File name: Pandora114s1_BuenosAires_20180106_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024532.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180106_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180106T085454.0Z 6580.371458 248 1 32.00 2 89.76 117.48 45.79 339.71 0.00 1 0.00 1 0 100 8.631e-01 4.549e-01 6.626e-01 4.313e-01 1.231623e+04 3.264856e+04 1.502203e+03 -6.000000e+00 4.872939e+04 288.02 -2.00 20.00 -2.00 505.58 0.00e+00 -1.641975e-03 1.311137e-02 3.368936e-04 -6.000000e+00 2.484652e-02 288.02 -2.00 20.00 -2.00 500.78 0.00e+00 7.736151e+00 8.673888e+00 6.979560e-02 -6.000000e+00 1.726733e+01 229.89 -2.00 3.16 -2.00 502.48 0.00e+00 19.979 0.075 489.00 513.00 1 1.0636e+01 6.6618e-01 3.2074e-02 -6.0000e+00 1.3221e+00 -1.2564e-01 1.6538e-01 2.5943e-03 -6.0000e+00 3.4902e-01 1.0941e-06 3.1073e-02 4.0088e-02 1.4171e-04 -6.0000e+00 8.8509e-02 -1.6544e-01 3.0776e-03 12 9 8 11 8 0 88.89 21.98 3.56 -0.16544 0.05009 8 2 1 4 0 4000.000 26.00 19.98 21.98 53839 43043 132593 -25191 50613 -288 4125 57098 20562 900000 42188 104497 106723 -36285 28915 -35320 131701 601 115920 47241 -30609 154257 -25166 43285 -2811 104443 40688 -16162 35751 1182 53771 -28971 99656 35875 45300 125547 -23214 900000 -21940 39465 -21685 100429 73002 -24281 -3563 -24346 121448 30380 900000 108272 29739 43627 11115 212926 41103 900000 -23156 110115 18882 37893 -4131 -41070 233051 52201 38998 30631 32992 7153 -635 110318 28052 74361 38385 900000 124341 4526 67893 -26768 168395 202930 -30085 900000 -54690 137361 1132 53536 136690 53829 68756 80127 129048 -42574 8228 -3398 17277 71836 31755 353220 -11539 197663 -19107 7388 151492 -23315 30983 9082 130303 -288 142197 30192 125773 65577 -19842 93103 -443 38972 -14084 -29792 71883 -7889 91385 -25276 127989 -19796 900000 -11048 -35845 148505 -30947 900000 39985 77157 -29896 46905 126404 -20652 61780 -30879 127382 40071 116645 39268 -10759 65631 23047 122208 281898 -14513 55962 -324 900000 900000 900000 34089 31147 55968 -37216 35098 -329 4477 36152 18599 900000 30527 44109 45048 -61264 26154 -61765 55592 744 48930 37033 -52604 65113 -40974 35236 -3559 44086 31896 -22416 30181 1462 40530 -47285 48075 32449 36877 52994 -34623 900000 -32722 34507 -32952 48448 46222 -37580 -4412 -36311 51264 24792 900000 45702 24269 31920 11573 89877 32386 900000 -34536 46480 18597 30924 -5115 -72812 98373 35255 29631 24997 25995 7246 -697 46566 23682 39758 29164 900000 52485 4585 36300 -36910 71081 85658 -44024 900000 -104651 57981 1242 34650 57698 34839 38697 40587 54472 -71883 8104 -3634 14585 34365 22340 149097 -12664 83435 -24734 7692 63946 -31984 26156 8865 55002 -311 60022 24692 53090 40598 -27220 41755 -514 30845 -18950 -46371 39824 -9574 40985 -36675 54025 -27679 900000 -14282 -59575 62685 -48985 900000 30591 40711 -46534 34648 53356 -31600 42376 -54582 53769 35943 49237 36258 -16462 46749 24929 51585 118991 -22207 42815 -445 900000 900000 900000 SO 20180106T085904.0Z 6580.374352 252 1 32.00 2 89.00 116.89 46.08 338.37 0.00 1 0.00 1 0 41 7.404e-01 3.788e-01 5.844e-01 3.905e-01 6.315018e+03 2.742322e+04 8.937850e+02 -6.000000e+00 4.132869e+04 288.02 -2.00 20.00 -2.00 505.11 0.00e+00 3.947857e-03 1.057356e-02 4.003361e-04 -6.000000e+00 2.077411e-02 288.02 -2.00 20.00 -2.00 499.93 0.00e+00 -5.394636e+00 8.198019e+00 8.443682e-02 -6.000000e+00 1.441401e+01 229.89 -2.00 3.16 -2.00 501.53 0.00e+00 18.527 0.060 489.00 513.00 1 1.1672e+01 6.2065e-01 2.9943e-02 -6.0000e+00 1.1074e+00 2.5902e-01 1.6955e-01 1.6512e-03 -6.0000e+00 2.8627e-01 1.3357e-06 -3.8002e-02 3.6792e-02 1.9566e-04 -6.0000e+00 7.2598e-02 -1.3161e-01 1.3525e-03 12 8 8 10 0 0 95.36 21.98 35.65 -0.13161 -0.39520 8 2 1 4 0 4000.000 26.00 20.02 21.98 12187 76628 58070 -2032 10905 -11146 118361 -16712 190483 -15552 66469 39169 109882 2832 1233 -17126 -23515 76199 -11883 115571 -7911 52389 -3090 55970 26276 -4965 52957 -14517 29241 4341 16829 11036 -14448 -5697 -14340 56216 19652 23305 453 -34332 56952 -45251 2136 -12167 -10923 312367 14026 61653 -7782 8749 -14108 2843 10043 79416 50351 58783 -10616 8712 6743 -559 -10227 61140 -26320 79141 5851 -42974 47809 -13347 32690 -4104 80152 9813 59907 120685 -33506 15073 66761 63261 30779 15088 -11863 67388 2541 99375 37209 -16947 65641 -12907 31440 7649 5226 132604 -26575 151654 112524 67060 -40701 95780 65111 -30653 64326 49670 90093 -19027 46886 35039 5093 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9978 44241 -2824 36167 23556 40131 -73792 67767 2432 36381 38133 -10230 42080 9205 77053 -18778 38246 30657 -51564 -32435 7152 62987 -40908 58556 9500 82178 32807 -48976 91591 -29826 60629 -303 6342 24861 31846 35524 35278 SO 20180106T090312.0Z 6580.377222 256 1 32.00 2 88.24 116.31 46.38 337.05 0.00 1 0.00 1 0 64 6.660e-01 3.631e-01 5.324e-01 3.787e-01 2.227085e+04 3.014863e+04 1.874711e+03 -6.000000e+00 3.713556e+04 288.02 -2.00 20.00 -2.00 505.16 0.00e+00 4.381891e-03 1.036542e-02 2.908995e-04 -6.000000e+00 1.897193e-02 288.02 -2.00 20.00 -2.00 500.42 0.00e+00 3.459754e+00 7.514749e+00 1.606755e-01 -6.000000e+00 1.345287e+01 229.89 -2.00 3.16 -2.00 501.87 0.00e+00 16.600 0.043 489.00 513.00 1 1.1226e+01 5.7514e-01 2.7702e-02 -6.0000e+00 1.0229e+00 -6.4343e-02 1.5191e-01 2.6052e-03 -6.0000e+00 2.8013e-01 1.4036e-06 2.1657e-02 3.3625e-02 2.3651e-04 -6.0000e+00 6.6214e-02 2.2944e-01 -3.7272e-03 12 8 8 10 0 0 -59.43 21.97 61.78 0.22944 0.37966 8 2 1 4 0 4000.000 26.00 19.98 21.97 900000 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