File name: Pandora114s1_BuenosAires_20170429_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T003619.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170429_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170429 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170429T103359.0Z 6328.440266 458 1 32.00 2 89.75 72.00 127.61 92.15 0.00 1 0.00 1 0 29 9.304e-02 8.899e-02 9.363e-02 9.129e-02 1.843165e+04 7.098569e+03 1.475076e+03 -6.000000e+00 5.141646e+03 285.77 -2.00 20.00 -2.00 505.34 0.00e+00 1.127423e-03 2.478196e-03 2.933882e-05 -6.000000e+00 2.597626e-03 285.77 -2.00 20.00 -2.00 500.12 0.00e+00 -4.708534e-01 1.826064e+00 3.129401e-02 -6.000000e+00 1.814969e+00 225.53 -2.00 3.16 -2.00 501.75 0.00e+00 20.058 0.076 489.00 513.00 1 9.6949e+00 1.3967e-01 3.0911e-02 -6.0000e+00 1.3921e-01 1.2950e-01 3.5485e-02 2.4170e-03 -6.0000e+00 3.6293e-02 6.7635e-06 6.9886e-03 8.0105e-03 1.2809e-04 -6.0000e+00 9.1543e-03 7.4521e-02 -3.6782e-04 12 8 8 10 0 0 54.88 21.50 6.56 0.07452 0.12300 8 2 1 4 0 4000.000 25.58 20.13 21.50 -8236 5477 1709 10931 -11819 3863 1485 6327 8559 -34 -13428 1803 -2405 6541 -4564 4304 -2512 9612 -924 14124 -3317 -6414 3105 -7762 -7401 -4426 27590 -3447 3048 -6136 -1206 8255 -7393 411 -26 1648 1523 4352 -9293 -14409 6308 8238 12452 10584 6790 -1234 3279 4977 -3981 6304 -6316 21944 -2273 -1265 7912 -1661 6775 -19531 17961 -1384 7758 7572 -5774 -3995 -2275 2151 21375 1380 4886 -7725 13719 -15992 -10278 -2376 -2181 -12996 -9399 2274 -10386 8308 -2224 11316 -3311 3690 19016 21755 2169 2276 9220 -7991 21958 5564 11710 -6005 -3474 7023 7736 13602 -4754 8843 -1225 -18001 93 -2531 4817 5261 -12696 -211 -5404 5253 -3056 13072 -16182 -5792 -9849 11712 484 -257 15652 -8769 5516 20175 24865 1690 1861 12111 -2040 12412 -3798 10470 -749 -14575 5182 -15604 -11724 -1363 2920 -2682 11054 -2376 -1438 -3820 1809 3273 1593 -3104 16356 7061 -8472 -3952 -1780 6299 2048 -8792 5251 1758 10550 -14655 4172 1661 6754 8862 -38 -16822 1914 -2629 6480 -5047 4401 -2810 9769 -992 14083 -3680 -7346 3241 -9076 -8654 -5016 22549 -3784 3055 -6552 -1209 7584 -8159 434 -28 1770 1626 4465 -10810 -17535 6247 8060 11811 10355 6967 -1377 3482 5137 -4418 6167 -6819 17411 -2264 -1252 7316 -1744 6710 -25517 16179 -1511 7729 7588 -6648 -4528 -2525 2258 18235 1416 4780 -8480 12031 -18794 -11466 -2480 -2303 -15350 -10598 2238 -10688 7484 -2215 9856 -3148 3302 15768 16668 2038 2138 8045 -8223 16702 5010 10020 -6180 -3458 6128 6447 10270 -4174 6627 -1001 -17316 76 -2208 4122 4708 -13988 -207 -5530 4789 -3025 11112 -18643 -6057 -10741 10283 476 -257 13568 -9809 5337 16587 19052 1598 1739 10227 -1997 10552 -3802 9076 -725 -16140 4666 -17017 -12131 -1265 2613 -2580 9459 -2365 -1439 -3974 1801 3050 1518 -3104 13430 6319 -8741 -3827 -1658 5372 1833 SO 20170429T103811.0Z 6328.443183 462 1 31.99 2 88.93 71.40 126.79 91.56 0.00 1 0.00 1 0 22 6.759e-02 6.490e-02 6.251e-02 6.142e-02 1.042503e+04 4.376061e+03 4.649041e+02 -6.000000e+00 3.735873e+03 285.77 -2.00 20.00 -2.00 505.28 0.00e+00 2.600352e-03 1.676027e-03 1.815489e-04 -6.000000e+00 1.886845e-03 285.77 -2.00 20.00 -2.00 500.22 0.00e+00 9.875351e-01 1.220020e+00 1.010013e-01 -6.000000e+00 1.316094e+00 225.53 -2.00 3.16 -2.00 501.83 0.00e+00 18.436 0.059 489.00 513.00 1 9.4027e+00 9.3113e-02 2.9131e-02 -6.0000e+00 1.0098e-01 8.6586e-02 2.3998e-02 2.4496e-03 -6.0000e+00 2.6259e-02 1.0231e-05 -6.0953e-03 5.6166e-03 6.3553e-05 -6.0000e+00 6.6461e-03 8.6604e-03 1.7105e-04 12 8 8 10 0 0 93.47 21.51 5.39 0.00866 -0.03362 8 2 1 4 0 4000.000 25.58 20.21 21.51 -8055 393 -2251 3077 -9061 272 11324 6309 -1639 -3139 -119 -803 -7874 2764 2514 6593 -4237 -720 892 -5093 3564 9265 -3673 8614 1751 -1986 6859 3249 2902 9516 -10407 -8150 -2879 3807 -336 -3667 5667 -2725 5572 -3348 -6145 2867 55 7127 -1777 -3767 650 9922 -3504 -2495 -80 -1288 4187 5469 9216 -10499 -1239 -2001 6563 -3807 -4998 6664 -2587 7982 -1080 3031 2856 -13677 10701 2870 -2592 366 -2573 5417 -9734 22125 -4115 -4079 2658 10660 913 -2468 12439 -7258 3482 8357 5508 -1612 -2439 3444 649 5293 -9154 308 -10874 -1825 6361 -298 784 1115 -6084 -3404 7830 9327 -11692 15697 4093 -5870 761 -1124 3776 -498 2055 -4040 1161 -1206 6881 4339 4911 8585 -11238 -171 -6939 9415 9412 -1081 -2347 1253 12057 -11710 -11164 991 -3464 9221 -8712 13809 -3275 9773 -9186 -3181 4578 3341 10403 2772 11910 -2555 -9357 291 -2349 10278 -13882 16789 -4070 -8451 387 -2352 3149 -10753 301 11395 6728 -1889 -3631 -131 -881 -8533 2663 2412 6086 -4421 -742 927 -5703 3676 9036 -4084 8505 1862 -2200 6937 3378 2970 8861 -11528 -8766 -2982 3804 -361 -4150 5845 -3030 5636 -3668 -6906 2958 59 7208 -1990 -4339 718 9916 -3952 -2734 -83 -1323 3983 5093 8359 -11925 -1323 -2200 6690 -4309 -5717 6793 -2908 8105 -1200 3212 2992 -15593 10050 2880 -2545 346 -2498 4892 -10365 17316 -4181 -4082 2440 8905 835 -2331 10156 -7264 3158 7295 4994 -1577 -2405 3188 615 4799 -9679 301 -11947 -1819 5720 -278 702 969 -5563 -2984 6128 7334 -11790 12581 3804 -6096 736 -1095 3481 -482 1964 -4165 1149 -1230 6499 4229 4805 8172 -13066 -177 -7520 8502 8393 -1069 -2227 1153 9991 -12316 -11663 916 -3337 7739 -8607 10758 -3015 7960 -9207 -3064 4150 3112 9137 2650 10459 -2606 -10239 289 -2371 8991 -15142 13258 -3949 SO 20170429T104212.0Z 6328.445972 466 1 32.00 2 88.15 70.83 126.01 90.99 0.00 1 0.00 1 0 15 1.877e-02 1.864e-02 1.618e-02 1.609e-02 1.145768e+04 1.139680e+03 7.487312e+02 -6.000000e+00 1.037443e+03 285.77 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