File name: Pandora114s1_BuenosAires_20170912_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T013932.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170912_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170912 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170912T100245.0Z 6464.418576 294 1 32.01 2 89.72 84.92 54.35 340.75 0.00 1 0.00 1 0 29 1.142e-01 1.073e-01 1.188e-01 1.148e-01 8.626681e+03 8.344292e+03 7.412505e+02 -6.000000e+00 6.241268e+03 282.47 -2.00 20.00 -2.00 505.34 0.00e+00 5.504905e-03 3.162370e-03 2.758172e-04 -6.000000e+00 3.162103e-03 282.47 -2.00 20.00 -2.00 500.11 0.00e+00 3.609651e+00 2.343563e+00 5.067638e-02 -6.000000e+00 2.231240e+00 227.75 -2.00 3.16 -2.00 501.75 0.00e+00 20.074 0.076 489.00 513.00 1 9.5715e+00 1.7986e-01 3.1745e-02 -6.0000e+00 1.7100e-01 6.4965e-02 4.5019e-02 2.0547e-03 -6.0000e+00 4.4406e-02 5.3346e-06 5.9761e-03 1.0648e-02 1.0247e-04 -6.0000e+00 1.1221e-02 -1.3229e-01 1.1805e-03 12 8 8 10 0 0 33.45 20.92 20.14 -0.13229 -0.09083 8 2 1 4 0 4000.000 25.07 19.96 20.92 -4627 1757 -6922 -8898 35014 6047 1150 4037 3767 6707 -3768 6860 -2793 -5084 -13490 12426 14511 -3174 -2210 -939 4187 -4101 7804 4822 17033 6949 11658 10042 -9196 7664 -13287 8176 -488 -11296 7986 10639 -16183 1392 -8994 -15535 12715 -7051 9800 15907 -6269 -1377 -6936 8867 657 4768 -3719 8943 -5923 -20356 -9619 10770 607 20878 -10397 -8694 -9908 25639 11396 -4645 22824 2132 8481 -9343 1684 6424 -2307 25418 12322 15939 -6750 -6109 5659 -8818 -2600 -5759 7936 -4604 313 -8055 -5906 7825 -4224 22870 -5765 21683 -22942 -7065 12979 -2359 527 -2558 16077 -4305 17984 -8669 -5088 3484 11127 15179 -9158 -6139 6473 -332 -2189 15395 13271 12239 9879 -7349 6105 89 -8834 3981 8679 786 -10140 -17936 33080 -2263 -13864 2986 15842 -20450 3029 -3423 14189 16602 12385 4457 -16489 330 12155 15542 11759 -13386 -729 -12527 17097 5496 -12911 13093 -3903 29002 -2296 1856 -571 8848 -1121 -4761 1752 -7791 -10515 27304 6416 1294 4413 4088 6956 -4271 6894 -3054 -5640 -16268 11688 13649 -3648 -2558 -1080 4578 -4554 7729 4957 15591 7039 11196 9644 -10419 7131 -15054 7545 -506 -13476 8029 10457 -20642 1472 -10460 -19233 11925 -8147 9706 15039 -7479 -1570 -8327 8981 710 4829 -3990 8253 -6266 -25049 -10898 10263 656 18641 -12716 -10437 -12044 21931 11287 -5402 20037 2272 8336 -10796 1718 6169 -2389 19835 11002 13873 -7445 -6692 5435 -9593 -2615 -5920 7086 -4663 303 -7989 -5775 6715 -4100 18018 -5637 16015 -26467 -7007 10682 -2290 496 -2447 12440 -3967 12903 -7927 -4402 2745 8219 11105 -8890 -5959 5601 -306 -2033 11912 10549 9986 8408 -7547 5540 86 -9445 3780 7936 779 -11128 -20943 22804 -2197 -15116 2772 13038 -24311 2855 -3443 11977 13664 10541 4045 -18210 306 10089 12682 10174 -15160 -738 -14451 14792 5374 -14360 11973 -3980 22441 -2250 1708 -529 7439 -1054 SO 20170912T100649.0Z 6464.421400 298 1 31.99 2 88.89 84.34 54.63 339.64 0.00 1 0.00 1 0 15 2.775e-02 2.745e-02 2.732e-02 2.716e-02 1.148288e+04 1.892801e+03 9.685555e+02 -6.000000e+00 1.515613e+03 282.47 -2.00 20.00 -2.00 505.41 0.00e+00 5.725730e-03 7.462380e-04 3.049806e-04 -6.000000e+00 7.684603e-04 282.47 -2.00 20.00 -2.00 500.74 0.00e+00 1.295768e+00 5.313300e-01 5.606002e-02 -6.000000e+00 5.442224e-01 227.75 -2.00 3.16 -2.00 502.30 0.00e+00 18.373 0.058 489.00 513.00 1 8.4962e+00 4.0814e-02 2.9029e-02 -6.0000e+00 4.1677e-02 2.3975e-02 1.0205e-02 2.0825e-03 -6.0000e+00 1.0882e-02 2.3885e-05 2.8078e-03 2.5347e-03 1.5457e-04 -6.0000e+00 2.7296e-03 -1.4017e-02 1.6479e-04 12 8 8 10 0 0 91.62 20.91 2.22 -0.01402 0.00546 8 2 1 4 0 4000.000 25.07 19.52 20.91 4310 -3244 1293 -2446 2174 3371 479 -1148 -3254 2368 4478 814 -825 54 5244 -1020 356 -2410 -2024 -1143 858 2084 -1509 4442 -3786 -392 -459 197 -4370 -695 910 -4042 2481 2332 1644 -2903 -1366 4692 -3542 1703 -5823 3015 3292 -2647 -54 2443 2726 -1984 3829 -3809 -5 -1814 -3658 -1824 -599 2575 3711 1195 -1682 643 83 848 101 -1472 3612 4731 -1329 -963 -1476 1521 -757 -5260 -29 798 2809 -2525 -2642 -3006 4610 1698 -5258 5128 -1682 1883 321 3019 -4740 -352 -22 -4084 6544 -978 4558 329 4669 1325 2656 2083 -2772 5378 -976 -603 -3758 -3622 2637 -3684 4943 -2457 3496 2483 631 -1934 -2007 185 -4450 -1249 -4068 -1950 3731 -86 777 1592 112 8 1478 3172 -6992 1893 -1854 950 -4310 1646 2321 422 -462 -3549 2734 1997 777 1160 -1466 -1652 66 737 -2520 626 1632 406 4790 -349 2367 -1345 -784 3581 -2989 1180 -2392 2084 3261 484 -1184 -3408 2312 4213 783 -797 51 4700 -980 343 -2447 -2091 -1182 873 2098 -1581 4416 -4120 -414 -484 204 -4639 -691 872 -4075 2395 2335 1707 -2995 -1384 4730 -3601 1744 -6046 2895 3200 -2775 -56 2492 2776 -2103 3779 -3981 -5 -1769 -3573 -1748 -578 2485 3649 1229 -1794 671 88 888 107 -1594 3715 4771 -1405 -999 -1518 1501 -756 -5453 -28 787 2754 -2630 -2739 -3076 4296 1610 -5319 4676 -1649 1792 313 2894 -4946 -352 -22 -4200 6033 -976 4361 334 4561 1325 2559 1958 -2657 4636 -879 -534 -3243 -3200 2280 -3537 4467 -2405 3203 2279 590 -1878 -1987 182 -4649 -1273 -4294 -2034 3722 -90 805 1618 114 8 1443 3056 -7523 1876 -1917 956 -4577 1647 2297 421 -457 -3591 2599 1936 777 1180 -1554 -1780 70 790 -2810 679 1756 441 4922 -370 2399 -1399 -814 SO 20170912T101045.0Z 6464.424132 302 1 31.99 2 88.08 83.78 54.92 338.58 0.00 1 0.00 1 0 22 6.083e-03 5.978e-03 1.046e-03 1.043e-03 1.327494e+04 7.276796e+01 8.852768e+02 -6.000000e+00 3.322306e+02 282.47 -2.00 20.00 -2.00 505.40 0.00e+00 9.960088e-03 2.858822e-05 5.457230e-04 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