File name: Pandora114s1_BuenosAires_20170814_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T013832.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170814_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170814T104018.0Z 6435.444653 319 1 32.00 2 89.73 72.45 50.76 331.85 0.00 1 0.00 1 0 29 1.041e-01 9.828e-02 8.985e-02 8.694e-02 6.702248e+03 6.070782e+03 3.250953e+02 -6.000000e+00 5.674784e+03 282.02 -2.00 20.00 -2.00 505.31 0.00e+00 2.067693e-03 2.369069e-03 2.333315e-05 -6.000000e+00 2.880516e-03 282.02 -2.00 20.00 -2.00 499.94 0.00e+00 3.810414e+00 1.752037e+00 3.094874e-02 -6.000000e+00 2.039569e+00 226.42 -2.00 3.16 -2.00 501.59 0.00e+00 20.113 0.076 489.00 513.00 1 9.3087e+00 1.3371e-01 3.0961e-02 -6.0000e+00 1.5618e-01 7.6836e-02 3.4054e-02 1.8626e-03 -6.0000e+00 4.0793e-02 7.1751e-06 9.6807e-03 8.1443e-03 3.0662e-05 -6.0000e+00 1.0243e-02 -3.2934e-03 7.5135e-05 12 8 8 10 0 0 91.70 21.16 10.27 -0.00329 0.06386 8 2 1 4 0 4000.000 25.28 19.56 21.16 5228 -10338 14958 -2482 -10880 -6510 6756 -1183 -4058 8073 -12389 730 1795 -3455 956 11001 15079 16362 1015 3860 2960 -9393 -1255 6667 -14452 -4353 5780 9795 11261 -8092 1839 2671 27582 6511 1268 13761 -1579 9496 2327 -893 -3326 13342 -22036 759 -6230 -9251 8264 -4417 6270 2198 -7007 -3813 -5293 -10710 -3721 13091 -10936 10127 9693 -2986 -21 19220 5980 -7912 2108 2973 721 18152 -1827 2490 4216 681 -7811 -4030 31062 12475 8107 -7089 12017 958 5505 -14742 14019 -5019 -12214 -472 -8751 -6594 7523 -2370 7112 -12932 13394 -14633 17765 6147 13948 22521 -4145 -15034 -6663 12461 10719 -7379 19976 -17554 8428 -19029 1351 -3675 17059 12845 5032 4661 -1181 6265 -6361 3029 2172 -7574 15888 -8838 15266 603 3318 4514 11300 8571 5741 13072 2794 -1217 -14360 7139 10134 -12366 -9879 -5072 -2881 -1991 -5088 8767 -13993 23434 -5512 17556 -9214 -5891 330 -10839 16201 -3280 22300 4964 -11831 13749 -2795 -13643 -7965 7320 -1390 -4866 8452 -15686 800 1923 -3870 1025 10781 14502 15936 1096 4079 3162 -11367 -1405 6931 -18639 -5070 6042 9683 10684 -9057 1839 2671 22095 6658 1398 13447 -1785 9495 2472 -974 -3722 12734 -30298 841 -7468 -11457 8545 -5119 6412 2285 -7762 -3986 -5533 -11865 -3933 12049 -13110 9954 9582 -3342 -23 17253 6150 -9350 2239 3092 754 15676 -1900 2447 4024 670 -8388 -4213 23119 11199 7507 -7491 10309 909 4973 -15311 11708 -4785 -12621 -437 -8856 -6533 6451 -2234 6099 -13638 10986 -16056 14099 5402 11069 15954 -3731 -14734 -5891 9026 7993 -6800 14577 -19261 7227 -21386 1223 -3465 13084 10399 4476 4220 -1145 5673 -6573 2872 2094 -8068 13286 -9320 12441 562 3004 4063 9570 7487 5168 10931 2590 -1173 -14758 6198 8420 -12778 -9998 -4971 -2824 -1972 -5285 8031 -15292 18847 -5610 14257 -9792 -6024 313 -11247 12589 -3075 16321 SO 20170814T104422.0Z 6435.447477 323 1 32.00 2 88.93 71.87 51.16 330.71 0.00 1 0.00 1 0 22 4.325e-02 4.303e-02 4.281e-02 4.250e-02 5.526802e+03 2.725547e+03 2.503388e+02 -6.000000e+00 2.356442e+03 282.02 -2.00 20.00 -2.00 505.30 0.00e+00 4.688849e-03 1.145955e-03 2.713632e-04 -6.000000e+00 1.195706e-03 282.02 -2.00 20.00 -2.00 500.42 0.00e+00 1.471612e+00 8.247656e-01 9.415419e-02 -6.000000e+00 8.452294e-01 226.42 -2.00 3.16 -2.00 502.01 0.00e+00 18.507 0.059 489.00 513.00 1 8.9390e+00 6.2974e-02 2.9537e-02 -6.0000e+00 6.4744e-02 6.8200e-02 1.6104e-02 2.2136e-03 -6.0000e+00 1.6874e-02 1.5186e-05 1.2489e-02 3.9792e-03 9.3580e-05 -6.0000e+00 4.2516e-03 7.3943e-02 -2.6962e-04 12 8 8 10 0 0 94.95 21.15 3.58 0.07394 0.16057 8 2 1 4 0 4000.000 25.28 20.10 21.15 1314 5654 -5487 426 -3072 3308 5326 322 6199 -8530 5384 2570 -3050 3480 -4426 3245 -8209 3294 -5448 -1276 -1182 -693 -401 -1502 6893 -8220 1439 -6744 8943 389 -2027 3617 -4817 6610 957 -1918 762 -4167 12016 -838 4413 1098 5767 6635 275 2729 -4117 505 -3883 2518 3734 -1920 528 -9499 -1441 -724 7795 1823 -350 5792 -9719 5536 -4538 785 1546 5689 3818 -3351 1705 -3955 -145 -2159 1864 5937 -956 -986 -3785 -4558 -2936 610 866 6736 3850 -3384 1245 -2033 5662 1397 1044 1913 -4091 -92 -3689 -1009 3071 325 -7530 -3886 -1217 -2913 6917 491 10143 -1707 -1080 2566 2430 192 -3606 168 -2986 -4845 7326 -5306 2794 4096 6657 6408 4884 -2986 -4369 9884 -2645 -3672 907 3765 1497 -3463 -885 -1441 2634 -1193 -3251 4188 -2697 -2724 -5855 2800 -5041 85 705 3696 -1784 -1517 1863 -219 -129 2820 4490 9688 -2743 -383 -6667 1274 5434 -5684 428 -3259 3344 5310 336 6025 -9452 5113 2477 -3074 3267 -4511 3109 -9028 3302 -6036 -1361 -1260 -737 -428 -1631 6911 -9565 1507 -7511 8270 383 -2032 3486 -5217 6590 1026 -2115 810 -4606 11212 -888 4473 1164 5925 6855 306 2964 -4756 549 -4335 2574 3671 -1957 522 -10526 -1516 -780 7880 1851 -363 5655 -11108 5463 -4974 816 1582 5510 3707 -3447 1647 -3995 -140 -2119 1772 5487 -956 -983 -3823 -4557 -2851 569 805 5928 3508 -3339 1183 -2011 5204 1339 1000 1813 -4132 -90 -3813 -1027 2998 321 -7881 -3824 -1138 -2708 5727 432 8239 -1613 -1052 2465 2348 188 -3624 162 -2993 -5033 6866 -5396 2650 3864 6166 5999 4668 -3080 -4518 8719 -2605 -3626 858 3488 1427 -3479 -867 -1420 2491 -1170 -3218 3787 -2577 -2589 -5782 2580 -5127 84 698 3586 -1840 -1569 1872 -226 -133 2785 4279 8570 -2702 -368 -6911 SO 20170814T104824.0Z 6435.450278 327 1 32.00 2 88.15 71.29 51.57 329.59 0.00 1 0.00 1 0 22 7.711e-03 7.607e-03 4.200e-03 4.186e-03 1.163593e+04 2.881316e+02 7.895533e+02 -6.000000e+00 4.202498e+02 282.02 -2.00 20.00 -2.00 505.41 0.00e+00 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