File name: Pandora114s1_BuenosAires_20170725_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T011819.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170725_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170725T105832.0Z 6415.457315 472 1 32.00 2 89.76 65.84 108.30 87.35 0.00 1 0.00 1 0 29 1.551e-01 1.378e-01 1.526e-01 1.436e-01 1.496056e+04 1.109756e+04 9.033238e+02 -6.000000e+00 8.460125e+03 282.20 -2.00 20.00 -2.00 505.28 0.00e+00 3.448819e-03 3.918411e-03 1.172385e-04 -6.000000e+00 4.290201e-03 282.20 -2.00 20.00 -2.00 499.88 0.00e+00 -1.227589e+00 2.906018e+00 9.780133e-02 -6.000000e+00 3.013953e+00 225.51 -2.00 3.16 -2.00 501.55 0.00e+00 20.152 0.077 489.00 513.00 1 1.0143e+01 2.2213e-01 3.2100e-02 -6.0000e+00 2.3111e-01 1.9306e-01 5.6745e-02 2.8078e-03 -6.0000e+00 5.9843e-02 4.2925e-06 5.0693e-03 1.2895e-02 5.1455e-05 -6.0000e+00 1.5208e-02 -2.1045e-03 5.2418e-04 12 8 8 10 0 0 -265.78 21.36 15.49 -0.00210 0.03306 8 2 1 4 0 4000.000 25.47 19.63 21.36 -14453 16374 53149 -21744 1561 -2051 -16841 6907 -3936 -5668 23401 -12888 11968 22012 6166 4512 15642 -16242 -1496 -10127 5759 22577 -2594 -1263 2409 2070 24501 5346 -15390 -1223 5608 8983 3325 15143 -16407 -5752 3449 15582 5848 15390 24449 -16200 -11128 -11383 8586 -11188 12723 -9409 6597 5987 -14225 25704 -4499 -4251 9972 9056 15182 7432 -11034 22326 -2170 6199 35998 10302 -6115 -2510 -9918 16037 6715 12576 19188 -5756 -15021 -14523 5501 14220 15862 5658 -4386 8426 23927 14853 -10790 -5565 9888 16103 -12584 11941 -8517 30127 14912 -1204 -16050 -6505 2234 8314 657 162 11532 8213 -14190 36219 11176 -6023 9950 11369 -2807 -1349 -8630 11765 -17835 18993 23665 -7223 36 16942 16340 -5353 11313 -18172 6646 16704 -20607 -8464 16806 23046 -15444 15658 -2445 47 -12665 -18934 -10400 -20559 20319 17563 -11308 -3264 -13911 18501 20908 -4159 -691 53955 8554 5515 17238 -20752 7953 6831 37828 26725 -24824 -17438 14982 34736 -30827 1790 -2475 -23706 7639 -4789 -6895 20941 -16327 11673 19255 6324 4764 15099 -22047 -1775 -13136 6369 21112 -3129 -1511 2786 2234 22418 5418 -18631 -1251 5315 8346 3370 14069 -21248 -6694 3625 14331 5872 14010 20420 -20524 -13576 -14100 8783 -13964 12417 -11303 6624 5899 -16687 19780 -4644 -4428 9265 8754 14105 7532 -13462 19485 -2423 6399 27701 10248 -7115 -2779 -11634 14297 6490 11329 16026 -6158 -17762 -17309 5421 12811 13844 5362 -4527 7591 18413 12545 -11847 -5849 9001 13903 -14526 10757 -9352 22335 12875 -1231 -18074 -6696 2083 7568 584 140 8624 6214 -13233 20394 8260 -5511 8141 9502 -2742 -1293 -8807 9729 -19927 14872 17906 -7499 35 13862 13514 -5557 10053 -21743 6140 13668 -23931 -8564 13160 17032 -16848 12536 -2345 44 -13371 -21156 -10523 -22609 14659 12979 -11242 -3044 -14686 14324 16003 -4135 -669 30380 7601 5047 13952 -24283 6857 5830 23297 18340 -27133 SO 20170725T110236.0Z 6415.460139 476 1 31.99 2 88.99 65.26 107.50 86.82 0.00 1 0.00 1 0 8 1.118e-01 1.019e-01 9.302e-02 9.013e-02 -1.137100e+03 5.224998e+03 1.306903e+02 -6.000000e+00 6.095562e+03 282.20 -2.00 20.00 -2.00 505.27 0.00e+00 -1.381158e-03 2.440421e-03 1.170160e-04 -6.000000e+00 3.094701e-03 282.20 -2.00 20.00 -2.00 500.05 0.00e+00 1.767298e+00 1.793611e+00 1.591997e-02 -6.000000e+00 2.189458e+00 225.51 -2.00 3.16 -2.00 501.71 0.00e+00 18.655 0.061 489.00 513.00 1 9.7628e+00 1.3672e-01 2.8275e-02 -6.0000e+00 1.6764e-01 1.1161e-01 3.5844e-02 1.5455e-03 -6.0000e+00 4.3849e-02 6.9675e-06 9.9761e-04 8.6050e-03 4.6691e-05 -6.0000e+00 1.1005e-02 2.5023e-02 -1.9107e-04 12 9 8 11 8 0 97.70 21.37 9.68 0.02502 0.03194 8 2 1 4 0 4000.000 25.47 20.15 21.37 -7877 1639 -4218 -5098 -5821 14570 1818 -4397 4709 -11183 12472 -13442 8576 -8098 10120 7395 -2702 9785 -8703 12475 -5302 10635 -10050 -9312 10697 -12299 1219 23694 11924 8440 666 20079 -7579 2152 -9480 19338 12367 -5708 11203 1376 16444 -12055 17850 -4952 -7567 667 1561 5620 -17924 26427 3338 -10855 -9405 -8605 11004 -8584 8815 -10044 9622 -3160 -5601 23707 -5773 18802 -7232 -4371 18436 -8488 3106 683 -4593 4784 1581 13565 7676 10679 -2419 5735 -7432 47431 6137 2485 14566 -14394 -1153 -4182 10889 -1389 7407 -2568 -8380 10341 3365 5885 -3 10132 3913 -17640 31808 -9669 3238 12898 7975 2657 9018 -8645 -8982 29865 -9533 -815 2330 -11825 -3575 3175 7039 -11378 5317 1250 6628 -1834 2903 5545 -13258 27297 -18953 10375 2332 -3671 4294 9636 -9461 -14608 17577 -996 8914 -4776 -8404 8344 -5035 11029 7903 -2266 8371 -6693 3548 -6062 6453 -2366 -3244 -12806 3576 8408 683 -8450 1634 -4605 -5790 -6832 14250 2053 -5328 5200 -14325 12435 -17134 8658 -9555 9898 7466 -2865 10065 -10302 12122 -6183 10585 -12311 -11353 10710 -15501 1336 20513 11377 8102 674 16674 -8436 2243 -11446 17767 12163 -6656 10887 1459 14914 -14554 16085 -5658 -8958 730 1691 5792 -23012 21322 3303 -12018 -10026 -9021 9591 -9352 8307 -11654 9237 -3443 -6235 19687 -6459 16499 -8220 -4788 15852 -9398 3018 671 -4707 4424 1508 11584 7053 9622 -2479 5336 -7263 28213 5494 2168 12095 -15100 -1069 -4041 9138 -1326 6502 -2495 -8652 8907 3140 5427 -3 9063 3694 -20356 21953 -9877 2843 10112 6561 2347 7718 -9117 -9671 21766 -10158 -783 2149 -12601 -3553 2998 6491 -12753 5078 1250 6294 -1894 2837 5205 -14787 20045 -21976 8994 2201 -3689 3983 8459 -10029 -15334 14169 -956 7629 -4615 -8352 7049 -4948 9439 7112 -2155 7673 -6748 3245 -6143 5801 -2324 -3186 -13575 3141 6904 603 SO 20170725T110642.0Z 6415.462986 480 1 32.00 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