File name: Pandora114s1_BuenosAires_20170913_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T013655.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20170913_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20170913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20170913T100121.0Z 6465.417604 324 1 31.99 2 89.72 85.38 54.07 357.62 0.00 1 0.00 1 0 22 1.133e-01 1.107e-01 9.081e-02 8.806e-02 2.378381e+03 5.542269e+03 2.402929e+02 -6.000000e+00 6.191060e+03 282.49 -2.00 20.00 -2.00 505.34 0.00e+00 4.634129e-03 2.423847e-03 1.664839e-04 -6.000000e+00 3.137724e-03 282.49 -2.00 20.00 -2.00 500.13 0.00e+00 3.118905e+00 1.790259e+00 2.175543e-02 -6.000000e+00 2.217822e+00 227.80 -2.00 3.16 -2.00 501.79 0.00e+00 20.069 0.076 489.00 513.00 1 9.3601e+00 1.3765e-01 3.1072e-02 -6.0000e+00 1.6991e-01 8.4172e-02 3.4964e-02 1.7121e-03 -6.0000e+00 4.4238e-02 7.0070e-06 -9.0516e-03 8.3912e-03 5.9453e-05 -6.0000e+00 1.1145e-02 -6.0020e-02 6.0413e-04 12 8 8 10 0 0 -82.90 21.43 12.10 -0.06002 -0.12281 8 2 1 4 0 4000.000 25.47 20.13 21.43 9578 -6489 -944 11801 -12647 9990 -21154 6251 -6141 14139 13795 -11349 -13766 -15490 2011 -3782 11720 5782 -5185 162 -3003 9258 -8833 21668 -3238 946 18291 -4448 18515 -8339 6047 -11363 5198 -4404 -12621 8211 -7753 19900 2680 2820 7599 -935 -2030 4154 14138 5464 9674 11480 -1199 696 -11346 13707 2098 3837 6324 -5480 20835 16101 633 3489 15439 13028 12819 1444 -13265 20014 -15211 -11255 6826 18639 -11595 -15753 -469 7053 26283 -11724 20970 14290 -15905 5714 -24006 6587 8109 13185 -623 -14516 13758 5860 -2927 8008 7099 17085 -1854 11544 -4406 1575 2534 16290 2183 -2582 14725 -17039 18901 -14518 15767 -4276 3799 3078 -6336 8694 8502 6418 -5445 8743 -1575 -9002 11239 -6241 -4066 -3654 2453 -1302 419 9439 -12214 17061 -10792 27471 19469 -8140 7669 -5557 -317 -1642 -976 -276 -10406 14369 -13266 2587 -13691 3657 15840 15228 -12000 -10532 2978 1477 266 10797 18394 2386 -24537 8504 -6881 -978 11132 -15673 10101 -29737 6745 -7497 13948 13438 -13995 -17145 -19387 2095 -4174 11200 5989 -5729 173 -3318 9057 -10369 18828 -3634 1023 16630 -5042 16408 -9405 5742 -12685 4965 -4765 -15325 8268 -9191 17750 2807 2921 7477 -1006 -2231 4351 13587 5786 9854 11429 -1339 749 -13450 12304 2065 3666 5932 -5928 17864 14824 689 3694 14482 12520 12393 1571 -16717 17967 -19170 -13407 6678 15981 -13278 -18584 -473 6616 20569 -12713 17497 12582 -17418 5294 -27845 5615 6825 10599 -578 -15584 11208 5185 -2827 6913 6166 13457 -1780 9840 -4468 1512 2392 13183 1991 -2410 11281 -17557 13460 -14568 11994 -4106 3444 2823 -6324 7364 7155 5540 -5376 7641 -1555 -9713 10004 -6666 -4277 -3844 2422 -1321 412 8351 -13310 13898 -11703 20452 15755 -8695 6992 -5446 -313 -1630 -948 -262 -10835 11705 -13607 2456 -14668 3343 13758 13391 -13100 -11390 2827 1425 258 9265 14290 2132 -28531 SO 20170913T100525.0Z 6465.420428 328 1 31.99 2 88.88 84.81 54.12 356.47 0.00 1 0.00 1 0 29 3.901e-02 3.839e-02 4.077e-02 4.048e-02 9.939472e+03 2.790056e+03 9.428987e+02 -6.000000e+00 2.130080e+03 282.49 -2.00 20.00 -2.00 505.38 0.00e+00 2.420187e-04 1.104089e-03 1.987626e-05 -6.000000e+00 1.079776e-03 282.49 -2.00 20.00 -2.00 500.52 0.00e+00 2.186788e+00 7.875722e-01 1.105524e-02 -6.000000e+00 7.637648e-01 227.80 -2.00 3.16 -2.00 502.11 0.00e+00 18.364 0.058 489.00 513.00 1 8.9265e+00 6.0231e-02 2.7677e-02 -6.0000e+00 5.8503e-02 2.4568e-02 1.5284e-02 1.7923e-03 -6.0000e+00 1.5252e-02 1.5761e-05 1.5777e-03 3.6874e-03 1.1068e-04 -6.0000e+00 3.8363e-03 4.7021e-02 -1.1525e-04 12 9 8 11 8 0 73.10 21.44 5.60 0.04702 0.05796 8 2 1 4 0 4000.000 25.58 19.68 21.44 -4750 -3641 4147 3750 -2937 797 -826 528 2740 784 4013 70 -530 -5841 -4734 -1701 -2493 -5051 1745 2388 -987 5820 3011 5846 1018 -1583 8593 -3234 -5735 1280 1095 -4563 -662 2039 109 5140 -2340 -2668 -3788 1327 5892 -432 1831 -3712 1151 -1462 -3328 -1752 5325 11807 -5280 -1941 -2182 -2018 945 2427 3409 1057 -1353 -1454 -1800 1165 -5223 4464 -716 4528 4615 3575 -55 367 9381 -4133 1857 4087 -8537 -1517 1344 -2690 -5216 424 -2625 3471 1912 -4767 4189 7064 -3456 -2807 -867 -1685 -3982 8214 2143 2765 1185 8703 4757 4701 -371 -1916 1647 -4860 25 -5356 3762 -1531 -665 3315 1245 1175 -384 1953 -128 157 -2822 -4910 -4695 -1617 4248 764 830 -1113 -3845 3157 -6892 1784 -660 4750 -7568 1314 3488 1264 1302 -4479 -4936 7123 1387 -3274 -1538 3734 -4005 10063 374 -676 6720 2041 3427 -2970 4909 -4664 -6101 -3183 2295 -4685 -3410 3719 3482 -2991 799 -855 542 2740 790 3864 69 -522 -6010 -4808 -1692 -2552 -5452 1800 2476 -1063 5866 3130 5938 1090 -1742 8501 -3559 -6327 1279 1077 -4768 -681 2114 118 5371 -2624 -2971 -4219 1394 5907 -464 1942 -4213 1258 -1647 -3812 -1955 5451 11087 -5726 -1982 -2193 -2023 937 2446 3499 1059 -1396 -1500 -1861 1173 -5634 4384 -738 4391 4406 3396 -54 352 8119 -4069 1727 3760 -9039 -1509 1290 -2641 -5161 393 -2493 3107 1750 -4705 3823 6342 -3480 -2819 -854 -1668 -4029 7394 2073 2688 1173 7878 4365 4186 -338 -1730 1409 -4399 22 -5074 3406 -1526 -675 3248 1235 1154 -382 1913 -130 151 -2825 -5043 -4832 -1627 4075 765 829 -1120 -3904 2940 -7046 1678 -641 4390 -7931 1260 3272 1212 1243 -4474 -4885 6202 1282 -3217 -1519 3573 -4216 9347 388 -715 6650 2129 3536 -3258 4927 -5061 -6593 -3306 2266 SO 20170913T100921.0Z 6465.423160 332 1 31.99 2 88.08 84.25 54.18 355.35 0.00 1 0.00 1 0 29 6.116e-03 6.015e-03 2.160e-03 2.153e-03 1.554617e+04 1.536846e+02 1.037125e+03 -6.000000e+00 3.340180e+02 282.49 -2.00 20.00 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