File name: Pandora114s1_BuenosAires_20171226_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T023110.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20171226_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20171226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20171226T091423.0Z 6569.384988 3 1 32.00 2 84.69 114.79 142.91 197.70 0.00 1 0.00 1 0 22 1.437e-01 1.323e-01 1.098e-01 1.047e-01 -1.130699e+03 6.155103e+03 1.870804e+02 -6.000000e+00 7.997299e+03 287.46 -2.00 20.00 -2.00 505.13 0.00e+00 1.688488e-03 2.874640e-03 1.299626e-05 -6.000000e+00 4.038594e-03 287.46 -2.00 20.00 -2.00 499.83 0.00e+00 2.175275e+00 2.104367e+00 2.811991e-02 -6.000000e+00 2.840248e+00 229.80 -2.00 3.16 -2.00 501.46 0.00e+00 9.367 0.008 489.00 513.00 1 1.1232e+01 1.6055e-01 1.3562e-02 -6.0000e+00 2.1743e-01 4.5671e-02 4.2539e-02 8.7964e-04 -6.0000e+00 5.7425e-02 5.5719e-06 8.0895e-03 1.0119e-02 2.8493e-05 -6.0000e+00 1.4150e-02 1.1579e-01 -1.3529e-03 12 8 8 10 0 0 92.96 23.09 4.16 0.11579 0.17190 8 2 1 4 0 4000.000 26.83 20.00 23.09 -20925 16903 3907 15227 3566 -8534 12206 -9955 13643 2536 -6387 741 -13383 28817 11111 33485 1220 4795 10618 -3822 25244 2202 18507 -8695 4870 -5152 -10483 26773 2801 24568 -11969 20712 2464 3327 7881 -3364 -7220 -18833 9166 198 -3447 3003 1182 -21800 -21658 30037 -12561 23125 7444 6878 5745 -12939 11179 -14404 8973 11391 -2218 1345 -15269 32344 -20729 -399 -1343 7411 -3487 -1703 18375 -1531 18231 2838 50384 6840 -2093 36607 960 1424 -14168 14131 -20160 3938 -1066 2414 21937 -6175 7862 14070 4335 7050 -22769 6554 -13715 19243 -9464 -12842 12043 -7806 -5129 -8754 272 2863 11612 -275 134 23640 -16250 854 -9292 18724 4779 -4324 -10588 -9899 22655 -379 19682 2941 3286 15129 -12696 33377 -3798 19939 -8999 -938 16231 1001 16879 -23990 28275 13589 15708 8170 -878 3813 -13712 -810 5783 -16220 -13194 414 3750 -5207 17941 -18115 8537 23303 -2246 7078 21165 8386 -181 -2471 -1517 -26390 14872 4039 14515 3922 -10825 12798 -13138 14205 2920 -7914 842 -17271 24087 10998 26517 1260 4889 10464 -4421 21940 2411 17225 -10651 5233 -6135 -13128 22902 2990 20512 -14007 17293 2495 3438 8036 -3914 -8745 -25390 9222 216 -3868 3165 1278 -29987 -30088 25078 -16074 20574 7642 6967 5740 -15142 10022 -16462 8167 10368 -2383 1426 -19331 25455 -27663 -435 -1480 7507 -3938 -1876 16347 -1634 15720 2816 30688 6367 -2120 25303 960 1432 -15635 12378 -22893 3462 -978 2137 16045 -6022 6709 11374 3894 6197 -27026 5803 -14871 15062 -9958 -14171 10508 -8364 -5331 -9324 260 2609 9462 -247 119 16684 -17516 800 -9836 15016 4354 -4245 -10936 -10161 17006 -364 15784 2830 3184 13104 -14580 24198 -3972 16246 -9642 -914 13225 951 13753 -27814 20680 11508 13000 7286 -806 3315 -13993 -759 5009 -16455 -13145 368 3283 -5062 13976 -20346 7372 17448 -2184 6283 16231 7191 -165 -2253 -1355 SO 20171226T092803.0Z 6569.394479 6 1 32.00 2 82.12 112.98 143.65 192.38 0.00 1 0.00 1 0 15 6.664e-02 6.384e-02 5.656e-02 5.548e-02 2.711669e+03 3.471564e+03 2.980474e+01 -6.000000e+00 3.709295e+03 287.46 -2.00 20.00 -2.00 505.14 0.00e+00 3.524878e-03 1.510288e-03 1.681944e-04 -6.000000e+00 1.868705e-03 287.46 -2.00 20.00 -2.00 499.98 0.00e+00 8.942969e-01 1.109567e+00 6.630281e-02 -6.000000e+00 1.309493e+00 229.80 -2.00 3.16 -2.00 501.58 0.00e+00 6.796 0.003 489.00 513.00 1 1.1014e+01 8.4836e-02 1.1629e-02 -6.0000e+00 1.0039e-01 4.4559e-02 2.2395e-02 1.1244e-03 -6.0000e+00 2.6283e-02 1.0835e-05 -3.3962e-03 5.2258e-03 6.3128e-05 -6.0000e+00 6.5665e-03 4.1364e-02 -3.7594e-04 12 8 8 10 0 0 98.64 23.17 1.64 0.04136 0.01781 8 2 1 4 0 4000.000 27.05 20.00 23.17 9614 3572 -11676 -48 -101 -3868 -6856 4992 2523 -866 1801 8305 4966 1843 4166 5131 19 -5995 15477 -1427 9316 7190 2069 1344 -5486 589 6811 -5741 -98 7248 -7105 7911 4973 193 -3849 -8854 -119 -4145 3498 -6758 -4705 4635 -8591 2940 5932 18578 -3607 -2867 3037 -6526 -4118 213 -9064 7116 -9193 -2764 -4073 -3275 6757 8741 1955 1940 4698 -6273 -1479 2569 -11 13828 -864 3417 2537 -6275 -8132 3130 -388 8457 5649 -2994 -2788 -3650 234 -8099 -6083 1291 -2407 -898 -2914 -305 -921 16566 -1690 8465 4376 -4054 -294 -5443 -3239 -147 -10095 9065 -2919 8229 3097 -12979 5693 2172 -2771 -4445 -3264 -6061 2461 -6613 -9295 11450 5573 8720 6650 9825 -1489 -125 -357 4386 -4700 -5305 7768 -5180 4454 -1068 12376 15575 1017 4105 -360 -482 -5196 -229 -7709 2286 18107 -779 5364 -12086 10751 16409 10168 -6959 -3691 6599 -12725 5347 -1321 -5953 5355 8962 3593 -14105 -53 -116 -4376 -8128 5302 2744 -964 1920 8159 4969 1878 4108 5004 20 -6737 14364 -1593 9389 7403 2242 1471 -6464 656 7112 -6743 -107 7147 -7856 7428 4850 203 -4354 -10753 -133 -4779 3690 -7815 -5305 4772 -10185 3145 6237 17376 -4224 -3316 3270 -7595 -4568 220 -10023 6604 -10098 -2915 -4489 -3669 6932 8809 2105 1958 4631 -6929 -1558 2585 -11 12884 -860 3217 2380 -6356 -8347 2883 -374 7559 5203 -2972 -2710 -3523 215 -8092 -5974 1185 -2307 -854 -2852 -293 -889 13400 -1637 7423 4030 -4120 -292 -5716 -3302 -143 -10602 7671 -2718 6713 2631 -13057 4876 1993 -2741 -4502 -3239 -6097 2250 -6630 -9698 9884 5190 7972 6261 9016 -1539 -128 -365 4234 -4601 -5142 6943 -4954 3890 -991 10055 12256 924 3611 -331 -439 -4886 -201 -7225 1938 13264 -702 4632 -12603 9010 13070 8652 -7056 -3636 5868 -13636 4703 -1212 -5599 4453 SO 20171226T094058.0Z 6569.403449 9 1 32.00 2 79.65 111.31 144.12 187.20 0.00 1 0.00 1 0 15 3.643e-02 3.603e-02 3.728e-02 3.679e-02 -6.681012e+00 2.138028e+03 9.082389e+01 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