File name: Pandora114s1_BuenosAires_20180122_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024625.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180122_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180122T090956.0Z 6596.381898 360 1 32.00 2 89.76 113.91 139.51 152.28 0.00 1 0.00 1 0 53 8.867e-01 5.171e-01 6.162e-01 3.921e-01 -3.161386e+04 2.198096e+04 1.097085e+03 -6.000000e+00 4.995047e+04 288.59 -2.00 20.00 -2.00 505.12 0.00e+00 -2.807016e-02 1.167263e-02 1.027577e-03 -6.000000e+00 2.541405e-02 288.59 -2.00 20.00 -2.00 499.72 0.00e+00 2.465050e+01 8.739764e+00 1.529350e-01 -6.000000e+00 1.819585e+01 229.89 -2.00 3.16 -2.00 501.43 0.00e+00 19.960 0.074 489.00 513.00 1 9.6856e+00 6.8277e-01 3.9836e-02 -6.0000e+00 1.3861e+00 -3.9006e-01 1.7600e-01 3.5533e-03 -6.0000e+00 3.7875e-01 1.1584e-06 -6.2527e-02 2.7943e-02 9.3228e-04 -6.0000e+00 8.9723e-02 2.3767e-01 -2.0196e-03 12 8 8 10 0 0 -10.19 23.32 3.01 0.23767 -0.19604 8 2 1 4 0 4000.000 27.15 20.00 23.32 25886 -19710 60529 26816 -50188 -26791 86373 4301 93165 218818 39551 165909 4743 39131 112182 2743 159747 -8795 47319 42834 43143 70674 35934 71583 49407 75022 4497 -76045 86042 81549 271589 -30051 94596 135434 67748 95109 10697 99947 51433 125628 74906 17094 23191 20904 36308 44329 120323 9209 291619 900000 32653 900000 9576 69835 -26134 22975 46927 88404 -25713 9351 97008 12837 48616 28152 18186 78340 15926 46767 46000 74786 -38504 93237 -12129 17220 70941 -40191 900000 -2106 -23422 49426 -25674 16517 -45452 25482 -9748 9546 26921 -21764 8489 -41140 300542 107717 60117 900000 170317 33390 -36722 14642 17768 126341 29451 138938 -20496 58952 -8601 -12307 164916 -33809 133077 62332 103250 142046 2496 100987 38123 39737 -1008 900000 272919 35539 92651 104666 157256 -18431 900000 174142 -32668 900000 -16360 900000 73909 62046 32400 32614 89019 43042 127069 -22274 121524 69812 182942 77759 20117 22148 -61364 900000 -26254 900000 32087 46381 118815 103435 900000 21996 -25932 34841 21316 -86666 -37452 40248 4716 43412 83969 33607 63666 5980 35395 49199 3608 61302 -13018 40208 38745 40207 52304 39398 56901 50108 59634 6787 -256798 61319 56328 104220 -62271 55661 55684 50262 53529 14230 56252 48685 57850 57489 23177 29071 26205 38083 41960 52329 12015 111906 900000 32579 900000 11515 44664 -42120 21748 33615 40709 -36837 9569 42190 13136 34825 24487 17214 40083 15075 32304 31774 38264 -60087 38164 -13964 14538 34483 -58607 900000 -2102 -29361 30347 -33498 13944 -69768 18905 -10225 8304 19972 -26726 7818 -59201 115330 41335 35373 900000 65358 27334 -57248 13696 16194 48482 24722 53316 -29494 38175 -10727 -15645 63285 -54328 51067 40364 44574 54509 2813 41175 28344 28591 -1087 900000 104730 28128 42220 42675 60346 -25197 900000 66825 -49360 900000 -21580 900000 40770 38691 27198 27377 42701 33034 48762 -33656 46634 41859 70202 42894 20264 22841 -144059 900000 -46225 900000 34630 44496 56993 59538 900000 SO 20180122T091349.0Z 6596.384595 364 1 32.00 2 89.03 113.36 139.16 150.96 0.00 1 0.00 1 0 50 7.418e-01 3.817e-01 5.319e-01 3.664e-01 7.892905e+04 3.691635e+04 4.086129e+03 -6.000000e+00 4.146831e+04 288.59 -2.00 20.00 -2.00 505.21 0.00e+00 -5.446934e-03 1.021838e-02 3.455360e-04 -6.000000e+00 2.085105e-02 288.59 -2.00 20.00 -2.00 499.83 0.00e+00 -9.047903e+00 7.632046e+00 3.341139e-01 -6.000000e+00 1.453219e+01 229.89 -2.00 3.16 -2.00 501.53 0.00e+00 18.580 0.060 489.00 513.00 1 1.1907e+01 5.8735e-01 4.0469e-02 -6.0000e+00 1.1152e+00 2.1583e-01 1.4478e-01 8.6392e-03 -6.0000e+00 2.9086e-01 1.4359e-06 6.9084e-03 1.9008e-02 6.3229e-05 -6.0000e+00 7.2988e-02 3.3030e-02 -1.3200e-04 12 9 8 11 8 0 54.37 23.32 -20.26 0.03303 0.08095 8 2 1 4 0 4000.000 27.15 20.00 23.32 59449 -460 29108 -32854 28215 27359 40437 16077 6253 166005 51193 9352 -13240 173027 -19912 -7276 37612 -6212 2014 -46831 -17399 19000 32003 -13827 86033 76531 -20176 24001 4618 16180 -23191 5713 47762 26858 12052 22344 -23628 20678 5500 57892 11059 78357 1082 80052 13851 53521 -12686 62949 -17 101509 48828 -13768 -2786 60458 124155 20205 28422 1257 -38823 36188 94473 -32459 14164 54097 10098 764 27516 34610 137751 177586 18644 -19285 72371 -14969 39636 -54260 89463 6227 47800 18830 20080 43762 2571 126320 102312 12453 14232 -15636 -22254 -51751 -26556 17591 127460 4250 6314 13130 357782 22392 24619 -39922 -19957 43241 -26320 -7533 27926 11055 3753 393440 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40112 -4130 -10976 13465 -6983 -11392 30983 35670 -5395 17938 41333 36585 10660 -58383 -566 -28405 33189 -301 31253 -22145 15942 18415 97900 -65 -83581 24231 -35888 -3833 32235 35444 28192 36558 16852 -13517 35993 SO 20180122T091744.0Z 6596.387315 368 1 31.99 2 88.29 112.82 138.78 149.65 0.00 1 0.00 1 0 43 6.149e-01 3.385e-01 4.939e-01 3.443e-01 6.334382e+04 3.473151e+04 5.546298e+02 -6.000000e+00 3.459598e+04 288.59 -2.00 20.00 -2.00 505.38 0.00e+00 1.030941e-02 9.688540e-03 1.043931e-03 -6.000000e+00 1.735821e-02 288.59 -2.00 20.00 -2.00 500.34 0.00e+00 2.051453e+00 7.147517e+00 7.035820e-01 -6.000000e+00 1.207737e+01 229.89 -2.00 3.16 -2.00 501.94 0.00e+00 16.716 0.044 489.00 513.00 1 1.1074e+01 5.4353e-01 6.3217e-02 -6.0000e+00 9.2454e-01 -2.9220e-02 1.3270e-01 1.1559e-02 -6.0000e+00 2.4136e-01 1.5388e-06 -2.6346e-02 2.2904e-02 4.5347e-04 -6.0000e+00 6.1517e-02 -6.6904e-02 2.2646e-03 12 9 8 11 8 0 -40.99 23.32 23.30 -0.06690 -0.24965 8 2 1 4 0 4000.000 27.15 20.00 23.32 6348 -23901 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