File name: Pandora114s1_BuenosAires_20170804_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T012329.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170804_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170804T105025.0Z 6425.451678 375 1 31.99 2 89.76 68.88 115.87 220.00 0.00 1 0.00 1 0 15 7.978e-02 8.030e-02 7.731e-02 7.571e-02 2.386280e+03 4.821072e+03 4.165542e+01 -6.000000e+00 4.350165e+03 282.11 -2.00 20.00 -2.00 505.32 0.00e+00 1.709994e-04 2.075670e-03 4.177033e-05 -6.000000e+00 2.207039e-03 282.11 -2.00 20.00 -2.00 500.09 0.00e+00 3.443784e+00 1.530285e+00 5.376892e-02 -6.000000e+00 1.557476e+00 225.96 -2.00 3.16 -2.00 501.76 0.00e+00 20.149 0.077 489.00 513.00 1 9.2202e+00 1.1742e-01 3.1188e-02 -6.0000e+00 1.1934e-01 7.4717e-02 3.0058e-02 1.8767e-03 -6.0000e+00 3.1051e-02 8.3561e-06 -9.3533e-03 7.1876e-03 1.7421e-05 -6.0000e+00 7.8436e-03 -6.3264e-02 6.4104e-04 12 8 8 10 0 0 86.78 20.88 9.42 -0.06326 -0.12814 8 2 1 4 0 4000.000 25.07 19.59 20.88 -6424 7718 -8554 -5222 -7045 -1464 3806 2063 -2815 -865 109 4569 -3942 -10942 8687 -948 -6716 2695 -5750 111 12903 588 -4989 -3399 15564 1352 5280 -26329 15376 3572 -131 1152 -12480 5507 5911 2889 -2526 11010 1653 2830 21278 -4993 17528 2041 -941 -616 -3963 12517 1083 2912 -13283 10678 4372 -8794 13941 -4013 403 14373 13347 126 -2440 3009 5215 11548 -8061 2011 -3449 -5119 6838 -6219 17541 -3367 -5733 14184 1435 9910 1237 4520 1565 12541 -9143 -1417 -6471 -8634 -5467 6667 -4526 982 11193 -1293 -4262 10271 3710 4965 2584 15271 -13689 -133 8438 -338 9902 7469 1793 -1672 4060 2536 -2639 -483 7673 8345 -2870 7409 9681 -9600 -832 -2512 1014 -2096 7035 -6804 -3942 -6716 -1959 -1536 -5685 2461 9740 -16493 11548 -949 7820 -14692 10356 -4663 -458 7254 -10136 -288 -2509 4643 -2849 -12396 -4918 12306 3231 13129 8786 -687 -14003 4459 -3701 3687 -3981 -6674 7078 -9523 -5813 -8216 -1653 4156 2319 -3327 -995 123 4844 -4493 -12343 8565 -961 -7310 2733 -6514 121 12449 643 -5776 -3885 14784 1485 5564 -37777 14302 3640 -135 1157 -14510 5504 6083 3130 -2899 10949 1783 2982 18529 -5657 15957 2191 -1052 -691 -4607 12262 1174 3040 -15904 9774 4153 -9398 11933 -4209 417 13227 12547 136 -2680 3126 5316 11084 -9412 2110 -3771 -5597 6530 -6677 14667 -3432 -5956 12141 1413 9071 1159 4046 1415 10005 -8990 -1289 -6213 -8530 -5274 5752 -4409 911 9397 -1230 -4171 8719 3390 4537 2445 12750 -15111 -126 7162 -305 7900 5993 1514 -1482 3503 2306 -2595 -469 6798 7238 -2756 6427 8308 -10153 -819 -2540 998 -2139 6592 -7353 -4132 -7164 -1963 -1511 -5775 2306 8538 -17784 10016 -933 7037 -15586 9078 -4438 -412 6325 -9823 -254 -2300 4054 -2736 -13312 -4959 10530 3047 11291 7940 -684 -15833 4127 -3635 3300 -3823 SO 20170804T105430.0Z 6425.454514 379 1 32.00 2 88.97 68.29 116.39 219.14 0.00 1 0.00 1 0 22 4.778e-02 4.685e-02 4.791e-02 4.734e-02 5.433947e+03 3.094117e+03 3.041613e+02 -6.000000e+00 2.603716e+03 282.11 -2.00 20.00 -2.00 505.26 0.00e+00 1.436075e-04 1.286373e-03 3.540846e-05 -6.000000e+00 1.321444e-03 282.11 -2.00 20.00 -2.00 500.19 0.00e+00 1.832372e+00 9.361145e-01 5.756590e-02 -6.000000e+00 9.336781e-01 225.96 -2.00 3.16 -2.00 501.81 0.00e+00 18.601 0.060 489.00 513.00 1 9.0726e+00 7.1691e-02 2.8433e-02 -6.0000e+00 7.1519e-02 8.2525e-02 1.8332e-02 1.9258e-03 -6.0000e+00 1.8649e-02 1.3616e-05 2.9351e-03 4.4179e-03 3.0139e-05 -6.0000e+00 4.6985e-03 6.7030e-02 -2.6243e-04 12 8 8 10 0 0 94.01 20.88 -1.75 0.06703 0.08739 8 2 1 4 0 4000.000 25.07 20.56 20.88 -2569 -4528 -3621 3657 847 1688 682 1684 4086 -5829 -115 -11021 46 -4146 4233 2938 -3115 4259 1365 2642 -7255 -5298 1227 -2776 7572 -4594 1105 18674 7757 -6933 1582 2602 -3616 -507 701 7027 2137 -4787 8370 -436 -839 2846 -1060 2610 3562 -2462 723 5336 -3471 -950 1905 -6749 -152 1067 12292 -3324 8710 -3617 -7281 1093 -1906 4106 -93 956 -260 1267 10465 -2155 342 -1732 2360 -3488 148 -231 -2439 6426 -2341 -1141 -7900 6981 -7196 -3649 -835 1567 1641 -32 5159 8760 -1804 5988 178 -3350 -9987 4024 -69 1287 3182 -3627 3753 -3735 3107 6625 -7390 -2720 2581 1282 1030 3029 -1105 10428 -3556 -967 1953 -3605 6463 -3913 5754 -581 710 3006 -7936 7225 -4666 7827 -2649 652 -6165 -1371 -3008 -1123 -964 -176 5290 6777 8140 -138 -2249 3604 -357 4106 -2569 10841 -1344 1569 -1912 -8357 -5825 -1434 -6074 -1367 1950 761 2881 -2615 -4833 -3961 3830 873 1760 728 1787 4210 -6546 -121 -12684 47 -4361 4086 2900 -3334 4349 1465 2828 -8597 -6163 1340 -3169 7825 -5358 1210 16928 7656 -7701 1586 2592 -3927 -553 774 7348 2334 -5539 8390 -473 -913 3003 -1175 2818 3846 -2834 803 5596 -3909 -1020 1933 -7266 -151 1043 10952 -3569 8515 -4062 -7983 1100 -1973 4013 -96 971 -266 1265 9379 -2156 329 -1682 2177 -3389 139 -220 -2412 5853 -2308 -1092 -7951 5993 -7097 -3482 -780 1441 1523 -31 4713 7749 -1774 5436 172 -3362 -10834 3840 -69 1254 2981 -3545 3320 -3477 2649 5399 -6988 -2525 2366 1234 1013 2917 -1096 9104 -3559 -950 1892 -3743 6130 -3899 5558 -567 688 2855 -8362 6449 -4611 6730 -2517 602 -6126 -1303 -2907 -1064 -911 -165 4664 5809 6777 -123 -2057 3148 -331 3721 -2532 9470 -1339 1530 -1942 -9103 -6202 -1456 -6384 -1344 1815 709 2634 SO 20170804T105831.0Z 6425.457303 383 1 31.99 2 88.20 67.72 116.88 218.29 0.00 1 0.00 1 0 22 3.455e-02 3.434e-02 3.197e-02 3.175e-02 4.618024e+03 2.007463e+03 2.501774e+02 -6.000000e+00 1.882609e+03 282.11 -2.00 20.00 -2.00 505.27 0.00e+00 9.406589e-04 8.636069e-04 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