File name: Pandora114s1_BuenosAires_20170905_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T014039.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170905_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170905T101226.0Z 6457.425301 312 1 32.00 2 89.74 81.72 96.20 252.43 0.00 1 0.00 1 0 15 9.766e-02 9.294e-02 8.915e-02 8.654e-02 3.406516e+03 5.477593e+03 2.501828e+02 -6.000000e+00 5.328918e+03 282.36 -2.00 20.00 -2.00 505.17 0.00e+00 3.409244e-03 2.342763e-03 1.711419e-04 -6.000000e+00 2.703705e-03 282.36 -2.00 20.00 -2.00 499.91 0.00e+00 -6.857216e-01 1.768326e+00 2.769219e-02 -6.000000e+00 1.917646e+00 227.43 -2.00 3.16 -2.00 501.54 0.00e+00 20.107 0.076 489.00 513.00 1 9.6360e+00 1.3502e-01 3.1172e-02 -6.0000e+00 1.4679e-01 1.9058e-01 3.5740e-02 1.7521e-03 -6.0000e+00 3.8437e-02 7.1596e-06 -7.6329e-03 8.3064e-03 7.2887e-05 -6.0000e+00 9.6143e-03 7.5083e-02 -5.3056e-04 12 8 8 10 0 0 93.90 20.82 9.84 0.07508 0.02214 8 2 1 4 0 4000.000 24.96 20.52 20.82 -9712 -3509 1076 -4463 405 -4651 146 83 23546 3781 12834 949 -4828 -5720 198 11023 2356 907 -1052 -7390 1768 -7282 14643 2456 6136 -2855 -7820 -4172 -17421 18696 1765 22845 72 -746 -4783 -7848 15155 -6069 14432 3502 -2965 -6874 -9019 25059 6352 15402 -4590 -3985 -3632 -16609 10333 -1493 -188 -2283 6187 15975 6703 9317 -2799 4380 -1546 2610 5685 -10492 -4567 -9329 10467 7757 19046 -7045 -4604 6039 -7921 9410 3411 5260 2286 -9259 -2669 4863 14057 -12267 29060 -14424 4691 -264 -4325 7592 -7220 7624 -1234 12390 -15646 960 14666 -2813 8056 -4092 21211 -13904 16311 10758 -13614 7403 -13294 10665 3318 -611 12128 691 1197 -14245 -628 8547 4366 -1464 3641 10422 -662 12511 153 16273 -13373 -4752 7253 -8580 6021 -1427 4883 -8688 -6403 -1350 -20029 21554 11292 -837 -6678 6499 1340 -3756 10313 -8631 1961 1392 -2134 11286 -21370 14672 6172 6340 -1252 5760 4424 -10946 -3764 1135 -5138 457 -5636 172 98 22113 4284 13064 1069 -5675 -6689 202 10753 2358 939 -1136 -8651 1900 -8566 13829 2625 6351 -3245 -9331 -4766 -22364 16282 1767 18216 73 -776 -5356 -9276 14312 -7036 13466 3605 -3236 -7814 -10558 21115 6538 14632 -5348 -4597 -4128 -21133 9817 -1553 -188 -2298 5738 13732 6520 9062 -3118 4558 -1705 2760 5851 -12757 -5243 -11184 10181 7633 16480 -7809 -4920 5738 -8600 8620 3357 5146 2169 -9769 -2590 4306 11253 -12747 20029 -15448 4178 -249 -4288 6721 -7426 6750 -1191 10444 -17586 926 12519 -2878 7346 -4144 16306 -14816 12539 8556 -13641 6045 -13673 8934 3078 -596 10352 652 1110 -15407 -599 7567 4097 -1475 3513 9448 -674 11210 155 13890 -15102 -4837 6461 -8915 5427 -1392 4479 -8584 -6166 -1233 -21987 16456 9399 -726 -6064 5478 1130 -3392 8748 -8441 1741 1250 -1991 9236 -24313 11641 5297 5346 -1112 4656 3576 SO 20170905T101630.0Z 6457.428125 316 1 32.00 2 88.91 81.15 96.98 251.85 0.00 1 0.00 1 0 15 3.917e-02 3.914e-02 3.396e-02 3.376e-02 4.922700e+03 2.132227e+03 3.916047e+02 -6.000000e+00 2.137335e+03 282.36 -2.00 20.00 -2.00 505.34 0.00e+00 4.174235e-03 9.223461e-04 2.293377e-04 -6.000000e+00 1.083941e-03 282.36 -2.00 20.00 -2.00 500.54 0.00e+00 2.582752e+00 6.558978e-01 4.376381e-02 -6.000000e+00 7.669103e-01 227.43 -2.00 3.16 -2.00 502.12 0.00e+00 18.436 0.059 489.00 513.00 1 8.6474e+00 5.0337e-02 2.8524e-02 -6.0000e+00 5.8739e-02 2.9476e-02 1.2747e-02 1.7324e-03 -6.0000e+00 1.5322e-02 1.9103e-05 6.9620e-03 3.1940e-03 8.8119e-05 -6.0000e+00 3.8525e-03 4.6689e-02 -1.4169e-04 12 8 8 10 0 0 77.56 20.83 4.40 0.04669 0.09498 8 2 1 4 0 4000.000 24.96 19.58 20.83 2616 -6803 -2876 -161 -420 7579 1946 6722 -3684 -521 1965 -273 -3863 -192 3729 3200 -1403 443 -6253 2306 -1922 -61 -23 1950 2561 3052 4856 -3754 3858 -3311 2494 -2197 -677 -2055 -3521 2706 -3810 8555 -151 1388 3505 -9330 886 2343 6389 -663 585 903 -7755 1976 -2361 3700 -2022 -2749 -964 -1560 -3200 -3369 4597 3280 -698 5044 -1292 7633 574 -377 -3130 -3278 560 -836 2354 -3286 3827 16 8707 -4455 -225 6515 -9145 6451 -2740 1693 3841 -577 -4585 -2905 -1953 -5350 2808 -2615 1567 6149 -1003 -1003 1529 4225 -1469 7305 -1454 -2697 -8142 -2981 -3633 4614 3500 2301 -1394 5305 -8654 3935 -5241 6155 2457 2160 879 -1338 1589 829 2354 1715 -2505 -4140 -2788 3616 -7835 5372 -382 4310 324 2362 3450 -1511 3445 -983 -637 -1674 2485 -2751 -3717 7620 -6439 3576 2871 -103 -1334 -6979 5583 -380 5603 -1923 5531 -816 -4138 2274 -6708 -2824 -158 -425 7207 1979 6525 -3933 -531 1925 -270 -3911 -186 3472 3029 -1421 451 -6939 2366 -2061 -64 -24 2040 2678 3178 4939 -4099 3805 -3412 2393 -2230 -696 -2217 -3946 2865 -4279 8399 -160 1445 3588 -10971 954 2523 6681 -701 609 926 -8534 2058 -2501 3600 -2056 -2656 -938 -1574 -3368 -3603 4554 3290 -729 4997 -1370 7420 596 -390 -3282 -3390 550 -823 2220 -3262 3554 15 7888 -4616 -221 5875 -9495 5684 -2641 1565 3495 -553 -4608 -2896 -1939 -5500 2654 -2602 1497 5659 -1007 -1020 1524 4064 -1468 6527 -1383 -2538 -7932 -2731 -3381 4065 3235 2218 -1327 4992 -8709 3679 -5070 5728 2277 2044 854 -1341 1559 827 2328 1710 -2584 -4279 -2801 3372 -8190 4957 -377 4070 319 2280 3297 -1518 3273 -963 -612 -1613 2303 -2725 -3799 7090 -7007 3564 2907 -109 -1425 -7934 5608 -403 5519 -1999 5233 -817 -4318 SO 20170905T102029.9Z 6457.430902 320 1 19.84 2 88.10 80.58 97.74 251.28 0.00 1 0.00 1 0 22 5.487e-03 5.437e-03 1.193e-03 1.191e-03 8.098847e+03 7.713834e+01 5.556369e+02 -6.000000e+00 2.994814e+02 282.36 -2.00 20.00 -2.00 505.37 0.00e+00 5.877405e-03 3.257978e-05 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