File name: Pandora114s1_BuenosAires_20170701_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011833.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170701_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170701T110730.0Z 6391.463542 484 1 31.99 2 89.77 61.40 141.90 158.93 0.00 1 0.00 1 0 45 1.012e-01 9.878e-02 1.020e-01 9.855e-02 3.416696e+03 6.537874e+03 3.841348e+02 -6.000000e+00 5.527935e+03 282.68 -2.00 20.00 -2.00 505.33 0.00e+00 -7.717312e-05 2.695648e-03 1.111645e-04 -6.000000e+00 2.805452e-03 282.68 -2.00 20.00 -2.00 499.87 0.00e+00 3.475451e+00 2.015641e+00 2.076415e-02 -6.000000e+00 1.979435e+00 224.63 -2.00 3.16 -2.00 501.57 0.00e+00 20.167 0.077 489.00 513.00 1 9.4858e+00 1.5402e-01 3.1052e-02 -6.0000e+00 1.5161e-01 9.5977e-02 3.9826e-02 1.7232e-03 -6.0000e+00 3.9642e-02 6.3589e-06 -7.5545e-03 9.1661e-03 4.7821e-05 -6.0000e+00 9.9610e-03 6.2624e-02 -4.1917e-04 12 8 8 10 0 0 92.25 21.10 9.07 0.06262 0.01022 8 2 1 4 0 4000.000 25.28 20.00 21.10 -7025 -6900 1299 -13719 -282 3954 3410 -5925 -530 -6358 -1399 9792 -5291 5300 -30 7075 1657 -2259 -4850 -8916 28794 12705 1097 6698 9597 6804 132 -32998 1969 6159 -2267 9100 1254 11712 5953 -7220 3982 -6338 -341 -2145 7992 6616 -6468 19420 5343 -3725 390 8828 6899 -7837 14541 -2160 8183 -5979 -8259 39 -10206 2271 -3657 19826 3368 11568 7781 -7505 8122 -9149 8278 -6417 1675 8265 8385 2376 4459 11191 1860 5774 -14694 5704 -6012 -2665 27547 -10276 10328 9455 -9258 14889 2209 14254 2484 7909 -8491 6456 20440 22359 675 12397 -1955 -8166 2176 12713 3575 869 3597 23400 -3872 -2687 5115 -3944 29564 -13505 -15892 5775 3952 3412 5510 -1165 -7667 -3008 -6558 -1866 1238 1057 -1063 -11568 9412 -13581 22504 -14196 -3413 -13337 5560 18455 9569 -15283 816 8239 8001 -10974 -2767 -9764 -4090 -14370 15338 -3770 -147 2335 11257 12878 -10351 12550 -8239 2375 13673 -7513 -7475 1335 -16945 -313 4311 3812 -7359 -625 -7897 -1632 10068 -6243 5559 -33 7225 1807 -2444 -5529 -10795 25829 12519 1215 7031 9827 7186 148 -51428 2131 6228 -2424 8556 1284 11088 6173 -8741 4334 -7592 -380 -2404 8029 6732 -7539 17634 5644 -4342 437 9040 7109 -9186 13298 -2267 7536 -6238 -8829 39 -11700 2355 -4075 17492 3492 11026 7717 -8700 8055 -10724 8050 -7108 1682 7664 7668 2280 4164 9802 1808 5467 -17128 5363 -6234 -2626 19870 -10113 8846 7707 -9167 11687 1987 11446 2249 6781 -8562 5613 15550 16875 640 10479 -1889 -8234 1931 9902 2979 729 2910 15682 -3507 -2498 4540 -3882 20706 -14351 -17079 4986 3507 3090 4956 -1132 -8008 -3015 -6850 -1870 1203 1022 -1033 -12292 8013 -14513 16848 -15428 -3338 -14414 4968 14485 8204 -16701 749 6914 6667 -11065 -2607 -10081 -4074 -15188 12965 -3664 -139 2163 9596 10831 -10941 10412 -8240 2092 10645 SO 20170701T111134.0Z 6391.466366 488 1 32.00 2 89.04 60.82 141.59 157.44 0.00 1 0.00 1 0 22 6.742e-02 6.589e-02 7.253e-02 7.095e-02 2.831828e+03 4.468661e+03 5.506603e+02 -6.000000e+00 3.681411e+03 282.68 -2.00 20.00 -2.00 505.25 0.00e+00 4.608254e-03 1.933481e-03 1.346340e-04 -6.000000e+00 1.868947e-03 282.68 -2.00 20.00 -2.00 499.92 0.00e+00 1.515056e+00 1.427290e+00 6.000926e-02 -6.000000e+00 1.319821e+00 224.63 -2.00 3.16 -2.00 501.57 0.00e+00 18.751 0.062 489.00 513.00 1 9.4322e+00 1.0940e-01 2.8770e-02 -6.0000e+00 1.0106e-01 1.2541e-01 2.8309e-02 1.6368e-03 -6.0000e+00 2.6468e-02 8.9512e-06 1.5455e-02 6.7061e-03 8.9950e-05 -6.0000e+00 6.6401e-03 4.5084e-02 -4.0499e-04 12 8 8 10 0 0 97.57 21.09 3.88 0.04508 0.15229 8 2 1 4 0 4000.000 25.28 19.53 21.09 4451 -8707 -584 1654 -13136 2789 -6453 725 6151 -4703 10407 3173 -3537 -3058 1019 310 4258 -6530 3439 2956 -5477 5277 -4615 2281 10818 6971 879 -3068 6590 -1323 2702 65 -6225 3492 -8700 9245 -915 -409 9496 -11885 1799 -223 271 -6542 4298 -2542 -1469 1441 -1238 -8605 2910 4331 -3324 -9091 13064 -3899 -733 1238 8496 5162 6558 3858 7386 9217 -693 4503 -10576 3980 10298 -460 6893 -5179 6929 -2204 -5502 -4233 4391 12506 -8970 -3030 -874 3255 3279 3373 17032 -877 4662 1297 -5773 -4734 8212 7619 7637 13519 3768 5251 7339 769 -6282 6246 -7167 -392 12256 -2685 17606 -1298 6696 10741 -941 555 -7696 -6189 5823 5672 -2906 -6214 1261 -6599 -16248 -5327 -1423 -12893 742 -2442 -5019 -4815 6179 6886 -3127 -4139 6230 11941 -5741 -13223 6229 2257 -6000 13400 -10014 -3609 7789 -6837 2728 8637 7633 9416 3383 379 -6544 -2081 -4196 -5374 12426 4356 -10035 -641 1824 -17162 3159 -8079 843 6692 -5608 10495 3389 -3988 -3403 1016 315 4244 -7417 3587 3111 -6272 5432 -5264 2443 10683 7142 950 -3386 6417 -1355 2630 66 -6898 3627 -10407 9259 -1005 -442 9202 -14217 1885 -240 295 -7735 4603 -2923 -1662 1563 -1355 -9894 2901 4156 -3406 -9947 11750 -4284 -799 1338 8548 5361 6719 4078 7568 9273 -764 4655 -12503 4004 9596 -471 6487 -5475 6522 -2155 -5620 -4268 4008 10329 -9046 -2858 -805 2886 2922 3021 13400 -831 4195 1206 -5746 -4650 7103 6690 6805 11517 3554 4839 6507 712 -6089 5213 -6698 -339 9429 -2462 13622 -1241 5938 9058 -880 507 -7661 -6160 5240 5202 -2943 -6564 1244 -7085 -19281 -5650 -1435 -14347 709 -2388 -5039 -4856 5613 6226 -2942 -3929 5327 9623 -5473 -13361 5097 1902 -5498 10892 -9873 -3396 6628 -6797 2477 7420 6651 8090 3086 354 -6425 -1907 -3845 -4947 9658 SO 20170701T111542.0Z 6391.469236 492 1 31.99 2 88.29 60.22 141.25 155.95 0.00 1 0.00 1 0 29 5.597e-02 5.591e-02 5.192e-02 5.103e-02 1.024969e+04 3.647525e+03 8.465821e+02 -6.000000e+00 3.056243e+03 282.68 -2.00 20.00 -2.00 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