File name: Pandora114s1_BuenosAires_20170522_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T005422.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170522_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170522 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170522T105136.0Z 6351.452500 412 1 32.00 2 89.76 64.69 47.20 43.69 0.00 1 0.00 1 0 29 8.062e-02 7.627e-02 7.990e-02 7.841e-02 9.258911e+03 5.518080e+03 1.245457e+03 -6.000000e+00 4.429389e+03 284.32 -2.00 20.00 -2.00 505.32 0.00e+00 2.209505e-03 2.136401e-03 7.678044e-05 -6.000000e+00 2.242765e-03 284.32 -2.00 20.00 -2.00 500.24 0.00e+00 1.192761e+00 1.558699e+00 6.142453e-02 -6.000000e+00 1.572658e+00 224.57 -2.00 3.16 -2.00 501.84 0.00e+00 20.121 0.076 489.00 513.00 1 9.3935e+00 1.1856e-01 3.1084e-02 -6.0000e+00 1.2056e-01 9.3338e-02 3.1015e-02 1.6906e-03 -6.0000e+00 3.1462e-02 8.0300e-06 -8.1624e-03 7.1932e-03 1.3376e-04 -6.0000e+00 7.9311e-03 1.1979e-01 -6.8381e-04 12 9 8 11 8 0 -583.29 21.26 11.27 0.11979 0.06317 8 2 1 4 0 4000.000 25.39 20.16 21.26 -5469 670 4959 -3546 -740 -3391 9152 933 2466 3054 6225 -5302 2875 3819 4116 -14636 -9766 24721 -1702 3480 7167 -2966 -952 10410 10443 5231 2655 -9065 1798 -10268 -3638 228 -9113 6164 -6114 10667 -2594 3269 11843 -7317 3602 3354 -6672 -1331 -2355 -4975 10530 -3357 -1824 -765 -10849 -6788 11548 -7687 -602 -9817 19355 -16298 8225 -5841 -3728 15261 426 11341 2954 -3611 -627 -1727 7761 8634 4288 14888 -4264 239 11081 6367 -4798 1868 -8281 11955 -8878 -1724 -2480 15267 -5506 -2014 6779 2706 3333 5139 14114 -5694 7101 10534 15519 -5055 5615 3492 28243 -4822 14580 -5735 -8486 3789 -8395 -3053 -2378 6334 1592 5609 -11260 -10696 -9971 6461 -5348 -355 -1750 13789 526 -8762 14390 -1521 -7557 4631 -9120 4283 1265 -11012 -665 9526 -7110 -11588 -1360 1746 -6467 -8376 -6763 -2061 2966 10824 965 1081 7226 -3982 4497 11966 797 12871 4874 2518 -1396 5399 -5490 -5554 651 4765 -3835 -800 -3854 9345 1045 2721 3319 6459 -6084 2999 3640 3880 -16649 -10708 19634 -1806 3566 7124 -3267 -1030 10081 10167 5387 2802 -10683 1871 -11733 -3785 226 -9993 5970 -6923 10439 -2911 3434 11287 -8361 3672 3437 -7624 -1459 -2643 -5787 10521 -3836 -2028 -827 -12674 -7409 10237 -8153 -598 -10966 16661 -20543 8218 -6734 -4202 14232 462 11099 3148 -3833 -681 -1867 7516 8185 4197 12968 -4199 226 9528 5811 -4910 1768 -8513 9878 -8955 -1615 -2347 12174 -5449 -1944 6057 2535 3106 4690 11729 -5771 6378 9260 13120 -5245 5152 3187 19536 -4517 10996 -5207 -7868 3149 -8146 -2933 -2353 5841 1537 5146 -12116 -11458 -10729 5990 -5652 -360 -1807 12254 538 -9933 12996 -1600 -8313 4427 -9277 4033 1161 -11500 -628 8140 -7168 -12207 -1291 1594 -6315 -8218 -6482 -1892 2628 9053 907 1031 6567 -4087 4269 10604 793 11348 4627 2414 -1363 4833 -5435 SO 20170522T105547.0Z 6351.455405 416 1 32.00 2 88.99 64.09 46.63 42.52 0.00 1 0.00 1 0 15 6.021e-02 5.842e-02 4.937e-02 4.870e-02 8.327632e+03 3.346394e+03 5.464618e+02 -6.000000e+00 3.308490e+03 284.32 -2.00 20.00 -2.00 505.28 0.00e+00 2.317976e-03 1.329017e-03 1.737312e-04 -6.000000e+00 1.674645e-03 284.32 -2.00 20.00 -2.00 500.24 0.00e+00 2.395072e+00 9.599372e-01 6.218026e-02 -6.000000e+00 1.171394e+00 224.57 -2.00 3.16 -2.00 501.84 0.00e+00 18.606 0.060 489.00 513.00 1 9.0287e+00 7.3410e-02 2.8763e-02 -6.0000e+00 8.9845e-02 6.3490e-02 1.8826e-02 2.0572e-03 -6.0000e+00 2.3362e-02 1.3175e-05 -1.8859e-03 4.4695e-03 7.6103e-05 -6.0000e+00 5.9177e-03 4.8984e-02 -5.5570e-05 12 8 8 10 0 0 99.16 21.26 -0.37 0.04898 0.03590 8 2 1 4 0 4000.000 25.39 19.57 21.26 -4044 7296 -3806 9906 -1559 7149 -8096 8184 293 818 4300 -7677 7919 -5228 591 3514 843 -314 -8147 3340 4862 3768 2208 -2212 6611 -8056 -753 21222 -1503 -4709 -4725 4043 -10673 140 -9014 4523 14551 4944 -2103 -8455 4173 2639 174 -2815 5862 -1061 6327 6307 -4763 -1483 -9233 2260 10003 -4684 -3012 -5362 3422 -5778 2506 -4719 -647 10174 334 1485 -774 578 7917 992 -2821 -2861 2108 -293 2291 -4764 8809 2456 -8520 1663 -3006 7496 -3850 9082 750 -5448 -245 -5060 1557 -6046 2308 -2458 -7694 7314 -7642 18769 -6689 7597 -1916 -2264 4091 -5042 7790 -8377 1460 -5181 6883 2831 -4891 2759 1241 103 -1493 -3084 9550 -950 9497 -4404 -436 -7 13016 -1260 -7265 4313 -732 -4373 -3386 3896 -2938 11965 8572 213 -2216 -4540 2132 -3285 -2450 9334 -8230 -1480 227 -972 -717 10085 -5927 -4595 9523 -1518 6104 7319 4206 -8968 -3719 6909 -1081 -4137 6842 -4127 9661 -1632 7008 -9379 8101 313 857 4284 -8503 7409 -5524 587 3411 856 -331 -9490 3507 5044 3958 2361 -2486 6838 -9666 -836 18709 -1627 -5111 -5023 3938 -12297 150 -10872 4822 13986 5177 -2336 -9929 4316 2789 190 -3216 6212 -1212 6706 6624 -5503 -1624 -10637 2259 9073 -4905 -3154 -5922 3562 -6712 2696 -5111 -672 9502 346 1524 -811 591 7417 980 -2854 -2859 1981 -280 2132 -4805 7859 2352 -9050 1568 -2915 6464 -3699 7669 692 -5380 -232 -5073 1473 -6187 2169 -2413 -7943 6525 -8004 15288 -7065 6891 -1869 -2155 3552 -4678 6229 -7773 1233 -4793 5873 2619 -5006 2626 1188 99 -1448 -3065 8491 -953 8671 -4378 -445 -7 11806 -1249 -7630 3984 -699 -4262 -3242 3479 -2830 9979 7414 200 -2134 -4475 1958 -3145 -2291 7680 -8066 -1371 211 -933 -699 8949 -6242 -4814 8718 -1560 5828 6885 4040 -9646 -3718 6131 -1041 SO 20170522T105948.0Z 6351.458194 420 1 32.00 2 88.25 63.51 46.11 41.38 0.00 1 0.00 1 0 15 2.996e-02 2.943e-02 3.021e-02 2.999e-02 7.222759e+03 2.020927e+03 5.919606e+02 -6.000000e+00 1.646335e+03 284.32 -2.00 20.00 -2.00 505.31 0.00e+00 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