File name: Pandora114s1_BuenosAires_20180208_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T024726.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v2d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180208_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180208 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180208T092700.0Z 6613.393750 283 1 32.00 2 89.77 108.08 24.47 37.93 0.00 1 0.00 1 0 128 8.713e-01 4.736e-01 6.683e-01 4.510e-01 -7.186828e+04 2.367136e+04 5.802648e+03 -6.000000e+00 5.300867e+04 288.83 -2.00 20.00 -2.00 504.94 0.00e+00 -2.763174e-02 1.409793e-02 9.280809e-04 -6.000000e+00 2.529595e-02 288.83 -2.00 20.00 -2.00 499.32 0.00e+00 2.302279e+01 9.382036e+00 8.182615e-01 -6.000000e+00 1.753989e+01 229.69 -2.00 3.16 -2.00 501.17 0.00e+00 19.963 0.074 489.00 513.00 1 1.0158e+01 7.3979e-01 6.7512e-02 -6.0000e+00 1.3468e+00 -1.8082e-01 1.7583e-01 9.0485e-03 -6.0000e+00 3.5379e-01 1.0193e-06 1.1689e-01 2.3531e-02 1.1290e-03 -6.0000e+00 8.8502e-02 -3.7033e-01 2.9612e-03 12 13 8 11 8 0 94.34 23.75 -28.32 -0.37033 0.44046 8 2 1 4 0 4000.000 27.45 20.00 23.75 188581 55497 697 92497 26292 230758 -27775 900000 -10876 25882 10995 127226 7817 9196 110912 58476 40977 -36727 -39328 40938 -15840 34533 45564 24732 14052 11209 83837 33372 -42216 -5098 -627 15651 46095 215763 -8382 50918 -11298 14874 35649 33599 364264 28111 28240 -24768 60310 9194 900000 137103 -8637 -42801 -20184 209118 68859 -44714 94746 102535 -11259 900000 118535 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900000 96411 -81169 22299 18886 -8364 59209 31259 38600 -64608 20250 -90740 -53427 -40410 -20839 13403 -31010 45526 36633 31130 38777 -9004 20291 33139 34163 -37659 98650 -22783 4526 18646 -6269 22760 -61722 900000 17497 -4114 20673 26516 900000 29347 -23814 -13979 154478 -38150 42305 -5903 14869 15791 73768 37984 49542 104133 10710 46320 46768 8967 8341 -2610 900000 31342 43777 47742 -2034 900000 -10945 -22214 -7893 14416 900000 30965 32612 -58203 32571 26564 17569 18222 33824 -37708 38384 51145 -76780 34478 -6208 11085 900000 -20445 67915 26670 900000 SO 20180208T093046.0Z 6613.396366 287 1 32.00 2 89.03 107.55 24.00 36.07 0.00 1 0.00 1 0 158 1.029e+00 6.691e-01 7.664e-01 5.663e-01 9.134513e+04 6.305445e+04 8.999651e+02 -6.000000e+00 6.401179e+04 288.83 -2.00 20.00 -2.00 505.66 0.00e+00 -6.161208e-03 1.720695e-02 1.168850e-03 -6.000000e+00 3.035161e-02 288.83 -2.00 20.00 -2.00 500.18 0.00e+00 -2.728667e+00 1.229282e+01 8.769599e-01 -6.000000e+00 2.160361e+01 229.69 -2.00 3.16 -2.00 501.95 0.00e+00 18.580 0.060 489.00 513.00 1 1.1886e+01 9.3456e-01 7.6645e-02 -6.0000e+00 1.6487e+00 9.0946e-02 2.2872e-01 1.4496e-02 -6.0000e+00 4.3460e-01 6.8538e-07 -1.3129e-02 2.8031e-02 1.1229e-03 -6.0000e+00 1.0711e-01 -1.9911e-01 1.4915e-03 12 8 8 10 0 0 -1.73 23.75 64.05 -0.19911 -0.29017 8 2 1 4 0 4000.000 27.56 20.00 23.75 -19802 107923 110535 39088 27401 -4341 -86358 182024 900000 79749 94276 111410 36141 -15997 177803 -32717 145130 -24306 56015 48010 35383 60389 9488 900000 24144 20517 85951 31385 900000 41228 204349 15546 52803 14732 -56486 940 -3921 37655 3552 140929 43405 117128 29685 -28055 900000 170457 900000 31639 8183 -8959 18414 900000 -32932 197894 6877 143871 85072 11088 81956 -9317 75189 23937 207500 69446 -29038 346880 -41227 55289 -28688 15553 14578 145009 21497 145264 900000 59353 900000 85599 229758 53450 900000 112546 -12378 261713 28148 900000 61063 35614 40322 98114 30460 -4392 53955 100551 45760 -20040 -4651 900000 -76425 63669 120592 900000 283920 288802 27452 -32221 900000 8613 109675 111400 92906 -22696 -17269 14613 -44881 8260 900000 -4505 261328 -27838 19584 -61654 900000 900000 67772 -41848 325469 -10611 -36437 28891 29515 900000 14491 -13778 254902 -47523 900000 39873 23000 -12253 156223 48031 -52943 49519 -24440 900000 -26838 -28623 3820 205116 -14084 114645 900000 -25047 59723 61169 29356 23828 -5319 -245774 100730 900000 44132 52171 61653 30000 -22132 98394 -53022 80313 -37470 39854 37954 32168 42967 11251 900000 24813 21897 47564 29774 900000 34222 113084 15977 37570 15722 -118784 1226 -5425 34234 4493 77988 36030 64817 28162 -44506 900000 94329 900000 28014 9057 -11569 17663 900000 -49812 109512 6850 79616 47078 11453 45353 -12030 41609 22077 114828 40992 -46065 191959 -73006 36715 -43393 14919 13984 80246 19034 80387 900000 37225 900000 47370 127145 33522 900000 62281 -14156 144829 21808 900000 36045 27591 29752 54295 23598 -4699 31849 55644 28699 -22920 -4118 900000 -109961 35234 66734 900000 157118 159819 15192 -34547 900000 7745 60693 61647 51413 -29830 -21502 13141 -71405 7428 900000 -4362 144616 -36588 16933 -123680 900000 900000 37504 -57895 180111 -10643 -47889 19985 20417 900000 11527 -14296 141059 -67391 900000 24823 17501 -13562 86452 29902 -93388 32541 -34657 900000 -38986 -41579 3964 113509 -17537 63443 900000 SO 20180208T093429.0Z 6613.398947 291 1 32.00 2 88.30 107.03 23.57 34.17 0.00 1 0.00 1 0 50 8.988e-01 4.821e-01 6.396e-01 4.157e-01 -4.092022e+04 2.334652e+04 1.374525e+03 -6.000000e+00 5.334708e+04 288.83 -2.00 20.00 -2.00 505.04 0.00e+00 2.290364e-02 1.217173e-02 1.151142e-03 -6.000000e+00 2.646261e-02 288.83 -2.00 20.00 -2.00 500.37 0.00e+00 2.253970e+00 8.411877e+00 4.661661e-01 -6.000000e+00 1.877709e+01 229.69 -2.00 3.16 -2.00 501.86 0.00e+00 16.748 0.044 489.00 513.00 1 1.1185e+01 6.5252e-01 5.1001e-02 -6.0000e+00 1.4563e+00 1.3917e-01 1.6036e-01 6.2612e-03 -6.0000e+00 3.7079e-01 1.1101e-06 5.0418e-02 2.5149e-02 6.7765e-04 -6.0000e+00 9.5407e-02 1.1906e-01 1.9023e-03 12 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