03 1.402191e+02 -6.000000e+00 2.320862e+03 287.10 -2.00 20.00 -2.00 505.28 0.00e+00 1.044791e-03 1.174407e-03 6.199643e-05 -6.000000e+00 1.169874e-03 287.10 -2.00 20.00 -2.00 500.27 0.00e+00 3.933893e+00 8.322150e-01 2.419528e-02 -6.000000e+00 8.141646e-01 226.71 -2.00 3.16 -2.00 501.89 0.00e+00 18.358 0.058 489.00 513.00 1 8.8779e+00 6.3915e-02 2.7651e-02 -6.0000e+00 6.2490e-02 3.4241e-02 1.6367e-02 1.5581e-03 -6.0000e+00 1.6254e-02 1.4720e-05 6.7896e-03 4.0978e-03 3.1478e-05 -6.0000e+00 4.1084e-03 2.1443e-02 7.0379e-05 12 8 8 10 0 0 11.07 22.22 5.66 0.02144 0.06854 8 2 1 4 0 4000.000 26.21 20.00 22.22 1628 9884 -1340 982 -5003 -419 -6192 3102 -335 -3263 -4108 -1910 -831 969 5992 2018 447 653 -2386 -2876 1176 3717 -2617 1473 -2413 1502 6107 -478 2478 -268 2690 1949 -658 -3931 -3659 748 1528 2673 1315 -1850 5406 -8625 3714 -2261 4956 -2169 -11 2543 -4852 6158 267 10813 -3995 5006 -363 488 -552 -900 5579 1854 -1857 -19 3227 -1407 -2761 -433 -4137 -6235 5708 -2255 2761 -4154 739 -554 2318 2806 3042 -245 -949 301 -6500 5668 -4573 3806 -3242 -998 3269 -5990 6491 -8996 -2387 1478 116 -5778 5932 -4111 9343 129 -5840 2942 39 -2583 -430 -5298 3536 -1782 -252 878 2670 10391 -11422 4725 -599 6981 1667 1921 7736 3710 5298 534 247 -921 706 -4131 -834 1997 484 11532 -3468 -441 5501 -6087 -6921 9217 -632 -5516 -5342 -2795 526 3714 3297 -1805 1896 2476 1695 2168 6538 -1547 -2330 -6005 -1221 -4717 2498 1568 9046 -1420 976 -5409 -441 -6989 3198 -354 -3510 -4395 -1974 -840 956 5622 1995 459 687 -2640 -3222 1268 3915 -2947 1601 -2737 1636 6312 -520 2547 -275 2652 1954 -696 -4448 -4223 830 1670 2853 1407 -2031 5526 -10219 3932 -2572 5289 -2491 -12 2735 -5517 6123 274 9722 -4107 4725 -370 509 -595 -985 5735 1850 -1921 -19 3194 -1459 -2886 -437 -4258 -6450 5171 -2184 2515 -4036 687 -528 2172 2623 2803 -229 -880 274 -6315 4896 -4406 3398 -3132 -952 3004 -6055 5794 -9377 -2338 1405 114 -6068 5576 -4253 8341 124 -5827 2626 35 -2367 -389 -5175 3268 -1778 -248 848 2496 8895 -12176 4342 -592 6507 1566 1818 6959 3493 4923 518 238 -886 660 -4022 -787 1846 457 9775 -3419 -422 4962 -6167 -7029 7858 -585 -5316 -5148 -2666 497 3469 3145 -1833 1869 2441 1696 2176 6301 -1610 -2407 -6293 -1195 -4744 2358 SO 20170407T102443.0Z 6306.433831 384 1 28.00 2 88.13 80.20 135.63 247.66 0.00 1 0.00 1 0 22 5.253e-03 5.190e-03 1.645e-03 1.641e-03 1.554957e+04 1.179226e+02 1.019439e+03 -6.000000e+00 2.918510e+02 287.10 -2.00 20.00 -2.00 505.38 0.00e+00 2.202897e-03 4.546124e-05 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